journal article·2014-06

Determination of optimum concentration of cloisite in an eco-friendly silane sol-gel film to improve corrosion resistance of mild steel

N. Asadi, R. Naderi, M. Saremi

Publisher page

Abstract

Abstract In this study, the effect of cloisite concentration on the protective performance of an eco-friendly silane sol-gel coating consisting of tetraethoxysilane (TEOS), methyltriethoxysilane (MTES) and glycidyloxypropyltrimethoxysilane (GPS) applied on mild steel substrate was investigated using electrochemical techniques and surface analysis. Through taking advantage of electrochemical impedance spectroscopy, potentiodynamic polarization and electrochemical noise measurements, the optimum concentration of nanoparticles was determined. In the presence of the cloisite content, superiority of the hybrid silane film was connected to the enhanced barrier properties, confirmed by FE-SEM, FTIR and water contact angle studies. Moreover, a good trend correlation was observed between the noise resistance and low-frequency impedance modulus data.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Analytical Chemistry and Sensors · Anodic Oxide Films and Nanostructures

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Study of corrosion protection of mild steel by eco-friendly silane sol-gel coating10.1007/s10971-014-3286-8 ↗
2. Characterization of thin water-based silane pre-treatments on aluminium with the incorporation of nano-dispersed CeO2 particles10.1016/j.surfcoat.2010.07.052 ↗
3. Interpretation of electrochemical noise data10.5006/1.3290350 ↗
4. Statistical evolution of EIS and ENM data collected for monitoring corrosion barrier properties of organic coating on Al-2024-T310.1016/S0010-938X(01)00173-1 ↗
5. Electrochemical investigation of high-performance silane sol-gel films, containing clay nanoparticles10.1016/j.porgcoat.2010.04.007 ↗
6. Preparation of polymer/clay mineral nanocomposites via dispersion of silylated montmorillonite in a UV curable epoxy matrix10.1016/j.clay.2007.12.011 ↗
7. Grundmeier · 2000 · vol. III
8. Correlation between electrochemical impedance and noise measurements of waterborne coatings10.1016/j.corsci.2008.12.011 ↗
9. Characterization and corrosion protection properties of epoxy powder coatings containing nanoclays10.1016/j.porgcoat.2013.01.005 ↗
10. Synergistic effect of silane modified nanocomposites for active corrosion protection10.1016/j.ceramint.2013.03.017 ↗
11. Koleske · 1995
12. New experimental arrangement for the acquisition of electrochemical noise data from high resistance organic anti-corrosive coatings10.1108/00035590210431773 ↗
13. Concerning trend removal in electrochemical noise measurements10.1016/S0010-938X(00)00064-0 ↗
14. Analytical characterization of silane films modified with cerium activated nanoparticles and its relation with the corrosion protection of galvanised steel substrates10.1016/j.porgcoat.2007.11.008 ↗
15. Synergistic effect of clay nano particles and cerium component on the corrosion behavior of eco-friendly silane sol-gel layer applied on pure aluminum10.1016/j.surfcoat.2013.03.005 ↗
16. Optimization of silane sol-gel coatings for the protection of aluminium components of heat exchangers10.1002/sia.5249 ↗
17. Nano particle-filled silane films as chromate replacements for aluminum alloys10.1016/j.porgcoat.2003.08.015 ↗
18. Analysis of hydrolysis process of g-methacryloxypropyltrimethoxysilane and its influence on the formation of silane coatings on 6063 aluminum alloy10.1016/j.apsusc.2009.02.022 ↗
19. Influence of curing temperature, silica nanoparticles and cerium on surface morphology and corrosion behaviour of hybrid silane coatings on mild steel10.1016/j.surfcoat.2009.02.020 ↗
20. The role of zinc phosphate pigment in the corrosion of scratched epoxy-coated steel10.1016/j.corsci.2008.11.015 ↗
21. Influence of silica nanoparticles added to an organosilane film on carbon steel electrochemical and tribological behaviour10.1016/j.porgcoat.2007.07.006 ↗
22. Electrochemical assessment of the self-healing properties of Ce-doped silane solutions for the pre-treatment of galvanised steel substrates10.1016/j.porgcoat.2005.07.006 ↗
23. Replacement of chromates by silanes-an overview
24. Corrosion protection properties of organofunctional silanes -an overview10.1016/S1007-0214(05)70134-6 ↗
25. Investigation of the barrier properties of silanes on cold rolled steel10.1016/j.electacta.2004.01.059 ↗