Base-free oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid over palygorskite-supported bimetallic Pt–Pd catalyst
Source abstract
Abstract
Aerobic oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to 2, 5-furandicarboxylic acid (FDCA) is an important reaction for producing green and sustainable chemicals. Herein, natural clay mineral palygorskite (Pal)-supported bimetallic Pt–Pd catalyst for the oxidation of HMF to FDCA in water without the addition of any bases was developed. The 1Pt 9Pd 1 /Pal catalyst with Pt/Pd molar ratio of 9/1 exhibited excellent catalytic performance, and 100% HMF conversion and 99% FDCA yield were obtained under optimum reaction conditions after 12 h, which was mainly attributed to the synergy between palygorskite and bimetallic Pt–Pd nanoparticles. Palygorskite used as support realized the immobilization and dispersion of bimetallic nanoparticles, increasing the catalytic activity. The basicity of palygorskite and alloying effects between Pt and Pd facilitated the formation of FDCA by synergistically catalyzing the oxidation of alcohol and aldehyde groups in the reactants and intermediates. Furthermore, this catalyst showed good stability and reusability. The present work provides a highly efficient, cost-effective, and environmentally benign catalyst for the base-free oxidation of HMF to FDCA in practical industrial applications.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Catalysis for Biomass Conversion · Nanomaterials for catalytic reactions · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (79)
Show source-provided references
1. Immobilization of nanoparticles on fibrous clay surfaces: towards promising nanoplatforms for advanced functional applications10.1002/tcr.201700113 ↗
2. All-metal mesoporous nanocolloids: solution-phase synthesis of core-shell Pd@Pt nanoparticles with a designed concave surface10.1002/anie.201307126 ↗
3. 2013 · vol. 5
4. AuPd-nNiO as an effective catalyst for the base-free oxidation of HMF under mild reaction conditions10.1039/C9GC01283D ↗
5. Continuous flow synthesis of bimetallic AuPd catalysts for the selective oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid10.1002/cnma.201900704 ↗
6. One-pot aqueous synthesis of two-dimensional porous bimetallic PtPd alloyed nanosheets as highly active and durable electrocatalyst for boosting oxygen reduction and hydrogen evolution10.1016/j.jcis.2019.01.122 ↗
7. High catalytic performance of the Al-promoted Ni/Palygorskite catalysts for dry reforming of methane10.1016/j.clay.2020.105498 ↗
8. 2, 5-Furandicarboxylic acid production via catalytic oxidation of 5-hydroxymethylfurfural: catalysts, processes and reaction mechanism10.1016/j.jechem.2020.05.068 ↗
9. Base-free atmospheric O2-mediated oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic acid triggered by Mg-bearing MTW zeolite supported au nanoparticles10.1016/j.apcata.2021.118106 ↗
10. Hydrotalcite-supported PdPt-catalyzed aerobic oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid in water10.1246/cl.160178 ↗
11. Characterization of calcium oxide catalysts from natural sources and their application in the transesterification of sunflower oil10.1016/j.biortech.2013.10.046 ↗
12. Amine formylation with CO2 and H2 catalyzed by heterogeneous Pd/PAL catalyst10.1016/S1872-2067(19)63397-8 ↗
13. Oxidation of 5-hydroxymethylfurfural over supported Pt, Pd and Au catalysts10.1016/j.cattod.2010.06.004 ↗
14. An overview of the biphasic dehydration of sugars to 5-hydroxymethylfurfural and furfural: a rational selection of solvents using COSMO-RS and selection guides10.1039/C9GC04208C ↗
15. Hydrotalcite-supported gold catalyst for the oxidant-free dehydrogenation of benzyl alcohol: studies on support and gold size effects10.1002/chem.201002469 ↗
16. Highly efficient and stable bimetallic AuPd over La-doped Ca–Mg–Al layered double hydroxide for base-free aerobic oxidation of 5-hydroxymethylfurfural in Water10.1021/acssuschemeng.7b00573 ↗
17. Ru/MnXCe1OYcatalysts with enhanced oxygen mobility and strong metal-support interaction: Exceptional performances in 5-hydroxymethylfurfural base-free aerobic oxidation10.1016/j.jcat.2018.09.034 ↗
18. Highly dispersed ruthenium nanoparticles on hydroxyapatite as selective and reusable catalyst for aerobic oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid under base-free conditions
19. Base-free aerobic oxidation of 5-hydroxymethylfurfural on a Ru(0) center in cooperation with a Co(II)/Co(III) redox pair over the one-pot synthesized Ru–Co composites
20. Pickering HIPEs derived hierarchical porous nitrogen-doped carbon supported bimetallic AuPd catalyst for base-free aerobic oxidation of HMF to FDCA in water10.1016/j.fuel.2020.118362 ↗
21. Hierarchical porous bowl-like nitrogen-doped carbon supported bimetallic AuPd nanoparticles as nanoreactors for high efficient catalytic oxidation of HMF to FDCA10.1016/j.jcat.2021.02.012 ↗
22. The structures and microtextures of the palygorskite–sepiolite group minerals
23. Synthesis of ultrathin and composition-Tunable PdPt porous nanowires with enhanced electrocatalytic performance10.1021/acssuschemeng.9b07189 ↗
24. Clever use of natural clay materials in the synthesis of non-symmetric carbonates by utilizing CO2 as a feedstock: Ag/attapulgite nano-catalyst10.1039/D0DT01992E ↗
25. Catalytic aerial oxidation of 5-hydroxymethyl-2-furfural to furan-2, 5-dicarboxylic acid over Ni–Pd nanoparticles supported on Mg(OH)2 nanoflakes for the synthesis of furan diesters10.1039/C7QI00026J ↗
26. Insight into the nature of Au-Au2O3 functionalized palygorskite10.1016/j.clay.2014.04.004 ↗
27. Biorefinery roadmap based on catalytic production and upgrading 5-hydroxymethylfurfural10.1039/D0GC02770G ↗
28. Sustainable bioplastics: recent progress in the production of bio-building blocks for the bio-based next-generation polymer PEF10.1016/j.cej.2020.124636 ↗
29. Nitrogen-doped carbon-decorated CeO2 supported Pt nanoparticles for base-free aerobic oxidation of 5-hydroxymethylfurfural10.1002/asia.201800738 ↗
30. The effect of support on the structure and photocatalytic activity of ternary ZnO-ZnFe2O4/palygorskite composite photocatalysts10.1016/j.apt.2019.08.030 ↗
31. Synthesis and characterization of AMO LDH-derived mixed oxides with various Mg/Al ratios as acid–basic catalysts for esterification of benzoic acid with 2-ethylhexanol10.1016/j.apcatb.2018.10.073 ↗
32. Biomass-based biorefineries: An important architype towards a circular economy10.1016/j.fuel.2020.119622 ↗
33. Attapulgite as natural catalyst for glucose isomerization to fructose in water10.1016/j.catcom.2017.05.011 ↗
34. Preparation of self-nitrogen-doped porous carbon nanofibers and their supported PtPd alloy catalysts for oxygen reduction reaction
35. Porous carbon supported PtPd alloy nanoparticles derived from N-heterocyclic carbene bimetal complex as efficient bifunctional electrocatalysts10.1016/j.electacta.2020.135855 ↗
36. An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural10.1039/C9GC01674K ↗
37. Pd-Pt Bimetallic nanodendrites with high activity for oxygen reduction10.1126/science.1170377 ↗
38. Synergetic effect of Cu and Mn oxides supported on palygorskite for the catalytic oxidation of formaldehyde: dispersion, microstructure, and catalytic performance10.1016/j.clay.2018.04.032 ↗
39. Effect of oxalic acid-leaching levels on structure, color and physico-chemical features of palygorskite10.1016/j.clay.2019.105301 ↗
40. Synthesis of Zn/Cu metal ion modified natural palygorskite clay-TiO2 nanocomposites for the photocatalytic outdoor and indoor air purification10.1016/j.jphotochem.2021.113568 ↗
41. Vibrational analysis of palygorskite and sepiolite10.1346/000986002320679549 ↗
42. Toward an intensified process of biomass-derived monomers: the influence of 5-(hydroxymethyl)furfural byproducts on the gold-catalyzed synthesis of 2,5-furandicarboxylic acid10.1021/acssuschemeng.0c01319 ↗
43. Study of surface acid–base properties of natural clays and zeolites by the conversion of 2-methylbut-3-yn-2-ol10.1016/j.clay.2014.08.005 ↗
44. Magnesium and/or calcium-containing natural minerals as ecologically friendly catalysts for the Baeyer–Villiger oxidation of cyclohexanone with hydrogen peroxide10.1016/j.apcata.2015.10.021 ↗
45. Selective oxidation of 5-hydroxymethyl-2-furfural using supported gold–copper nanoparticles10.1039/c1gc15355b ↗
46. Palladium nanoparticles on silica-rich substrates by spontaneous reduction at room temperature10.1007/s11051-011-0508-7 ↗
47. Is the BET equation applicable to microporous adsorbents?10.1016/S0167-2991(07)80008-5 ↗
48. Advanced materials and new applications of sepiolite and palygorskite
49. Recent advances on fibrous clay-based nanocomposites10.1007/12_2014_283 ↗
50. Sepiolite-hydrogels: synthesis by ultrasound irradiation and their use for the preparation of functional clay-based nanoarchitectured materials
51. Pd immobilized on the composite of halloysite and low-cost bio-based eutectic solvent-derived carbon: An efficient catalyst for hydrogenation in the presence of cyclodextrin10.1016/j.clay.2020.105640 ↗
52. Applications of dimethyl carbonate for the chemical upgrading of biosourced platform chemicals10.1021/acssuschemeng.9b00464 ↗
53. Advances in the crystal chemistry of sepiolite and palygorskite
54. New insight into the mechanism for the excellent gas properties of poly (ethylene 2, 5-furandicarboxylate) (PEF): Role of furan ring’s polarity10.1016/j.eurpolymj.2019.06.033 ↗
55. Eco-friendly synthesis of SO3H-containing solid acid via mechanochemistry for the conversion of carbohydrates to 5-hydroxymethylfurfural10.1021/acssuschemeng.0c00784 ↗
56. Pd-modified au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2, 5-furandicarboxylic acid10.1002/cssc.201200778 ↗
57. New insight into the phase transformation of sepiolite upon alkali activation: Impact on composition, structure, texture, and catalytic/sorptive properties10.1016/j.clay.2020.105740 ↗
58. Base-free aerobic oxidation of 5-hydroxymethyl-furfural to 2,5-furandicarboxylic acid in water catalyzed by functionalized carbon nanotube-supported Au–Pd alloy nanoparticles10.1021/cs5003096 ↗
59. Surfacial carbonized palygorskite as support for high-performance Pt-based electrocatalysts10.1007/s10008-013-2029-z ↗
60. Pd–palygorskite catalysts: Preparation, characterization and catalytic performance for the oxidation of styrene10.1016/j.clay.2014.12.007 ↗
61. Basicity-tuned hydrotalcite-supported Pd catalysts for aerobic oxidation of 5-hydroxymethyl-2-furfural under mild conditions10.1021/acssuschemeng.6b00965 ↗
62. Hydrophilic mesoporous poly(ionic liquid) supported Au-Pd alloy nanoparticles towards aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under mild Condition10.1039/C7GC01116D ↗
63. Synthesis of palygorskite-supported Mn1−xCexO2 clusters and their performance in catalytic oxidation of formaldehyde10.1016/j.clay.2017.08.023 ↗
64. Preparation of Pd–B/palygorskite amorphous catalyst for the selective hydrogenation of o-chloronitrobenzene to o-chloroaniline10.1049/mnl.2015.0395 ↗
65. Aerobic oxidation of 5-hydroxymethylfurfural to 2, 5-difurancarboxylic acid over Pd-au nanoparticles supported on Mg-Al hydrotalcite10.1016/j.cattod.2018.05.050 ↗
66. Recent catalytic routes for the preparation and the upgrading of biomass derived furfural and 5-hydroxymethylfurfural10.1039/D0CS00041H ↗
67. Ultra-clean PtPd nanoflowers loaded on GO supports with enhanced low-temperature electrocatalytic activity for fuel cells in harsh environment10.1016/j.apsusc.2020.145603 ↗
68. FTIR spectroscopy study of the structure changes of palygorskite under heating10.1016/j.saa.2012.07.085 ↗
69. Utilization of biomass waste: Facile synthesis high nitrogen-doped porous carbon from pomelo peel and used as catalyst support for aerobic oxidation of 5-hydroxymethylfurfural10.1016/j.fuel.2020.118361 ↗
70. Effective conversion of saccharides into hydroxymethylfurfural catalyzed by a natural clay, attapulgite10.1016/j.renene.2019.11.084 ↗
71. Plasma-synthesized octahedral PtPd alloy/reduced graphene oxide nanocomposites with boosted electrocatalytic activity for methanol oxidation10.1016/j.jallcom.2020.155334 ↗
72. Palygorskite-anchored Pd complexes catalyze the coupling reactions of pyrimidin-2-yl sulfonates10.1039/C9RA06035A ↗
73. Recent advances in the catalytic synthesis of 2,5-furandicarboxylic acid and its derivatives10.1021/acscatal.5b01491 ↗
74. Catalytic oxidation of carbohydrates into organic acids and furan chemicals10.1039/C7CS00213K ↗
75. Selective aerobic oxidation of the biomass-derived precursor 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid under mild conditions over a magnetic palladium nanocatalyst10.1039/C4GC01833H ↗
76. Microwave-assisted oxidation of hydroxymethyl furfural to added-value compounds over a ruthenium-based catalyst10.1021/acssuschemeng.9b05656 ↗
77. Rational construction of metal-base synergetic sites on au/Mg-beta catalyst for selective aerobic oxidation of 5-hydroxymethylfurfural10.1016/j.jechem.2021.04.022 ↗
78. Influences of micropores and water molecules in the palygorskite structure on the color and stability of Maya blue pigment10.1016/j.micromeso.2021.111615 ↗
79. Alkaline Ionic liquid modified Pd/C catalyst as an efficient catalyst for oxidation of 5-hydroxymethylfurfural