journal article·2025-03Open access

Mechanochemical activation of non-conventional precursors for use as suplementary cementitious materials

A. Seco, M.A. Martín-Antunes, S. Espuelas, A. Fernández, E. Prieto

Abstract

This work analyzes the effect of Mechanochemical Activation (MA) of a Commercial low-grade kaolinite and low-grade illite, a feldspar, a diatomite and a clayey soil (non-commercial) as supplementary cementitious materials. Milling was conducted at different times for up to 360 min. MA decreased the particles size and increased the specific surface area except for low-grade illite. However, prolonged milling produced agglomeration in feldspar, diatomite and clayey soil. MA partially reduced diffractogram peaks and modified the dehydroxylation losses of mass in the thermogravimetric tests. MA's effect over the solubility of SiO 2 and Al 2 O 3 was not conclusive, with differences among aluminosilicate minerals and with no relationships with their physical parameters or chemical structures. Feldspar was the only one not to show Strength Activity Index (SAI) increases due to MA. Low-grade illite, feldspar and diatomite combinations surpassed 75 % on the SAI. No clear relationships were observed between the combinations SAI and their physical parameters, chemical structure or SiO 2 and Al 2 O 3 availability. • Milling times exceeding the optimal produced particles agglomeration. • Mechanochemical activation (MA) partially amorphized the samples. • MA demonstrated its effectiveness in the Strength Activity Index test.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Innovations in Concrete and Construction Materials · Magnesium Oxide Properties and Applications

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References (35)

Show source-provided references
1. Physico-mechanical characteristics of blended white cement pastes containing thermally activated ultrafine nano clays10.1016/j.conbuildmat.2013.05.011 ↗
2. Mechanochemical and thermal activation of kaolin for manufacturing geopolymer mortars – Comparative study10.1016/j.ceramint.2016.06.182 ↗
3. MAS NMR and EPR study of structural changes in talc and montmorillonite induced by grinding10.1180/claymin.2016.051.1.06 ↗
4. Novel low emissions supersulfated cements of pumice in concrete; mechanical and electrochemical characterization10.1016/j.jclepro.2020.122520 ↗
5. Turning sandstone clay into supplementary cementitious material: activation and pozzolanic reactivity evaluation10.1016/j.compositesb.2021.109137 ↗
6. Effects of processing on the mineralogy and solubility of carbonate-rich clays for alkaline activation purpose: mechanical, thermal activation in red/ox atmosphere and their combination10.1016/j.clay.2017.11.036 ↗
7. Performance of mortar incorporating calcined marine clays with varying kaolinite content10.1016/j.jclepro.2020.124513 ↗
8. Pozzolanic activity of thermally and mechanically treated kaolins of hydrothermal origin10.1016/j.clay.2015.08.028 ↗
9. Thermally and mechanically treated Greek palygorskite clay as a pozzolanic material10.1016/j.clay.2021.106306 ↗
10. The effect of mechanical treatment on the structure of montmorillonite10.1016/j.matlet.2006.11.063 ↗
11. Effects of mechanical and thermal activation on pozzolanic activity of kaolin containing mica10.1016/j.clay.2016.01.029 ↗
12. Comprehensive examination of dehydroxylation of kaolinite, disordered kaolinite, and dickite: experimental studies and density functional theory10.1007/s42860-020-00082-w ↗
13. Supplementary cementitious materials: new sources, characterization, and performance insights10.1016/j.cemconres.2019.05.008 ↗
14. The dissolution kinetics of raw and mechanochemically treated kaolinites in industrial spent liquor – the effect of the physico-chemical properties of the solids10.1016/j.clay.2021.105994 ↗
15. Advances in alkali-activation of clay minerals10.1016/j.cemconres.2020.106050 ↗
16. Kaolinite structural modifications induced by mechanical activation10.1016/j.clay.2023.106918 ↗
17. Water treatment sludge as precursor in non-dehydroxylated kaolin-based alkali-activated cements10.1016/j.clay.2021.106032 ↗
18. Potential reactivity assessment of mechanically activated kaolin as alternative cement precursor10.1016/j.clay.2022.106648 ↗
19. Phase formation behaviour in alkali activation of clay mixtures10.1016/j.clay.2019.03.037 ↗
20. The use of stabilised Spanish clay soil for sustainable construction materials10.1016/j.enggeo.2012.02.010 ↗
21. Investigation of particle characteristics and enhancing the pozzolanic activity of diatomite by grinding10.1016/j.matchemphys.2021.124799 ↗
22. Structural changes in smectites subjected to mechanochemical activation: the effect of the occupancy of the octahedral sites10.1016/j.clay.2021.106214 ↗
23. A thermo-mechano-chemical activation technique to use quartz rich marine clay for one-part geopolymer preparation10.1016/j.cemconcomp.2023.105057 ↗
24. Effects of grinding of the feldspar in the sintering using a planetary ball mill10.1016/j.jmatprotec.2004.04.367 ↗
25. The use of non-conventional additives in Marls stabilization10.1016/j.clay.2010.12.032 ↗
26. Sulfate soils stabilization with magnesium-based binders10.1016/j.clay.2016.10.033 ↗
27. Pozzolanic activity of mechanochemically and thermally activated kaolins in cement10.1016/j.cemconres.2015.04.017 ↗
28. Hydration mechanism of calcium sulfoaluminate-activated supersulfated cement
29. Mechanochemical activation of natural clay minerals: an alternative to produce sustainable cementitious binders – review10.1007/s00710-019-00666-y ↗
30. Enhancement of the pozzolanic activity of natural clays by mechanochemical activation10.1016/j.conbuildmat.2022.128739 ↗
31. The surface properties of clay minerals modified by intensive dry milling — revisited10.1016/j.clay.2010.03.006 ↗
32. Effects of Mechanical Activation on Physical and Chemical Characteristics of Coal-Gasification Slag10.3390/coatings11080902 ↗
33. Effect of mechanochemical processing on illite particles10.1002/ppsc.200500953 ↗
34. Pozzolanic activity and hydration properties of feldspar after mechanical activation10.1016/j.powtec.2021.01.042 ↗
35. The influence of two types of alkali activators on the microstructure and performance of supersulfated cement concrete: mitigating the strength and carbonation resistance10.1016/j.cemconcomp.2021.103947 ↗