journal article·2018-09

Vermiculite as a potential component of the engineered barriers in low- and medium-level radioactive waste repositories

L. Fuks, I. Herdzik-Koniecko

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Abstract

Abstract Vermiculite (VMT) was tested as a low-cost, eco-friendly adsorbent for the removal of cesium(I), strontium(II), europium(III), americium(III), and technetium(VII) radionuclides from aqueous solutions. The raw material was characterized and checked as potential adsorbent. The removal efficiency (Er, %) was studied as a function of the main factors important for the management of radioactive liquid wastes. It was found that the uptake from the aqueous solutions simulating the radioactive liquid wastes was in the order: Cs(I) Sr(II) (both about 95%) > Am(III) (about 90%) > Eu(III) (about 80%). When a reducing agent is added to the solution technetium-99 may also be completely removed. The usefulness of VMT in liquid low level radioactive waste management has also been confirmed by checking its radiation stability. Vermiculite can be considered as a promising material for sorption of the radionuclides from radioactive waste solutions and as a potential additive to the engineered barriers in LLRW repositories.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Radioactive element chemistry and processing · Chemical Synthesis and Characterization · Nuclear materials and radiation effects

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (54)

Show source-provided references
1. Web 1
2. Adsorption process of heavy metals by low-cost adsorbent: a review
3. Removal of fulvic acid from aqueous media by adsorption onto modified vermiculite10.1016/j.clay.2006.02.004 ↗
4. Sorption characteristics of materials of the filtration barrier in upper aquifers contaminated with radionuclides10.1134/S1066362217040154 ↗
5. ASTM · 2004
6. Mycoextraction of radiolabeled cesium and strontium by Pleurotus eryngii mycelia in the presence of alumina nanoparticles: sorption and accumulation studies10.1016/j.jenvrad.2016.07.020 ↗
7. Bergaya · 2006 · Vol. 1
8. Volumen und Hydratationswarme der Ionen10.1007/BF01881023 ↗
9. A novel technique for the removal of strontium from water using thermophilic bacteria in a membrane reactor10.1016/j.jiec.2014.04.018 ↗
10. Removal of strontium from aqueous solutions by adsorption onto activated carbon: kinetic and thermodynamic studies10.1016/j.desal.2008.01.018 ↗
11. Acid-activated vermiculites and phlogophites as catalysts for the DeNOx process10.1016/j.clay.2010.04.020 ↗
12. Combined radioactive liquid waste treatment processes involving inorganic sorbents and micro/ultrafiltration
13. Immobilization of cesium and strontium radionuclides in zeolite-cement blends10.1016/j.jhazmat.2005.12.020 ↗
14. Ammonium-potassium-calcium exchange on vermiculite and Hydroxy-aluminum vermiculite10.2136/sssaj2002.4450 ↗
15. Removal of the radionuclides from aqueous solutions by biosorption on the roots of the dandelion (Taraxacum officinale)10.1007/s13762-016-1067-3 ↗
16. Characterizations of strontium(II) and barium(II) adsorption from aqueous solutions using dolomite powder10.1016/j.jhazmat.2011.04.006 ↗
17. How do we define the concepts specific activity, radioactive concentration, carrier, carrier-free and no-carrier-added?10.1007/s10967-005-0004-6 ↗
18. Local minerals for engineering barriers for the national radioactive waste repository (NRWR): sorption of U(VI), Am(III), Sr(II) and Cs(I) ions on red clay
19. Adsorption of metal ions by clays and inorganic solids10.1039/C4RA03673E ↗
20. Chemical activation of vermiculite to produce highly efficientmaterial for Pb2+ and Cd2+ removal10.1016/j.clay.2015.07.042 ↗
21. Mechanochemical treatment of vermiculite in vibration milling and its effect on lead (II) adsorption ability10.1016/j.clay.2012.09.016 ↗
22. Effect of precipitation and complexation on nanofiltration of strontiumcontaining nuclear wastewater10.1016/S0011-9164(02)00554-4 ↗
23. Use of inorganic sorbents for treatment of liquid radioactive waste and backfill of underground repositories
24. Combined methods for liquid radioactive waste treatment. Final report of a coordinated research project 19972001
25. Removal of strontium ions from simulated radioactive wastewater by vacuum membrane distillation10.1016/j.anucene.2017.02.003 ↗
26. Kerrisk · 1985
27. Modeling the adsorption of Cd(II) onto goethite in the presence of citric acid10.1016/j.jcis.2003.08.041 ↗
28. Competitive adsorption of Ag+, Pb2+, Ni2+, and Cd2+ ions on vermiculite10.1080/01496390903255572 ↗
29. Programmed gradient descent biosorption of strontium ions by Saccaromyces cerevisiae and ashing analysis: a decrement solution for nuclide and heavy metal disposal10.1016/j.jhazmat.2016.04.049 ↗
30. Efficient removal of cesium from aqueous solution with vermiculite of enhanced adsorption property through surface modification by ethylamine10.1016/j.jcis.2014.05.001 ↗
31. Near-infrared spectroscopy: a powerful tool in studies of acid-treated clay minerals10.1016/j.vibspec.2008.08.001 ↗
32. Photocatalytic reduction of Cs(I) ions removed by combined maghemite-titania PVA-alginate beads from aqueous solution10.1016/j.jenvman.2017.01.019 ↗
33. Adsorption of heavy metals on vermiculite: influence of pH and organic ligands10.1016/j.jcis.2006.03.011 ↗
34. Cobalt and strontium sorption by moss biosorbent: modeling of single and binary metal systems10.1016/j.desal.2010.08.014 ↗
35. Adsorption-desorption of heavy metal ions
36. Cs+ and Sr2+ adsorption selectivity of zeolites in relation to radioactive decontamination10.1016/j.jascer.2015.04.002 ↗
37. Recovery of scandium from sulfation-roasted leachates of bauxite residue by solvent extraction with the ionic liquid betainium bis(trifluoromethylsulfonyl)imide10.1016/j.seppur.2016.12.009 ↗
38. Polish National Atomic Energy Agency · 2017
39. Experimental design investigation for vermiculite modification: intercalation reaction and application for dye removal10.1016/j.clay.2016.02.031 ↗
40. Vibrational spectroscopy of acid treated vermiculites10.1016/j.vibspec.2013.11.007 ↗
41. Roy · 1992
42. Selectivity of similar compounds' identification using IR spectrometry: β-lactam antibiotics10.1016/j.molstruc.2005.12.054 ↗
43. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
44. Experimental design approach in the synthesis of hydroxyapatite by neutralization method10.1016/j.seppur.2004.12.010 ↗
45. Preparation of porous silica from vermiculite by selective leaching
46. The Vermiculite Association
47. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade10.1016/j.cej.2016.09.029 ↗
48. Modeling adsorption-desorption processes of cu on edge and planar sites of montmorillonit10.1021/es011154x ↗
49. Studies on the acid activation of Brazilian smectitic clays
50. Sodium cobalt hexacyanoferrate encapsulated in alginate vesicle with CNT for both cesium and strontium removal10.1016/j.carbpol.2014.04.037 ↗
51. Treatment of molten salt wastes by phosphate precipitation: removal of fission product elements after pyrochemical reprocessing of spent nuclear fuels in chloride melts10.1016/j.jnucmat.2003.08.024 ↗
52. World Health Organization · 2006 · Vol. 1
53. Synthesis and characterization of disordered layered silica obtained by selective leaching of octahedral sheets from chrysotile and phlogopite structures10.1016/j.jcis.2004.08.139 ↗
54. Removal of strontium(II) and cobalt(II) from acidic solution by manganese antimonate10.1016/j.cej.2016.05.040 ↗