Thermal stability and decomposition kinetics of styrene-butadiene rubber nanocomposites filled with different particle sized kaolinites
Source abstract
Abstract
Abstract A series of styrene-butadiene rubber (SBR) nanocomposites filled with different particle sized kaolinites are prepared via a latex blending method. The thermal stabilities of these clay polymer nanocomposites (CPN) are characterized by a range of techniques including thermogravimetry (TG), digital photos, scanning electron microscopy (SEM) and Raman spectroscopy. These CPN show some remarkable improvement in thermal stability compared to that of the pure SBR. With the increase of kaolinite particle size, the residual char content and the average activation energy of kaolinite SBR nanocomposites all decrease; the pyrolysis residues become porous; the crystal carbon in the pyrolysis residues decrease significantly from 58.23% to 44.41%. The above results prove that the increase of kaolinite particle size is not beneficial in improving the thermal stability of kaolinite SBR nanocomposites.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Polymer Nanocomposites and Properties · Polymer crystallization and properties · Thermal and Kinetic Analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. Organophilic clay minerals
2. Introduction to clay–polymer nanocomposites (CPN)
3. Covalent grafting of pyridine-2-methanol into kaolinite layers10.1016/j.molstruc.2012.08.004 ↗
4. Thermooxidative degradation of natural rubber/clay composite10.1002/app.23808 ↗
5. Thermal degradation behavior of hydrogenated nitrile-butadiene rubber (HNBR)/clay nanocomposite and HNBR/clay/carbon nanotubes nanocomposites10.1016/j.tca.2009.03.010 ↗
6. Thermogravimetric analysis of selected coal-bearing strata kaolinite10.1016/j.tca.2010.05.004 ↗
7. Permeability of polymer/clay nanocomposites: a review10.1016/j.eurpolymj.2009.01.027 ↗
8. Two-dimensional nanosheets produced by liquid exfoliation of layered materials10.1126/science.1194975 ↗
9. Raman microprobe studies on carbon materials10.1016/0008-6223(94)90148-1 ↗
10. Curing and thermal behaviour of diamide–diimide–diamines based on l-phenylalanine with epoxy blends containing phosphorus/silicon10.1007/s10973-011-1722-3 ↗
11. Interpretation of Raman spectra of disordered and amorphous carbon10.1103/PhysRevB.61.14095 ↗
12. A quick, direct method for the determination of activation energy from thermogravimetric data10.1002/pol.1966.110040504 ↗
13. Galimberti · 2011
14. Layered polymer–kaolinite nanocomposites10.1023/A:1004820003253 ↗
15. Flammability and thermal stability studies of polymer layered–silicate (clay) nanocomposites10.1016/S0169-1317(99)00019-8 ↗
16. Preparation and properties of styrene butadiene rubber/natural rubber/organo-bentonite nanocomposites prepared from latex dispersions10.1016/j.clay.2009.08.010 ↗
17. Ozawa's kinetic method for analyzing thermoanalytical curves10.1007/s10973-012-2882-5 ↗
18. Introduction: from clay mineral–polymer interactions to clay mineral–polymer nanocomposites
19. A rheological method for selecting nano-kaolin powder as filler in SBR rubber10.1016/j.partic.2010.03.014 ↗
20. Properties of vulcanized rubber nanocomposites filled with nanokaolin and precipitated silica10.1016/j.clay.2007.12.005 ↗
21. Effect of nanoclay reinforcement on structure, thermal and mechanical properties of natural rubber–styrene butadine rubber (NR–SBR)10.1016/j.jiec.2011.02.019 ↗
22. A new method of analyzing thermogravimetric data10.1246/bcsj.38.1881 ↗
23. Estimation of activation energy by isoconversion methods10.1016/0040-6031(92)85192-X ↗
24. Kinetic analysis of thermal decomposition of polymer using a dynamic model10.1007/BF02707154 ↗
25. A review on polymer-layered silicate nanocomposites10.1016/j.progpolymsci.2008.07.008 ↗
26. Raman spectroscopy for the analysis of coal: a review10.1002/jrs.2636 ↗
27. The non-isothermal kinetic analysis of the thermal decomposition of kaolinite by thermogravimetric analysis10.1016/j.powtec.2010.08.004 ↗
28. The kinetic analysis of the thermal decomposition of kaolinite by DTG technique10.1016/j.powtec.2010.11.035 ↗
29. Thermogravimetric analysis, flammability and oil resistance properties in natural rubber and dichlorocarbene modified styrene butadiene rubber blends10.1016/j.reactfunctpolym.2004.02.005 ↗
30. Raman spectroscopy of graphite10.1098/rsta.2004.1454 ↗
31. Raman microspectroscopy of soot and related carbonaceous materials: spectral analysis and structural information10.1016/j.carbon.2005.02.018 ↗
32. An investigation on the dispersion of montmorillonite (MMT) primary particles in PP matrix10.1016/j.eurpolymj.2007.05.030 ↗
33. Gas transport through nano and micro composites of natural rubber (NR) and their blends with carboxylated styrene butadiene rubber (XSBR) latex membranes10.1016/j.polymer.2005.12.020 ↗
34. Natural rubber-based nanocomposites by latex compounding with layered silicates10.1016/S0032-3861(03)00480-4 ↗
35. Observation of Raman band shifting with excitation wavelength for carbons and graphites10.1016/0038-1098(81)90686-4 ↗
36. Silica–styrene-butadiene rubber filled hybrid composites: experimental characterization and modeling10.1177/0731684409355722 ↗
37. Characterization and thermal behavior of kaolin10.1007/s10973-011-1385-0 ↗
38. Preparation and characterization of epoxy/kaolinite nanocomposites10.1002/app.32421 ↗
39. Mechanical properties of organomodified kaolin/natural rubber vulcanizates10.1016/j.clay.2009.08.018 ↗
40. Gas barrier properties of natural rubber/kaolin composites prepared by melt blending10.1016/j.clay.2010.08.006 ↗
41. Thermal stability of styrene butadiene rubber (SBR) composites filled with kaolinite/silica hybrid filler10.1007/s10973-013-3382-y ↗