Assessment of technological properties of calcareous and non-calcareous clays used for the brick-making industry of Zaragoza (Spain)

The granulometric, mineralogical, and geochemical features of two different types of clayey raw materials (carbonated clays, CC; and non-carbonated clays, NCC) used for the brickmaking industry near Zaragoza (Spain) have been studied. Their particle-size distribution suggests that they may be classified as silty clays and are suitable for use as thin-walled hollow bricks. For technological testing, prismatic bars obtained by extrusion under vacuum conditions from raw materials were fired from 800 to 1050 °C. Technological determinations, such as linear shrinkage, bulk density, hydric tests, and an accelerated decay test, indicate that both CC and NCC are suitable to be used as bricks for building, although bricks made of NCC would be of better quality. In addition, pore-size distribution suggests that the durability of the highest temperature fired products will be higher because of an increase both in the dominant pore access radius and in the percentage of larger pore sizes.