journal article·2014-02Open access

Promoting effect of cerium on the characteristic and catalytic activity of Al, Zr, and Al–Zr pillared clay

S. Mnasri-Ghnimi, N. Frini-Srasra

Applied Clay Science· Volume 88-89

Abstract

A series of pillared interlayered clays (PILCs) including Al-, Zr- and Al–Zr-PILC have been prepared and characterized by X-ray diffraction, elemental analyses, N2 adsorption, cationic exchange capacity and IR measurements after n-butylamine adsorption. Cerium introduced in the Zr4 + and/or Al3 + intercalated solution allows for an improvement of the stability and crystallinity of PILC and creates pillared clays with new properties. The resulting materials were used for the synthesis of 1,3-dioxolane. The addition of cerium has a major influence in this reaction.
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OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Mesoporous Materials and Catalysis · Zeolite Catalysis and Synthesis

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