The clay mineral modifier as the key to steer the properties of rubber nanocomposites
Source abstract
Abstract
An innovative organoclay containing polybutadiene chains was prepared in order to make rubber nanocomposites based on natural rubber or styrene-butadiene copolymer. It was obtained by reacting a maleinised polybutadiene oligomer with the single bond CH2CH2OH moieties present in the ammonium cation of a commercially available organoclay (Cloisite 30B). Elastomeric nanocomposites were also prepared with a reference organoclay, formed by intercalation during mixing with dialkyl dimethylammonium chloride. Sulphur cured nanocomposites were characterised in terms of curing kinetics, morphology, tensile and dynamic-mechanical properties; chemical interactions between the modifier of the new organoclay and the matrices can be inferred by experimental evidences.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Polymer Nanocomposites and Properties · biodegradable polymer synthesis and properties · Polymer crystallization and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (24)
Show source-provided references
1. Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials10.1016/S0927-796X(00)00012-7 ↗
2. Organo-montmorillonite as substitute of carbon black in natural rubber compounds10.1016/S0032-3861(03)00090-9 ↗
3. Synthesis, characterisation and properties of clay mineral and silica based rubber nanocomposites10.1179/174328406X101265 ↗
4. Clay-based Polymer nanocomposites (CPN), in CMS workshop lectures series
5. A critical appraisal of polymer-clay nanocomposites10.1039/B702653F ↗
6. Exfoliated/intercalated rubber/organo-montmorillonite nanocomposites: preparation and characterization10.1002/mame.200900147 ↗
7. 2011
8. Clay delamination in hydrocarbon rubbers10.1021/cm062782m ↗
9. Formation of clay intercalates with organic bilayers in hydrocarbon polymers10.1002/pat.1287 ↗
10. Reinforcement of diene elastomers by organically modified layered silicates
11. Control of organoclay structure in hydrocarbon polymers10.1002/pat.1757 ↗
12. Reinforcement of diene elastomers by organically modified layered silicates
13. Morphology of rubber clay nanocomposites
14. Polymer-silicate nanocomposites: model systems for confined polymers and polymer brushes10.1007/3-540-69711-X_3 ↗
15. Chemistry of rubber/organoclay nanocomposites
16. Organically modified layered silicates as reinforcing fillers for natural rubber10.1021/cm020093e ↗
17. Thermoset rubber/layered silicate nanocomposites. Status and future trends10.1002/pen.20101 ↗
18. Preparation and characterization of organoclay nanocomposites based on natural rubber10.1002/pi.1161 ↗
19. Elastomer nanocomposites10.5254/1.3548215 ↗
20. Preparation and characterization of UV-cured epoxy nanocomposites based on o-montmorillonite modified with maleinized liquid polybutadienes10.1016/j.polymer.2007.10.008 ↗
21. Biodegradable polymers and their layered silicate nanocomposites: in greening the 21st century materials world10.1016/j.pmatsci.2005.05.002 ↗
22. Polymer/layered silicate nanocomposites: a review from preparation to processing10.1016/j.progpolymsci.2003.08.002 ↗
23. A short review on rubber/clay nanocomposites with emphasis on mechanical properties10.1002/pen.20921 ↗
24. Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs)10.1002/pat.852 ↗