Phosphate intercalated Mg/Al layered double hydroxide nanosheets as a novel flame retardant for leather: Synthesis, characterization, and application studies
Source abstract
Abstract
Ammonium polyphosphate (APP) modified Mg/Al layered double hydroxide (LDH) flame retardants (FR) were synthesized by varying the APP concentration between 5 and 15% (PLDH-5, PLDH-10, PLDH-15). Synthesized PLDH (APP modified LDH) were characterized for their microstructural, physicochemical, and thermal properties. FE-SEM images of the PLDH showed agglomerated nanosheets indicating the interaction of APP with the LDH. XRD studies of the PLDH confirmed the intercalation of phosphate ions into the interlayer gallery, leading to an increase in the interlayer distance from 0.76 to 1.07 nm. Emphasis was given to the thermogravimetric (TGA/DTG) and differential scanning calorimetric (DSC) examination of the PLDH, and PLDH treated leathers to understand their thermal insight. The PLDH-treated leathers showed an increase in the thermal stability of the collagen. The endothermic dehydroxylation and decomposition observed in the DSC studies indicated the suitability of the PLDH as flame-retardant material. Application of 3% PLDH during leather making improved the flammability degree of leather by 18.2%. The synthesized PLDH exhibited equivalent or better flame retardant performance as compared to the other flame retardant chemicals reported in the literature for leather applications. The flame retardant mechanism of PLDH was also discussed.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Flame retardant materials and properties · Silicone and Siloxane Chemistry · biodegradable polymer synthesis and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (62)
Show source-provided references
1. Prospects use of hybrid layered double hydroxides-polyacrylamide as controlled release media for antibiotic molecules: ARTICLE10.1002/app.45442 ↗
2. Bio-template synthesis of MgAl layered double hydroxide with enhanced flame retardant property for leather finishes10.1016/j.apsusc.2021.149409 ↗
3. Behavior of leather as a protective heat barrier and fire resistant material
4. Characterisation and evaluation of the environmental impact on historical parchments by differential scanning calorimetry10.1007/s10973-011-1495-8 ↗
5. Sulfamerazine Schiff-base complex intercalated layered double hydroxide: synthesis, characterization, and antimicrobial activity10.1016/j.heliyon.2019.e01521 ↗
6. Layered double hydroxides: new technology in phosphate fertilizers based on nanostructured materials10.1021/acssuschemeng.6b01784 ↗
7. Modified rapeseed oil/silane coupling agent-montmorillonite nanocomposites prepared by in-situ method: Synthesis and properties10.1016/j.indcrop.2015.03.034 ↗
8. Nanocomposite based on erucic acid modified montmorillonite/sulfited rapeseed oil: Preparation and application in leather10.1016/j.clay.2015.12.021 ↗
9. Layer−Anion Interactions in Magnesium Aluminum Layered double Hydroxides Intercalated with Cobalticyanide and Nitroprusside10.1021/cm990148l ↗
10. The use of thermal analysis methods for authentication and conservation state determination of historical and/or cultural objects manufactured from leather10.1007/s10973-010-1183-0 ↗
11. Preparation of silica doped titania nanoparticles with thermal stability and photocatalytic properties and their application for leather surface functionalization10.1016/j.arabjc.2016.09.002 ↗
12. Infrared Analysis of Phosphorous Compounds10.1002/jctb.5010061007 ↗
13. Covington · 2009
14. Chemical exfoliation of layered magnesium diboride to yield functionalized nanosheets and nanoaccordions for potential flame retardant applications10.1021/acsanm.8b00101 ↗
15. Influence of ammonium polyphosphate o the mechanism of thermal degradation of an acrylic binder resin10.1002/app.20868 ↗
16. Flame retardance of leather with flame retardant added in retanning process10.1016/j.rinp.2019.102717 ↗
17. Flame retardant biocomposites: Synergism between phosphinate and nanometric metal oxides10.1016/j.eurpolymj.2011.04.001 ↗
18. Ammonium Polyphosphate Intercalated Layered double Hydroxide and Zinc Borate as Highly Efficient Flame Retardant Nanofillers for Polypropylene10.3390/polym10101114 ↗
19. Characterizing Flame Retardant applications and potential Human Exposure in Backpacking Tents10.1021/acs.est.6b00923 ↗
20. Flame retardancy by phosphorous compounds10.1021/ar50125a001 ↗
21. Efficient Flame-Retardant and Smoke-suppression Properties of Mg–Al-Layered Double-Hydroxide Nanostructures on Wood Substrate10.1021/acsami.7b06803 ↗
22. Harper · 2004
23. Correlation between bulk- and surface chemistry of Cr-tanned leather and the release of Cr(III) and Cr(VI)10.1016/j.jhazmat.2014.08.061 ↗
24. Structural transformation of layered double hydroxides: an in situ TEM analysis
25. Nano CaAlCO3-layered double hydroxide-doped intumescent fire-retardant coating for mitigating wood fire hazards
26. Performance of flame retardants on leather
27. Phosphorus-containing flame retardant epoxy thermosets: recent advances and future perspectives10.1016/j.progpolymsci.2021.101366 ↗
28. ISO 17074 · 2006
29. Study on a novel multifunctional nanocomposite as flame retardant of leather10.1016/j.polymdegradstab.2015.02.018 ↗
30. Intercalation of organic and inorganic anions into layered double hydroxides for polymer flame retardancy
31. Synthesis, characterization and optical properties of Mg(OH)2 micro−/nanostructure and its conversion to MgO10.1016/j.ceramint.2009.05.035 ↗
32. Thermal behaviour of ammonium polyphosphate – inorganic compound mixtures. Part 110.1016/0040-6031(94)87054-3 ↗
33. Flame retardant and mechanical properties of polyethylene/magnesium hydroxide/montmorillonite nanocomposites10.1016/j.jiec.2013.10.020 ↗
34. Formation of a Compact protective Layer by Magnesium Hydroxide Incorporated with a Small Amount of Intumescent Flame Retardant: New Route to High Performance Nonhalogen Flame Retardant TPV10.1021/ie5008147 ↗
35. Mechanical, thermal and flame retardant properties of magnesium hydroxide filled poly(vinyl chloride) composites: the effect of filler shape10.1016/j.compositesa.2018.07.012 ↗
36. Adsorption and catalytic degradation of organic dyes in water using ZnO/ZnxFe3-xO4 mixed oxides10.1016/j.jece.2015.04.021 ↗
37. Azoin dye hosted in layered double hydroxide: physicochemical characterization of the intercalated materials10.1021/la901201s ↗
38. Alginate and hydrotalcite-like anionic clay composite systems: Synthesis, characterization and application studies10.1016/j.micromeso.2012.03.046 ↗
39. Reduction in chemicals leaching in the leather industry effluent using hydrated layered double hydroxide as a fixative
40. Recent advances on polyoxometalates intercalated layered double hydroxides: from synthetic approaches to functional material applications10.1016/j.ccr.2013.08.039 ↗
41. Ozonation as an environmentally friendly method to decolorize the leather products
42. Development of metal hydroxide nanoparticles from eggshell waste and seawater and their application as flame retardants for ethylene-vinyl acetate copolymer (EVA)10.1016/j.ijbiomac.2019.02.065 ↗
43. Recent developments in phosphorus based flame retardant coatings for textiles: synthesis, applications and performance
44. Fabrication of flame retardant coating on cotton fabric by alternate assembly of exfoliated layered double hydroxides and alginate10.1039/C6RA21804K ↗
45. Synthesis and characterization of Mg–Al-layered double hydroxides intercalated with cubane-1,4-dicarboxylate anions10.1039/C4DT03152K ↗
46. FTIR analysis of natural and synthetic collagen10.1080/05704928.2018.1426595 ↗
47. Sodium montmorillonite effect on the morphology, thermal, flame retardant and mechanical properties of semi-finished leather10.1016/j.clay.2014.10.007 ↗
48. Improvement of leather flame retardancy through nano clay addition
49. In-situ coprecipitation formed Fe/Zn-layered double hydroxide/ammonium polyphosphate hybrid material for flame retardant epoxy resin via synergistic catalytic charring10.1016/j.compositesa.2022.106841 ↗
50. Halogenated flame retardants: do the fire safety benefits justify the risks?10.1515/REVEH.2010.25.4.261 ↗
51. Synergistic effect of Layered Nanofillers in Intumescent Flame-Retardant EPDM: Montmorillonite versus Layered double Hydroxides10.1021/ie4010546 ↗
52. Sonication accelerated formation of Mg-Al-phosphate layered double hydroxide via sol-gel prepared mixed metal oxides10.1038/s41598-019-46910-5 ↗
53. Hydrogen generation by aluminum corrosion in seawater promoted by suspensions of aluminum hydroxide10.1016/j.ijhydene.2009.08.008 ↗
54. Advancements in traditional and nanosized flameretardants for polymers—a review10.1002/app.50050 ↗
55. Van Krevelen · 2009
56. Effect of P3O105- intercalated hydrotalcite on the flame retardant properties and the degradation mechanism of a novel polypropylene/hydrotalcite system10.1016/j.clay.2018.07.024 ↗
57. Synergistic Flame Retardant Effects between Aluminum Hydroxide and Halogen-free Flame Retardants in High Density Polyethylene Composites10.1016/j.proeng.2016.01.130 ↗
58. Synergistic flame retardant effect of metal hydroxide and nanoclay in EVA composites10.1016/j.polymdegradstab.2012.03.043 ↗
59. New flame-retardant composite separators based on metal hydroxides for lithium-ion batteries10.1016/j.electacta.2015.01.078 ↗
60. The preparation of a composite flame retardant of layered double hydroxides and α-zirconium phosphate and its modification for epoxy resin
61. Flame retardancy and thermal and mechanical performance of intercalated, layered double hydroxide composites of polyamide 11, aluminum phosphinate, and sulfamic acid10.1002/app.43370 ↗
62. Effects of modified layered double hydroxides on the thermal degradation and combustion behaviors of intumescent flame retardant polyethylene nanocomposites10.3390/polym14081616 ↗