Efficient removal of fluoroquinolones antibiotics by using kaolin-tannic acid-Fe(III) composite adsorbents from water
Source abstract
Abstract
In this work, a series of novel composite adsorbents (k-TAFe) was designed and fabricated through a one-step method, that is, the chelation crosslinking of tannic acid, kaolin particles and different contents of Fe(III). k-TAFe had a high efficiency in adsorption of various fluoroquinolones antibiotics (FQs) from water. The detailed performance of k-TAFe in FQs adsorption, including the influences of Fe(III) content, solution pH, inorganic and organic additives, adsorption time and FQs` concentration, has been investigated systematically using ofloxacin (OFL), one of popular FQs, as an example. The maximal OFL uptake of k-TAFe was 0.405 mmol/g at an initial pH of 6.0. On the basis of the analysis of the x-ray photoelectron and fourier transform-infrared spectra before and after adsorption, the comparison in the apparent performance of k-TAFe in adsorption of seven FQs with similar structures and their two sub-structural analogs, and theoretical calculation, multiple adsorption mechanisms, including chelating effect, hydrogen bonding, electrostatic attraction, and π-π electron–donor–acceptor interactions, were involved and discussed in detail. Among them, chelating effect due to Fe(III) played a key role in OFL adsorption, and the addition of kaolin particles synergistically enhanced Fe(III) fixed on the composite adsorbents, increased the Fe(III) contents, and caused an improved OFL uptake of k-TAFe. Because of the evident advantages of environmental-friendliness, high adsorption performance and low cost, k-TAFe as an efficient adsorbent has notable application potentials in removal of FQs from water.
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Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Covalent Organic Framework Applications · Analytical chemistry methods development
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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