journal article·2015-08

Organosilane-functionalized halloysite for high performance halloysite/heterophasic ethylene–propylene copolymer nanocomposites

Eveline Bischoff, Tales Daitx, Douglas Alexandre Simon, Henri Stephan Schrekker, Susana Alcira Liberman, Raquel Santos Mauler

Applied Clay Science· Volume 112-113
Publisher page

Abstract

Abstract The surface modification of hydrophilic inorganic clays with organosilanes is a promising strategy to improve its dispersion as filler and interaction with hydrophobic polymers. Successful organomodification strongly depends on the characteristics of the silane precursor (functional group, chain size and concentration) and the reaction conditions (solvent polarity). This study correlates these factors with the morphological, thermal and mechanical properties of the final halloysite/heterophasic ethylene–propylene copolymer nanocomposites. When the halloysite (Hal) silane-modification was conducted in nonpolar solvents, the most efficient filler dispersion was achieved. Additionally, a good balance in the mechanical properties was obtained by using the more hydrophobic silane-modifier, improving the Young modulus in 38%, without loss of the impact properties at 23 °C. These optimized clay polymer nanocomposites exhibit properties suitable for many industrial applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Clay minerals and soil interactions · Therapeutic Uses of Natural Elements · Layered Double Hydroxides Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Morphological structures and tribological performance of unsaturated polyester based untreated/silane-treated halloysite nanotubes10.1016/j.matdes.2012.08.035 ↗
2. Role of silanized halloysite nanotubes on structural, mechanical properties and fracture toughness of thermoset nanocomposites10.1016/j.matdes.2013.12.017 ↗
3. FTIR and zeta potential measurements of sepiolite treated with some organosilanes10.1016/j.micromeso.2005.05.016 ↗
4. Surface modification of natural halloysite clay nanotubes with aminosilanes. Application as catalyst supports in the atom transfer radical polymerization of methyl methacrylate10.1016/j.apcata.2011.08.003 ↗
5. Notched impact behavior of polymer blends: part 1: new model for particle size dependence10.1016/j.polymer.2009.09.059 ↗
6. The effects of silane coupling agents on the properties of PHBV/halloysite nanocomposites10.1016/j.clay.2013.11.032 ↗
7. Organoclays: properties, preparation and applications10.1016/j.clay.2008.02.006 ↗
8. Thermal stability and flame retardant effects of halloysite nanotubes on poly (propylene)10.1016/j.eurpolymj.2005.12.006 ↗
9. Adsorption of ionic liquid onto halloysite nanotubes: mechanism and reinforcement of the modified clay to rubber10.1080/00222341003609823 ↗
10. Effect of clay surface modification and concentration on the tensile performance of clay/epoxy nanocomposites10.1016/j.msea.2006.10.052 ↗
11. Synthesis of organoclays: a critical review and some unresolved issues10.1016/j.clay.2014.02.008 ↗
12. Properties of halloysite nanotubes-filled natural rubber prepared using different mixing methods10.1016/j.matdes.2013.03.038 ↗
13. Oral extended release of dexamethasone: montmorillonite–PLGA nanocomposites as a delivery vehicle10.1016/j.clay.2014.11.028 ↗
14. Effects of organobentonites on imidacloprid release from alginate-based formulation10.1016/j.clay.2014.12.023 ↗
15. Effect of the silane modification of an organoclay on the properties of polypropylene/clay composites10.1002/app.28151 ↗
16. Halloysite clay minerals—a review10.1180/0009855054040180 ↗
17. Water-assisted extrusion as a novel processing route to prepare polypropylene/halloysite nanotube nanocomposites: structure and properties10.1016/j.polymer.2011.07.021 ↗
18. Dendrimer-like assemblies based on organoclays as multi-host system for sustained drug delivery10.1016/j.ejpb.2014.09.014 ↗
19. Natural inorganic nanotubes reinforced epoxy resin nanocomposites10.1007/s10965-007-9160-4 ↗
20. Nanocomposites of halloysite and polylactide10.1016/j.clay.2013.02.019 ↗
21. Recent advance in research on halloysite nanotubes–polymer nanocomposite10.1016/j.progpolymsci.2014.04.004 ↗
22. Elaboration and properties of novel biobased nanocomposites with halloysite nanotubes and thermoplastic polyurethane from dimerized fatty acids10.1016/j.polymer.2014.08.049 ↗
23. Eco-friendly functionalization of natural halloysite clay nanotube with ionic liquids by microwave irradiation for Suzuki coupling reaction10.1016/j.jorganchem.2013.10.044 ↗
24. Aminosilanes grafting on FAU/EMT zeolite: effect on CO2 adsorptive properties10.1016/j.micromeso.2011.03.002 ↗
25. Characterization of organo-modified bentonite sorbents: the effect of modification conditions on adsorption performance10.1016/j.apsusc.2014.09.105 ↗
26. Influence of maleic anhydride grafted ethylene propylene diene monomer (MAH-g-EPDM) on the properties of EPDM nanocomposites reinforced by halloysite nanotubes10.1016/j.polymertesting.2009.04.004 ↗
27. EPDM/modified halloysite nanocomposites10.1016/j.clay.2010.01.015 ↗
28. Characterisation of properties of various halloysites relevant to their use as nanotubes and microfibre fillers10.1016/j.clay.2012.06.014 ↗
29. Development of high performance electroless Ni–P–HNT composite coatings10.1016/j.apsusc.2012.09.020 ↗
30. Optimization of the mechanical properties of polypropylene-based nanocomposite via the addition of a combination of organoclays10.1016/j.compositesa.2009.05.009 ↗
31. Toward efficient nanoporous catalysts: controlling site-isolation and concentration of grafted catalytic sites on nanoporous materials with solvents and colorimetric elucidation of their site-isolation10.1021/ja074128t ↗
32. Silylation of montmorillonite surfaces: dependence on solvent nature10.1016/j.jcis.2012.08.077 ↗
33. Loading and in vitro release of ibuprofen in tubular halloysite10.1016/j.clay.2014.01.018 ↗
34. Influences of processing methods and chemical treatments on fracture toughness of halloysite–epoxy composites10.1016/j.matdes.2012.06.036 ↗
35. Polypropylene–elastomer (TPO) nanocomposites: 1. Morphology10.1016/j.polymer.2011.08.019 ↗
36. Polypropylene-elastomer (TPO) nanocomposites: 2 room temperature Izod impact strength and tensile properties10.1016/j.polymer.2011.10.002 ↗
37. Effects of halloysite nanotube orientation on crystallization and thermal stability of polypropylene nanocomposites10.1016/j.polymdegradstab.2013.06.022 ↗
38. Incorporation of halloysite nanotubes into PVDF matrix: nucleation of electroactive phase accompany with significant reinforcement and dimensional stability improvement10.1016/j.compositesa.2014.07.001 ↗
39. Structure and properties research on montmorillonite modified by flame-retardant dendrimer10.1016/j.clay.2014.01.001 ↗
40. Evaluation on the thermal and mechanical properties of HNT-toughened epoxy/carbon fibre composites10.1016/j.compositesb.2011.05.010 ↗
41. Functionalization of halloysite clay nanotubes by grafting with γ-aminopropyltriethoxysilane10.1021/jp805657t ↗
42. Silane-grafted silica-covered kaolinite as filler of styrene butadiene rubber10.1016/j.clay.2012.04.024 ↗