Immobilization of a cationic manganese(III) porphyrin on lithium gordaite (LiZn4(OH)6(SO4)Cl·6H2O), a layered hydroxide salt with cation exchange capacity
Source abstract
Abstract
Abstract Sodium gordaite (NaG - NaZn 4 (OH) 6 (SO 4 )Cl·6H 2 O) was synthesized, characterized and the intercalated sodium cations (in hydrated state) of NaG were replaced by lithium where the basal parameter was altered from 13.03 A to 17.84 A. The obtained lithium gordaite (LiG) was used as support for the immobilization of a cationic manganese(III) porphyrin (MnP) on the outer surfaces of the layered crystals. Before and after MnP immobilization, the material was investigated by several instrumental techniques, showing that this class of layered compounds is a new alternative for the immobilization of cationic species for a broad range of potential applications.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Mesoporous Materials and Catalysis · Porphyrin and Phthalocyanine Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (23)
Show source-provided references
1. Tubular and spheroidal halloysite in pyroclastic deposits in the area of the Roccamonfina volcano (Southern Italy)10.1016/S0016-7061(00)00076-8 ↗
2. The crystal structure of gordaite NaZn4(SO4)(OH)6Cl·6H2O
3. Layered hydroxide salts: synthesis, properties and potential applications10.1016/j.ssi.2007.04.016 ↗
4. Manganese porphyrin in solution and heterogenized in different materials mediates oxidation of hydrocarbons by iodosylbenzene10.1016/j.molcata.2013.06.022 ↗
5. The crystal structure of hydrozincite, Zn5(OH)6(CO3)210.1107/S0365110X64002651 ↗
6. Synthesis and vibrational spectroscopic characterisation of synthetic hydrozincite and smithsonite10.1016/j.poly.2007.07.002 ↗
7. Cobaltogordaite, IMA 2014-043. CNMNC Newsletter 22, 2014, 1243
8. Immobilization of metalloporphyrins into nanotubes of natural halloysite toward selective catalysts for oxidation reactions10.1016/j.molcata.2007.12.009 ↗
9. Aluminosilicate obtained by sol–gel process as support for an anionic iron porphyrin: development of a selective and reusable catalyst for oxidation reactions10.1016/j.colsurfa.2009.08.013 ↗
10. Anionic iron(III) porphyrins immobilized on zinc hydroxide chloride as catalysts for heterogeneous oxidation reactions10.1016/j.apcata.2011.10.046 ↗
11. Recent advances in solid catalysts obtained by metalloporphyrins immobilization on layered anionic exchangers: a short review and some new catalytic results10.3390/molecules21030291 ↗
12. Gordaite [Zn4Na(OH)6(SO4)Cl·6H2O]: second occurrence in the Juan de Fuca Ridge, and new data10.2138/am-1998-9-1020 ↗
13. Interstratified composite of the anionic clays, Zn5(OH)8(NO3)2∙2H2O and Ni3Zn2(OH)8(NO3)2∙2H2O, by delamination-costacking10.1016/j.jpcs.2013.03.015 ↗
14. Formation of NaZn4Cl(OH)6SO4·6H2O in a marine atmosphere10.1016/0010-938X(93)90082-R ↗
15. Zinc chlorohydroxosulfates: newly discovered corrosion products on zinc. Structure determination of NaZn4Cl(OH)6SO4·6H2O and X-ray study of Zn4Cl2(OH)4SO4·5H2O10.1016/0010-938X(93)90083-S ↗
16. Evaluation of layered zinc hydroxide nitrate and zinc/nickel double hydroxide salts in the removal of chromate ions from solutions10.1016/j.jssc.2016.08.019 ↗
17. Mn porphyrins immobilized on non-modified and chloropropyl-functionalized mesoporous silica SBA-15 as catalysts for cyclohexane oxidation10.1016/j.apcata.2016.07.018 ↗
18. Chromate intercalation in Ni–Zn layered hydroxide salts10.1016/j.clay.2010.04.023 ↗
19. Investigation of the hydrozincite structure by infrared and solid-state NMR spectroscopy10.2138/am.2013.4158 ↗
20. Gordaite, NaZn4(SO4)(OH)6Cl·6H2O, a new mineral from the San Francisco Mine, Antofagasta10.1127/njmm/1997/1997/155 ↗
21. Wülfingite, ε-Zn(OH)2, and simonkolleite, Zn5(OH)8Cl2·H2O, two new minerals from Richelsdorf
22. The crystal structure of zinc hydroxide nitrate, Zn5(OH)8(NO3)2·2H2O10.1107/S0567740870003230 ↗
23. Crystal structure of Zn4Na(OH)6SO4Cl·6H2O10.1007/BF02575981 ↗