journal article·2022-10

Investigation on guanidine phosphate modified LDH and its flame-retardant mechanism in cellulosic composites

Kecan Zhang, Jing Li, Liang He, Qingqing Guan, Ximeng Xu, Rongrong Miao, Minli Wang, Huajing Zhou

Publisher page

Abstract

Layered double hydroxides (LDH) was proved as preferable retardants for lignocellulosic materials. In this study, Mg/Al-LDH was selected and one-step modified by GP which exhibited superior characteristics of flame retardancy and non-toxicity. Results showed that more complete two-dimensional layered structure with suitable crystal particle size was formed for GP modified LDH. Specifically, GP 3 -LDH not only enhanced the thermal stability of cellulosic composites, but also assisted the peak heat release rate (PHRR) and total heat release (THR) in declining 42.5% and 22.7% compared with those added with non-modified Mg/Al-LDH. In addition, the limiting oxygen index (LOI) achieved as high as 27.7% with 15 wt% addition, indicating the successful modification with GP for outstanding flame-retardant performance, low addition and controlled strength of cellulosic composites.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Flame retardant materials and properties · Layered Double Hydroxides Synthesis and Applications · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Improving the flame-retardant efficiency of layered double hydroxide with disodium phenylphosphate for epoxy resin10.1007/s10973-019-08372-9 ↗
2. Process for coating of reconstituted tobacco sheet with citrates10.1016/j.jaap.2015.05.013 ↗
3. Fabrication of hydrotalcite containing N/P/S and its ternary synergistic efficiency on thermostability and fire resistance of ethylene vinyl acetate (EVA)10.1002/vnl.21684 ↗
4. Flame retardant, heat insulating cellulose aerogels from waste cotton fabrics by in situ formation of magnesium hydroxide nanoparticles in cellulose gel nanostructures10.1021/acssuschemeng.5b00438 ↗
5. Phosphorus-containing organic-inorganic hybrid nanoparticles for the smoke suppression and flame retardancy of thermoplastic polyurethane10.1016/j.polymdegradstab.2020.109179 ↗
6. Intercalation of organic and inorganic anions into layered double hydroxides for polymer flame retardancy10.1016/j.clay.2020.105481 ↗
7. Preparation of flame retardant paper with multiple-element layered double hydroxides (LDHs) as flame retardants
8. Highly efficient composite flame retardants for improving the flame retardancy, thermal stability, smoke suppression, and mechanical properties of EVA10.3390/ma13051251 ↗
9. A flame-retardant DOPO-MgAl-LDH was prepared and applied in poly (methyl methacrylate) resin10.1002/pat.4748 ↗
10. Morphology, thermal stability, and flammability properties of polymer-layered double hydroxide (LDH) nanocomposites: a review10.3390/cryst10070612 ↗
11. Polypropylene/layered double hydroxide nanocomposites: influence of LDH intralayer metal constituents on the properties of polypropylene10.1021/acsomega.6b00485 ↗
12. Sustainable glass foams produced from glass bottles and tobacco residue10.1590/1980-5373-mr-2018-0452 ↗
13. Nanofibrillated cellulose from tobacco industry wastes10.1016/j.carbpol.2016.04.045 ↗
14. Synthesis and application of layered doubled hydroxides
15. Study on Mg-Al hydrotalcites in flame-retardant paper preparation10.15376/biores.7.1.997-1007 ↗
16. Thermal analysis and flame-retarded mechanism of composites composed of ethylene vinyl acetate and layered double hydroxides containing transition metals (Mn, Co, Cu, Zn)10.3390/app6050131 ↗
17. Properties and mechanisms of different guanidine flame retardant wood pulp paper10.1016/j.jaap.2017.10.007 ↗
18. Acid-base synergistic flame retardant wood pulp paper with high thermal stability10.1016/j.carbpol.2017.08.099 ↗
19. Modification and compounding of camgal-layered double hydroxides and their application in the flame retardance of acrylonitrile-butadiene-styrene resin10.3390/polym11101623 ↗
20. Effect of modified hydrotalcites on flame retardancy and physical properties of paper10.15376/biores.14.2.3991-4005 ↗
21. TEMPO-oxidized cellulose nanofibril/layered double hydroxide nanocomposite films with improved hydrophobicity, flame retardancy and mechanical properties10.1016/j.compscitech.2018.12.019 ↗
22. Highly efficient flame-retardant kraft paper10.1007/s10853-018-2911-2 ↗
23. Effect of P3O105− intercalated hydrotalcite on the flame retardant properties and the degradation mechanism of a novel polypropylene/hydrotalcite system10.1016/j.clay.2018.07.024 ↗
24. Surface modification of phosphorus-containing hydrotalcite using rare-earth coupling agent and its application in polypropylene10.1016/j.powtec.2018.10.033 ↗
25. Fabrication of green alginate-based and layered double hydroxides flame retardant for enhancing the fire retardancy properties of polypropylene10.1016/j.carbpol.2020.115891 ↗
26. The effect of ammonium polyphosphate on the mechanism of phosphorous-containing hydrotalcite synergism of flame retardation of polypropylene10.1016/j.clay.2019.105348 ↗
27. Intercalation of a novel containing nitrogen and sulfur anion into hydrotalcite and its highly efficient flame retardant performance for polypropylene10.1016/j.clay.2020.105600 ↗
28. Structural modifications of sugarcane bagasse lignins during wet-storage and soda-oxygen pulping10.1021/acssuschemeng.6b00726 ↗
29. Mechanically robust, flame-retardant and anti-bacterial nanocomposite films comprised of cellulose nanofibrils and magnesium hydroxide nanoplatelets in a regenerated cellulose matrix10.1007/s10570-014-0255-x ↗
30. In situ synthesis of layered double hydroxides-silicon dioxide hybrids and its flame retardancy in EVA composites10.1007/s10973-018-7331-7 ↗