journal article·2023-01

Enhanced adsorption properties of polyoxometalates/coal gangue composite:The key role of kaolinite-rich coal gangue

Hao Zhang, Rongbo Zhao, Zhiliang Liu, Xiangchao Zhang, Chunfang Du

Publisher page

Abstract

As a kind of solid waste, kaolinite-rich coal gangue (CG) occupies many lands and brings great pollution to the environment. Ciprofloxacin (CIP), as a widely used antibiotic, can not only easily lead to bacterial resistance, but also cause serious impacts on the environment and thus threaten human health. Therefore, the comprehensive utilization of kaolinite-rich CG and removal of CIP are definitely imminent. In this study, a series of adsorbents ammonium phosphotungstate/CG (NH 4-PW/CG) were synthesized through a simple precipitation method using kaolinite-rich CG as a support for the removal of CIP. The obtained NH 4-PW/CG displayed the excellent adsorption efficiency (82%) toward CIP within 10 min, which was much higher than NH 4-PW (25%) and CG (10%), respectively. The presence of kaolinite-rich CG made the surface charges of composite NH 4-PW/CG more negative and the particle size of NH 4-PW smaller, both of which contributed to the enhanced adsorption efficiency of NH 4-PW/CG. This work offers a new strategy for the comprehensive utilization of kaolinite-rich CG and provides an efficient adsorbent for the removal of positively charged pollutants.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Phosphorus and nutrient management · Arsenic contamination and mitigation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (58)

Show source-provided references
1. Enhancement of ciprofloxacin sorption on chitosan/biochar hydrogel beads10.1016/j.scitotenv.2018.05.129 ↗
2. The investigation into the ammonium removal performance of yemeni natural zeolite: modification, ion exchange mechanism, and thermodynamics10.1016/j.powtec.2014.02.063 ↗
3. Ciprofloxacin-induced acute renal failure in a patient with cystic fibrosis10.1097/00006454-200103000-00024 ↗
4. Adsorption of lead by chemically activated carbons from three lignocellulosic precursors10.1016/j.jaap.2016.06.018 ↗
5. Construction of self-sufficient Z-scheme Ag3PW12O40/TiO2 photocatalysts for the improved visible-light-driven photo-degradation of rhodamine B10.1007/s11164-018-3585-8 ↗
6. Effect of calcination condition on the microstructure and pozzolanic activity of calcined coal gangue10.1016/j.minpro.2015.11.008 ↗
7. Adsorption of ciprofloxacin on surface-modified carbon materials10.1016/j.watres.2011.06.008 ↗
8. Waste expanded polystyrene modified with H2SO4/biodegradable chelating agent for reuse: as a highly efficient adsorbent to remove fluoroquinolone antibiotic from water10.1016/j.chemosphere.2021.132619 ↗
9. A binary MOF of iron and copper for treating ciprofloxacin-contaminated waste water by an integrated technique of adsorption and photocatalytic degradation10.1039/D1NJ02880D ↗
10. Multivariate optimization of ciprofloxacin removal by polyvinylpyrrolidone stabilized NZVI/Cu bimetallic particles10.1016/j.cej.2019.02.051 ↗
11. Effect of ligands of functional magnetic MOF-199 composite on thiophene removal from model oil10.1007/s10853-020-05422-8 ↗
12. Two-dimensional lamellar stacked (NH4)0.8V3O7·3.5H2O: a promising material with high dielectric properties and microwave absorption performance10.1016/j.apsusc.2019.145079 ↗
13. Halloysite nanotubes as an effective and recyclable adsorbent for removal of low-concentration antibiotica ciprofloxacin
14. Effective adsorption of Co2+ and Sr2+ ions by 10-tungsten-2-molybdophosphoric acid supported amine modified magnetic SBA-1510.1007/s10967-019-06595-6 ↗
15. First organic-inorganic hybrid nanomaterial constructed from a Keggin-type polyoxometallate and a copper-dithiocarbamate complex: sonochemical synthesis, crystal structure and its adsorption performance for organic dye pollutants10.1016/j.poly.2017.01.036 ↗
16. Preparation of core-shell PW12@TiO2 microspheres and oxidative desulfurization performance10.1039/C9DT00203K ↗
17. Photocatalytic mineralization of hydroperfluorocarboxylic acids with heteropolyacid H4SiW12O40 in water10.1016/j.chemosphere.2010.11.038 ↗
18. Recognition of typical antibiotic residues in environmental media related to groundwater in China (2009-2019)10.1016/j.jhazmat.2020.122813 ↗
19. Adsorption and reaction pathways of 1H-pyrazole on Cu(100) and O/Cu(100)10.1021/acs.jpcc.8b00042 ↗
20. Catalytic selective oxidation of isobutane to methacrylic acid on supported (NH4)3HPMo11VO40 catalysts10.1016/j.jcat.2013.09.014 ↗
21. Heterogeneous acid catalysis by heteropoly acids: approaches to catalyst deactivation10.1016/j.molcata.2008.11.029 ↗
22. TiO2 nanoparticles assembled on kaolinites with different morphologies for efficient photocatalytic performance10.1038/s41598-018-29563-8 ↗
23. Waste control by waste: Fenton-like oxidation of phenol over Cu modified ZSM-5 from coal gangue10.1016/j.scitotenv.2019.05.242 ↗
24. Heterogeneous electrocatalytic degradation of ciprofloxacin by ternary Ce3ZrFe4O14-x/CF composite cathode10.1016/j.cattod.2018.05.043 ↗
25. Cu, Ag-containing systems based on coal gangue as catalysts for highly efficient antibiotics removal via persulfate activation under visible light irradiation
26. Strong adsorption properties and mechanism of action with regard to tetracycline adsorption of double-network polyvinyl alcohol-copper alginate gel beads10.1016/j.jhazmat.2021.126863 ↗
27. Adsorption and desorption behaviors of antibiotic ciprofloxacin on functionalized spherical MCM-41 for water treatment10.1016/j.jclepro.2020.121644 ↗
28. Pb(II), Cu(II) and Cd(II) removal using a humic substance-based double network hydrogel in individual and multicomponent systems10.1039/C8TA07250G ↗
29. Experimental and theoretical aspects of biochar-supported nanoscale zero-valent iron activating H2O2 for ciprofloxacin removal from aqueous solution10.1016/j.jhazmat.2019.120848 ↗
30. One-pot synthesis of ZnO nanoparticles supported on halloysite nanotubes for catalytic applications10.1016/j.clay.2020.105527 ↗
31. Effective removal of ciprofloxacin from aqueous solutions using magnetic metal-organic framework sorbents: mechanisms, isotherms and kinetics10.1007/s13738-016-0878-y ↗
32. The extra-large calixarene-based MOFs-derived hierarchical composites for photocatalysis of dye: facile syntheses and contribution of carbon species10.1016/j.jallcom.2021.163178 ↗
33. Urethanes PDMS-based: functional hybrid coatings for metallic dental implants10.1016/j.apsusc.2019.04.058 ↗
34. Interaction of engineered nanomaterials with hydrophobic organic pollutants10.1088/0957-4484/27/28/284003 ↗
35. Ciprofloxacin-induced immune-mediated thrombocytopenia: no cross-reactivity with gemifloxacin10.1111/jcpt.12596 ↗
36. Transesterification between dimethyl carbonate and phenol in the presence of (NH4)8Mo10O34 as a catalyst precursor10.1016/j.apcata.2009.03.029 ↗
37. Immobilization Na7PW11O39 on quanternary ammonium functionalized chloromethylated polystyrene by electrostatic interactions: an efficient recyclable catalyst for alcohol oxidation10.1016/j.apcata.2016.03.034 ↗
38. Halloysite nanotube@carbon with rich carboxyl groups as a multifunctional adsorbent for the efficient removal of cationic Pb(II), anionic Cr(VI) and methylene blue (MB)10.1039/C8EN00561C ↗
39. Carbon composite lignin-based adsorbents for the adsorption of dyes10.1016/j.chemosphere.2018.04.183 ↗
40. Core-shell TiO2@C ultralong nanotubes with enhanced adsorption of antibiotics10.1039/C9TA06735C ↗
41. Heteropolyacid supported on Zr-Beta zeolite as an active catalyst for one-pot transformation of furfural to γ-valerolactone10.1016/j.apcatb.2018.09.031 ↗
42. Adsorption and intercalation of ciprofloxacin on montmorillonite10.1016/j.clay.2010.08.001 ↗
43. Photodegradation of ciprofloxacin adsorbed in the intracrystalline space of montmorillonite10.1016/j.jhazmat.2018.07.041 ↗
44. Thermal decomposition of selected coal gangue10.1007/s10973-017-6687-4 ↗
45. Adsorption characteristics of ciprofloxacin onto g-MoS2 coated biochar nanocomposites10.1007/s11783-019-1218-0 ↗
46. Pt modulates the electronic structure of Pd to improve the performance of Pd-based catalytic combustion catalyst10.1016/j.ijhydene.2021.03.028 ↗
47. Enhanced driving force and charge separation efficiency of protonated g-C3N4 for photocatalytic O2 evolution10.1021/acscatal.5b02185 ↗
48. Amorphous TiO2-supported Keggin-type ionic liquid catalyst catalytic oxidation of dibenzothiophene in diesel10.1007/s12182-018-0268-4 ↗
49. Intrinsic peroxidase-like activity and enhanced photo-Fenton reactivity of iron-substituted polyoxometallate nanostructures10.1039/C8DT01146J ↗
50. Multi- and unilamellar liposomal encapsulation of ciprofloxacin as ways to modify its phototoxicity and photodegradation10.1016/j.ejps.2019.01.006 ↗
51. Ciprofloxacin derivatives and their antibacterial activities10.1016/j.ejmech.2018.01.078 ↗
52. Performance of NOx capture with Dawson polyoxometalate H6P2W18O62·28H2O10.1016/j.cej.2020.125880 ↗
53. Insight to unprecedented catalytic activity of double-nitrogen defective metal-free catalyst: key role of coal gangue10.1016/j.apcatb.2019.118316 ↗
54. Indium oxide/halloysite composite as highly efficient adsorbent for tetracycline removal: key roles of hydroxyl groups and interfacial interaction10.1016/j.apsusc.2021.150708 ↗
55. A novel and green strategy for efficient removing Cr(VI) by modified kaolinite-rich coal gangue10.1016/j.clay.2021.106208 ↗
56. Quantifying the fate and risk assessment of different antibiotics during wastewater treatment using a Monte Carlo simulation10.1016/j.jclepro.2017.09.065 ↗
57. Unprecedented catalytic activity of coal gangue toward environmental remediation: key role of hydroxyl groups10.1016/j.cej.2019.122432 ↗
58. Transformation behavior of mineral composition and trace elements during coal gangue combustion10.1016/j.fuel.2012.02.027 ↗