journal article·2023-08

Effects of modified palygorskite on performance, crystallization and rheology of polyphenylene sulfide

Chunyao Wang, Zhe Wang, Chen Li, Weijun Zhen, Shigang Wang, Shengbing Huang

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Abstract

In this work, Pal-Fe 3O 4 was prepared by magnetic modification of purified palygorskite (Pal), and then STAC@Pal-Fe 3O 4 was prepared by organic modification of Pal-Fe 3O 4 with Stearyl trimethyl ammonium chloride (STAC). The preparation conditions of STAC@Pal-Fe 3O 4 were optimized by orthogonal experiment. Some characterization results such as X-ray diffraction and Fourier transform infrared spectroscopy (FTIR) showed that palygorskite had been successfully modified. In addition, STAC@Pal-Fe 3O 4/polyphenylene sulfide (PPS) nanocomposites were prepared by melt blending method. The mechanical properties, rheological properties and crystallization properties of STAC@Pal-Fe 3O 4/PPS nanocomposites were studied. When the mass fraction of STAC@Pal-Fe 3O 4 in PPS was 2.5 wt%, the tensile strength and impact strength of STAC@Pal-Fe 3O 4/PPS nanocomposites were 65.06% and 366% higher than those of pure PPS, respectively. Thermogravimetric analysis showed that STAC@Pal-Fe 3O 4 improved the thermal stability of PPS. The non-isothermal crystallization behavior of STAC@Pal-Fe 3O 4/PPS nanocomposites was studied by DSC method and Rheonaut technology for simultaneous rheology and FTIR, respectively. The results showed that STAC@Pal-Fe 3O 4 can significantly improve the crystallization rate and crystallinity of PPS. Rheological studies presented that STAC@Pal-Fe 3O 4 had strong compatibility with PPS.
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Research context

OpenAlex topics: Polymer Nanocomposites and Properties · biodegradable polymer synthesis and properties · Polymer crystallization and properties

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