journal article·2023-12

Nest-like NiFe-LDH derived from the ethylene glycol-assisted hydrothermal route: A highly efficient electrocatalyst for water oxidation in neutral solutions

Zolfaghar Rezvani, Leila Jafari Foruzin, Kamellia Nejati, Hongxing Dai

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Abstract

Water oxidation is an optimistic pathway for hydrogen generation with high quality. In this work, nest-like nickel iron-layered double hydroxide (NiFe-LDH) nanomaterials were successfully prepared using the ethylene glycol-assisted hydrothermal strategy. Morphological and structural studies showed that in the assistance of ethylene glycol (EG), morphologies of the NiFe-LDH nanomaterials were modified, and their surface areas were enhanced. The nano nest-like NiFe-LDH-EG3 derived with 3.0 mL of EG exhibited an excellent oxygen evolution reaction (OER) activity with a low overpotential of about 400 mV at a current density of 10 mA/cm 2 and a Tafel slope of 79 mV/dec in neutral media, and such an outstanding OER activity was attributed to the modified morphology, good crystallinity, and high surface area of the nest-like NiFe-LDH-EG3.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (64)

Show source-provided references
1. Tertiary-amine-assisted synthesis of hierarchical porous nitrogen-incorporated cobalt–iron (oxy) hydroxide nanosheets for improved oxygen evolution reaction10.1021/acsaem.1c01030 ↗
2. The catalysis of the oxygen evolution reaction by iron impurities in thin film nickel oxide electrodes10.1149/1.2100463 ↗
3. Effect of rare-earth element doping on NiFe-layered double hydroxides for water oxidation at ultrahigh current densities10.1021/acssuschemeng.2c05060 ↗
4. Enhanced surface wettability and innate activity of an iron borate catalyst for efficient oxygen evolution and gas bubble detachment10.1039/C9TA03346G ↗
5. Efficient oxygen evolution and gas bubble release achieved by a low gas bubble adhesive iron–nickel vanadate electrocatalyst10.1002/smll.202002412 ↗
6. In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution10.1038/s41467-020-16237-1 ↗
7. “Structural instability” induced high-performance NiFe layered double hydroxides as oxygen evolution reaction catalysts for pH-near-neutral borate electrolyte: the role of intercalates10.1016/j.apcatb.2019.118343 ↗
8. Direct electrolytic splitting of seawater: opportunities and challenges10.1021/acsenergylett.9b00220 ↗
9. Partially reduced Ni2+, Fe3+-layered double hydroxide for ethanol electrocatalysis10.1007/s10853-019-03964-0 ↗
10. Stable and active NiFeW layered double hydroxide for enhanced electrocatalytic oxygen evolution reaction10.1016/j.cej.2021.130768 ↗
11. Dry gel synthesis of hierarchical ZSM-5 zeolite using hydroxyl propyl methyl cellulose (HPMC) as a mesoporogen and its catalytic activity in alkylation reactions10.1039/D2RA04325D ↗
12. Self-assembling of conductive interlayer-expanded WS2 nanosheets into 3D hollow hierarchical microflower bud hybrids for fast and stable sodium storage10.1002/adfm.201907677 ↗
13. Active surface area and intrinsic catalytic oxygen evolution reactivity of NiFe-LDH at reactive electrode potentials using capacitances10.1021/acscatal.2c04452 ↗
14. A nickel-borate nanoarray: a highly active 3D oxygen-evolving catalyst electrode operating in near-neutral water10.1039/C6CC09893B ↗
15. Carbon-layered double hydroxide nanocomposite for efficient removal of inorganic and organic based water contaminants–unravelling the adsorption mechanism10.1039/D1MA00064K ↗
16. Deciphering iron-dependent activity in oxygen evolution catalyzed by nickel–iron layered double hydroxide10.1002/ange.201915803 ↗
17. Highly efficient Ni nanotube arrays and Ni nanotube arrays coupled with NiFe layered-double-hydroxide electrocatalysts for overall water splitting10.1016/j.jpowsour.2019.227434 ↗
18. Amorphous NiFe-layered double hydroxides nanosheets for oxygen evolution reaction10.1016/j.electacta.2020.136827 ↗
19. Boosting oxygen evolution activity of NiFe-LDH using oxygen vacancies and morphological engineering10.1039/D1TA06263H ↗
20. Crystalline NiFe layered double hydroxide with large pore volume as oxygen evolution electrocatalysts10.1016/j.matchemphys.2020.123496 ↗
21. Electronic structure regulation of nickel-iron layered double hydroxides by tuning ternary component for overall water splitting
22. CoMoP/NiFe-layered double-hydroxide hierarchical nanosheet arrays standing on Ni foam for efficient overall water splitting10.1021/acsaem.0c01538 ↗
23. Flower-like Co3O4@ NiFe-LDH nanosheets enable high-performance bifunctionality towards both electrocatalytic HER and OER in alkaline solution10.1016/j.jallcom.2022.165877 ↗
24. An approach to understanding the electrocatalytic activity enhancement by superexchange interaction toward OER in alkaline media of Ni–Fe LDH10.1021/jp506946b ↗
25. Effect of pH on the uptake of arsenate and vanadate by hydrotalcites in alkaline solutions: a Raman spectroscopic study10.1002/jrs.2680 ↗
26. Engineering active Fe sites on nickel–iron layered double hydroxide through component segregation for oxygen evolution reaction10.1002/cssc.201902841 ↗
27. Nanostructured manganese oxide on fullerene soot for water oxidation under neutral conditions10.1016/j.ijhydene.2022.12.236 ↗
28. Effect of the synthesis route and Fe presence on the redox activity of Ni in layered double hydroxides10.1002/celc.201600197 ↗
29. Effect of N-doping, exfoliation, defect-inducing of Ni-Fe layered double hydroxide (Ni-Fe LDH) nanosheets on catalytic hydrogen storage of N-ethylcarbazole over Ru/Ni-Fe LDH10.1016/j.fuel.2021.121688 ↗
30. Microporous 2D NiCoFe phosphate nanosheets supported on Ni foam for efficient overall water splitting in alkaline media10.1039/C8NR03350A ↗
31. Eutectic solvent-mediated synthesis of NiFe-LDH/sulfur-doped carbon nitride arrays: investigation of electrocatalytic activity for the dimetridazole sensor in human sustenance10.1021/acssuschemeng.0c06070 ↗
32. Ternary Ni-Co-Fe oxyhydroxide oxygen evolution catalysts: Intrinsic activity trends, electrical conductivity, and electronic band structure10.1007/s12274-019-2391-y ↗
33. Single-layer nanosheets with exceptionally high and anisotropic hydroxyl ion conductivity10.1126/sciadv.1602629 ↗
34. Partial sulfidation strategy to NiFe-LDH@FeNi2S4 heterostructure enable high-performance water/seawater oxidation10.1002/adfm.202200951 ↗
35. Nickel–iron oxyhydroxide oxygen-evolution electrocatalysts: the role of intentional and incidental iron incorporation10.1021/ja502379c ↗
36. Demonstrating the source of inherent instability in NiFe LDH-based OER electrocatalysts10.1039/D2TA07261K ↗
37. Iron vs aluminum based layered double hydroxides as water splitting catalysts10.1016/j.electacta.2015.12.059 ↗
38. Inducing the SnO2-based electron transport layer into NiFe LDH/NF as efficient catalyst for OER and methanol oxidation reaction10.1016/j.jmst.2022.01.022 ↗
39. MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions10.1039/C9CS00906J ↗
40. Atomically dispersed Mo supported on metallic Co9S8 nanoflakes as an advanced noble-metal-free bifunctional water splitting catalyst working in universal pH conditions10.1002/aenm.201903137 ↗
41. Construction of an advanced NiFe-LDH/MoS2–Ni3S2/NF heterostructure catalyst toward efficient electrocatalytic overall water splitting10.1021/acs.inorgchem.3c00425 ↗
42. Investigation of nickel iron layered double hydroxide for water oxidation in different pH electrolytes10.1016/S1872-2067(22)64190-1 ↗
43. Missing-linker metal-organic frameworks for oxygen evolution reaction10.1038/s41467-019-13051-2 ↗
44. Core–shell NiFe-LDH@NiFe-Bi nanoarray: in situ electrochemical surface derivation preparation toward efficient water oxidation electrocatalysis in near-neutral media10.1021/acsami.7b01637 ↗
45. 3D-printed zeolite with combined structure for xylene isomerization10.1016/j.matdes.2022.110744 ↗
46. Oxygen vacancies and surface reconstruction on NiFe LDH@Ni(OH)2 heterojunction synergistically triggering oxygen evolution and urea oxidation reaction10.1016/j.jallcom.2022.166145 ↗
47. Hierarchical hollow nanoprisms based on ultrathin Ni-Fe layered double hydroxide nanosheets with enhanced electrocatalytic activity towards oxygen evolution10.1002/ange.201710877 ↗
48. An alkaline electro-activated Fe–Ni phosphide nanoparticle-stack array for high-performance oxygen evolution under alkaline and neutral conditions10.1039/C7TA03163G ↗
49. Support and interface effects in water-splitting electrocatalysts10.1002/adma.201808167 ↗
50. Designed formation of double-shelled Ni–Fe layered-double-hydroxide nanocages for efficient oxygen evolution reaction10.1002/adma.201906432 ↗
51. Hierarchical trimetallic layered double hydroxide nanosheets derived from 2D metal-organic frameworks for enhanced oxygen evolution reaction10.1016/j.apcatb.2019.118532 ↗
52. Self-supported hierarchical CoFe-LDH/NiCo2O4/NF core-shell nanowire arrays as an effective electrocatalyst for oxygen evolution reaction10.1016/j.jallcom.2019.153345 ↗
53. Magnetic field enhanced electrocatalytic oxygen evolution of NiFe-LDH/Co3O4 p-n heterojunction supported on nickel foam10.1002/smtd.202200084 ↗
54. Electrostatically assembling 2D nanosheets of MXene and MOF-derivatives into 3D hollow frameworks for enhanced lithium storage10.1002/smll.201904255 ↗
55. Multiple structural defects in ultrathin NiFe-LDH nanosheets synergistically and remarkably boost water oxidation reaction10.1007/s12274-021-3475-z ↗
56. Facile, controllable, and ultrathin NiFe-LDH in situ grown on a Ni foam by ultrasonic self-etching for highly efficient urine conversion10.1021/acs.est.2c07282 ↗
57. Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption10.1038/nchem.2886 ↗
58. A high surface area flower-like Ni–Fe layered double hydroxide for electrocatalytic water oxidation reaction10.1039/C5DT01474C ↗
59. Defective and ultrathin NiFe LDH nanosheets decorated on V-doped Ni3S2 nanorod arrays: a 3D core–shell electrocatalyst for efficient water oxidation10.1039/C9TA06347A ↗
60. The influence of increased content of Ni (III) in NiFe LDH via Zn doping on electrochemical catalytic oxygen evolution reaction10.1016/j.ijhydene.2022.11.075 ↗
61. Tube-sponge-inspired hierarchical electrocatalysts with boosted mass and electron transfer for efficient oxygen evolution10.1002/adma.202209500 ↗
62. Self-assembled ruddlesden–popper/perovskite hybrid with lattice-oxygen activation as a superior oxygen evolution electrocatalyst10.1002/smll.202001204 ↗
63. Metal oxide-based materials as an emerging family of hydrogen evolution electrocatalysts10.1039/D0EE02485F ↗
64. Boosting oxygen evolution reaction by activation of lattice-oxygen sites in layered Ruddlesden-Popper oxide10.1002/eom2.12021 ↗