Efficient poly(methyl-ether-imide)/LDH nanocomposite derived from a methyl rich bisphenol: From synthesis to properties
Source abstract
Abstract
Abstract New poly(methyl-ether-imide)/layered double hydroxide (LDH) nanocomposites were successfully fabricated through solution intercalation technique. For this purpose a methyl rich bisphenol was synthesized and used as starting material to produce a new diamine with an ether linkage and then was used to synthesis a new poly(methyl-ether-imide) (PMEI). The produced polymer was fully characterized using various techniques. The Effects of the one step synthesized organo-modified Mg–Al LDH on the thermal, combustion and mechanical properties of PMEI/Mg–Al LDH nanocomposites were studied. Microscopic investigations revealed that the corresponding nanocomposites exhibited exfoliated and/or intercalated morphology. Thermogravimetric analysis results in both nitrogen and air atmospheres indicated that thermal stability of the developed nanocomposites was improved as compared to the neat PMEI. Microscale combustion calorimetry revealed that the synthesized PMEI had low flammability and Mg–Al LDH inclusion could further improve its combustion properties. Tensile strength of PMEI filled with 4 mass% of LDH was increased from 54 to 58 MPa as compare to the neat PMEI.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Synthesis and properties of polymers · Flame retardant materials and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. Studies on thermal and mechanical properties of polyimide–clay nanocomposites10.1016/S0032-3861(00)00824-7 ↗
2. Improved breakdown strength and energy density in thin-film polyimide nanocomposites with small barium strontium titanate nanocrystal fillers10.1021/jp312519r ↗
3. Synthesis and characterisation of new polyamides containing 6,6′-oxy or 6,6′-carbonyldiquinoline units10.1016/S0032-3861(00)00752-7 ↗
4. Cassidy · 1980
5. Costa · 2008 · 101
6. Fluorinated high-performance polymers: poly(arylene ether)s and aromatic polyimides containing trifluoromethyl groups10.1016/j.progpolymsci.2010.04.003 ↗
7. Synthesis and characterization of polyimide–silver nanocomposite containing chalcone moieties in the main chain by UV radiation10.1177/0892705711401845 ↗
8. In situ preparation of nano ZnO/hyperbranched polyimide hybrid film and their optical properties10.1016/j.polymer.2010.05.019 ↗
9. Synthesis of poly(ether ether ketone)-block-polyimide copolymer and its compatibilization for poly(ether ether ketone)/thermoplastic polyimide blends10.1016/j.polymer.2013.11.022 ↗
10. Zn–Al LDH reinforced nanocomposites based on new polyamide containing imide group: from synthesis to properties10.1016/j.clay.2015.06.008 ↗
11. Development of one-step synthesized LDH reinforced multifunctional poly(amide-imide) matrix containing xanthene rings: study on thermal stability and flame retardancy10.1039/C5RA05565B ↗
12. Poly(aryl ethers) by nucleophilic aromatic substitution. II. Thermal stability10.1002/pol.1967.150050917 ↗
13. Preparation and properties of LDHs/polyimide nanocomposites10.1016/S0032-3861(02)00887-X ↗
14. Poly(aryl ethers) by nucleophilic aromatic substitution. I. Synthesis and properties10.1002/pol.1967.150050916 ↗
15. Polymer/layered silicate (clay) nanocomposites: an overview of flame retardancy10.1016/j.progpolymsci.2010.03.001 ↗
16. Synthesis and characterization of polyurethane/Mg–Al layered double hydroxide nanocomposites10.1002/app.30791 ↗
17. On the nature of polyimide–clay hybrid composites10.1021/cm00041a002 ↗
18. Polymer interleaved layered double hydroxide: a new emerging class of nanocomposites10.1021/cm0110268 ↗
19. Liquid crystal alignment by polyhedral oligomeric silsesquioxane (POSS)–polyimide nanocomposites10.1016/j.optmat.2013.02.011 ↗
20. Sulfonated naphthalenic polyimides containing ether and ketone linkages as polymer electrolyte membranes10.1016/j.memsci.2010.09.027 ↗
21. Comparative study on the flammability of polyethylene modified with commercial fire retardants and a zinc aluminum oleate layered double hydroxide10.1016/j.polymdegradstab.2009.02.004 ↗
22. Polymer nanocomposites using zinc aluminum and magnesium aluminum oleate layered double hydroxides: effects of LDH divalent metals on dispersion, thermal, mechanical and fire performance in various polymers10.1016/j.polymer.2009.06.014 ↗
23. pTSA-catalyzed condensation of xylenols and aldehydes under solvent-free conditions: one-pot synthesis of 9H-xanthene or bisphenol derivatives10.1016/j.crci.2013.03.008 ↗
24. Effect of MgAl-layered double hydroxide exchanged with linear alkyl carboxylates on fire-retardancy of PMMA and PS10.1039/b806531d ↗
25. Polymer nanotechnology: nanocomposites10.1016/j.polymer.2008.04.017 ↗
26. Structure–property relationships of nanocomposites based on polypropylene and layered double hydroxides10.1021/ma200323k ↗
27. Arrangement of layered double hydroxide in a polyethylene matrix studied by a combination of complementary methods10.1016/j.polymer.2012.03.041 ↗
28. Novel nanocomposites consisting of a semi-crystalline polyamide and Mg–Al LDH: morphology, thermal properties and flame retardancy10.1016/j.clay.2013.12.033 ↗
29. New poly(ether-imide)/MWCNT nanocomposite10.1007/s10973-014-3682-x ↗
30. Bio-based semi-aromatic polyamide/functional clay nanocomposites: preparation and properties10.1039/c4ra02949f ↗
31. Effect of clay modifier on morphology, thermal properties and flammability of newly synthesized poly (sulfide–sulfone–amide)10.1016/j.clay.2015.02.020 ↗
32. Ethylene vinyl acetate/layered silicate nanocomposites prepared by a surfactant-free method: enhanced flame retardant and mechanical properties10.1016/j.polymer.2009.06.013 ↗
33. Polymer nanocomposites with prescribed morphology: going beyond nanoparticle-filled polymers10.1021/cm062693+ ↗
34. Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets10.1021/cr200434v ↗
35. One-step synthesis of organic LDH and its comparison with regeneration and anion exchange method10.1021/cm901238a ↗
36. Preparation and investigation of the combustion behavior of polypropylene/organomodified MgAl-LDH micro-nanocomposite10.1016/j.jallcom.2010.12.138 ↗
37. Structural characteristics and flammability of fire retarding EPDM/layered double hydroxide (LDH) nanocomposites10.1039/c2ra20189e ↗
38. Effect of polyaniline-modified clay on the processing and properties of clay polyimide nanocomposites10.1016/j.clay.2014.06.036 ↗
39. Synthesis and properties of polyimide–clay hybrid10.1002/pola.1993.080311009 ↗
40. Synthesis and properties of polyimide–clay hybrid films10.1002/(SICI)1099-0518(199708)35:11<2289::AID-POLA20>3.0.CO;2-9 ↗
41. Investigating the structure–property relationship of aromatic–aliphatic polyamide/layered silicate hybrid films10.1016/j.solidstatesciences.2009.03.014 ↗