journal article·2018-01

Competitive adsorption of Cu (II) and Zn (II) on impregnate raw Algerian bentonite and efficiency of extraction

Djamila Bouazza, Hafida Miloudi, Mehdi Adjdir, Abdelkader Tayeb, Anne Boos

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Abstract

Abstract Impregnated homoionic raw Algerian bentonite (HB) with high basal spacing was prepared to remove a copper (Cu2 +) and zinc (Zn2 +) from 0.33 M (Na+, H+)SO42 − sulphate medium in aqueous solutions. The impregnated solid was characterized by X-ray diffraction (XRD), Fourier- Transform Infrared (FTIR) and Ultra-violet (UV). The effect of contact time, initial pH of a solution, heavy metal concentration and ligand concentration on the adsorption efficiency were investigated. Pseudo-first/s orders isotherms are applied to determine the efficiency of impregnate solid. The experimental data fitted well with the pseudo-second order model for Cu2 + and Zn2 + adsorption. Maximum capacities for Cu2 + and Zn2 + were 440 mmol/kg and 32 mmol/kg respectively. However, the adsorption is selective to copper in binary system. Moreover, impregnated solid was also regenerated and reused for subsequent recovery.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Clay minerals and soil interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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