journal article·2018-12

Assembling polypyrrole coated sepiolite fiber as efficient particle adsorbent for chromium (VI) removal with the feature of convenient recycling

Qi Zhou, Junlong Huang, Xing Zhang, Yun Gao

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Abstract

Abstract To overcome the inherent defect of particle adsorbent that difficult to be recycled from waterbody, a new adsorbent was successfully prepared based on the surface polypyrrole (PPy) functionalized sepiolite fiber (SEP), with properties of magnetism and floatation. This adsorbent can be recovered easily from water surface by a magnet. The resultant MSEP/PPy retains the feature of sepiolite fiber template, along with a large surface area to have more surface adsorption sites. Batch experiment shows the experiment data is in good agreement with the pseudo-second order kinetic and Langmuir isotherm model. The adsorption mechanism reveals that the ion exchange occurs between Cl− and Cr(VI), followed by the reduction of Cr(VI) to Cr(III) via the surface PPy moiety. Additionally, most of the adsorption capacity of the adsorbent can be maintained in the cyclic regeneration, ranging from 87.93 to 58.36 mg/g even in the incomplete desorption.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Clay minerals and soil interactions · Electrochemical sensors and biosensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (60)

Show source-provided references
1. Application of solid phase extraction on multiwalled carbon nanotubes of some heavy metal ions to analysis of skin whitening cosmetics using ICP-AES10.3390/ijerph10010361 ↗
2. Removal of hexavalent chromium with a lignocellulosic substrate extracted from wheat bran10.1021/es0342345 ↗
3. Polypyrrole conducting electroactive polymers: synthesis and stability studies10.1155/2006/860413 ↗
4. Removal of chromium ions from aqueous solutions by polymer-enhanced ultrafiltration10.1016/j.jhazmat.2007.01.120 ↗
5. Cr(VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan10.1016/j.chemosphere.2003.10.001 ↗
6. Removal of Cr (VI) from aqueous solutions using chitosan/MWCNT/Fe3O4 composite nanofibers-batch and column studies10.1016/j.cej.2015.08.158 ↗
7. Removal of fluoride from aqueous solution by polypyrrole/Fe3O4 magnetic nanocomposite10.1016/j.jhazmat.2010.10.098 ↗
8. Enhanced removal of Cr(VI) from aqueous solution using polypyrrole/Fe3O4 magnetic nanocomposite10.1016/j.jhazmat.2011.03.062 ↗
9. Chromium(VI) removal from water using fixed bed column of polypyrrole/Fe3O4 nanocomposite10.1016/j.seppur.2013.02.037 ↗
10. A comparative study between chloride and calcined carbonate hydrotalcites as adsorbents for Cr(VI)10.1016/j.clay.2007.01.006 ↗
11. Sepiolite fiber oriented-polypyrrole nanofibers for efficient chromium(VI) removal from aqueous solution10.1021/je500319a ↗
12. Removal of C.I. Basic Green 4 (Malachite Green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: kinetic and equilibrium studies10.1016/j.seppur.2006.06.018 ↗
13. Organic cation exchanged montmorillonite and vermiculite as adsorbents for Cr(VI): effect of layer charge on adsorption properties10.1016/j.clay.2012.05.004 ↗
14. How can nanohybrids enhance polyester/sepiolite nanocomposite properties?10.1002/macp.200700335 ↗
15. Cr(VI) removal from aqueous solution by activated carbon coated with quaternized poly(4-vinylpyridine)10.1021/es061969b ↗
16. A Feasibility study of polypyrrole/zinc tungstate (ceramics) nano composites for D. C. conductivity and as a humidity sensor10.1016/j.matpr.2018.01.068 ↗
17. Multiwalled carbon nanotubes as adsorbents for the kinetic and equilibrium study of the removal of Alizarin Red S and Morin
18. Enhanced chromium recovery from tanning wastewater10.1016/j.jclepro.2005.01.005 ↗
19. Adsorption of Cr(VI) on STAC-modified rectorite10.1016/j.clay.2008.01.015 ↗
20. Facile synthesis of polypyrrole decorated reduced graphene oxide–Fe3O4 magnetic composites and its application for the Cr(VI) removal10.1016/j.cej.2014.10.020 ↗
21. Fast removal and recovery of Cr(VI) using surface-modified jacobsite (MnFe2O4) nanoparticles10.1021/la051076h ↗
22. Rapid removal of heavy metal cations and anions from aqueous solutions by an amino-functionalized magnetic nano-adsorbent10.1016/j.jhazmat.2008.06.075 ↗
23. Radiolytic synthesis of conducting polypyrrole/carbon nanotube composites10.1016/j.matlet.2006.07.100 ↗
24. Removal of Cr(III) and Cr(VI) ions from aqueous solutions by means of polyelectrolyte-enhanced ultrafiltration10.1016/j.desal.2008.12.036 ↗
25. A novel technology for biosorption and recovery hexavalent chromium in wastewater by bio-functional magnetic beads10.1016/j.biortech.2007.12.002 ↗
26. Preparation of bamboo-like PPy nanotubes and their application for removal of Cr(VI) ions in aqueous solution10.1016/j.jcis.2012.03.065 ↗
27. Preparation of magnetic ionic liquid/chitosan/graphene oxide composite and application for water treatment10.1016/j.ijbiomac.2014.02.031 ↗
28. Hydrothermal carbonization synthesis of a novel montmorillonite supported carbon nanosphere adsorbent for removal of Cr (VI) from waste water10.1016/j.clay.2014.02.015 ↗
29. Effective removal of emulsified oil from oily wastewater using surfactant-modified sepiolite10.1016/j.clay.2018.02.014 ↗
30. Extraction and recycling utilization of metal ions (Cu2+, Co2+ and Ni2+) with magnetic polymer beads10.1016/j.cej.2012.06.074 ↗
31. A study on adsorption of Cr (VI) by modified rice straw: characteristics, performances and mechanism10.1016/j.jclepro.2018.05.279 ↗
32. Adsorption of direct yellow 12 onto ordered mesoporous carbon and activated carbon10.1021/je900391p ↗
33. Effect of pH, ionic strength, and temperature on the phosphate adsorption onto lanthanum-doped activated carbon fiber10.1016/j.jcis.2011.08.067 ↗
34. Nanoscale zero-valent iron (nZVI) assembled on magnetic Fe3O4/graphene for chromium (VI) removal from aqueous solution10.1016/j.jcis.2013.11.044 ↗
35. Magnetic adsorption separation (MAS) process: an alternative method of extracting Cr(VI) from aqueous solution using polypyrrole coated Fe3O4 nanocomposites10.1016/j.seppur.2015.12.021 ↗
36. Removal of trace arsenic to meet drinking water standards using iron oxide coated multiwall carbon nanotubes10.1021/je1010664 ↗
37. Polyethyleneimine (PEI) loaded MgO-SiO2 nanofibers from sepiolite minerals for reusable CO2 capture/release applications10.1016/j.clay.2017.11.023 ↗
38. Structural characterization of dodecyltrimethylammonium (DTMA) bromide modified sepiolite and its adsorption isotherm studies10.1016/j.molstruc.2011.09.044 ↗
39. Facile modification of nanoscale zero-valent iron with high stability for Cr(VI) remediation10.1016/j.scitotenv.2017.04.121 ↗
40. Chromium VI adsorption on cerium oxide nanoparticles and morphology changes during the process10.1016/j.jhazmat.2010.08.052 ↗
41. High performance of symmetrical supercapacitor based on multilayer films of graphene oxide/polypyrrole electrodes10.1016/j.apsusc.2014.01.080 ↗
42. Removal of chromium from aqueous solution using polyaniline--poly ethylene glycol composite10.1016/j.jhazmat.2010.08.029 ↗
43. Review of the evidence regarding the carcinogenicity of hexavalent chromium in drinking water10.1080/10590500600614337 ↗
44. Biosorption of Rhodamine 6G from aqueous solutions onto almond shell (Prunus dulcis) as a low cost biosorbent10.1016/j.desal.2009.10.021 ↗
45. Exfoliated polypyrrole-organically modified montmorillonite clay nanocomposite as a potential adsorbent for Cr(VI) removal10.1016/j.cej.2013.02.061 ↗
46. High-performance towards Cr(VI) removal using multi-active sites of polypyrrole–graphene oxide nanocomposites: batch and column studies10.1016/j.cej.2014.10.034 ↗
47. Large-pore diameter nano-adsorbent and its application for rapid lead(II) detection and removal from aqueous media10.1016/j.cej.2015.03.073 ↗
48. Highly efficient removal of acid Red 18 from aqueous solution by magnetically retrievable chitosan/carbon nanotube: batch study, isotherms, kinetics, and thermodynamics
49. Highly efficient removal of acid Red 18 from aqueous solution by magnetically retrievable chitosan/carbon nanotube: batch study, isotherms, kinetics, and thermodynamics10.1021/je400700c ↗
50. Synthesis of polyethylenimine-functionalized poly(glycidyl methacrylate) magnetic microspheres and their excellent Cr(VI) ion removal properties10.1016/j.cej.2013.08.082 ↗
51. Thermal and morphological characterisation of organically modified sepiolite10.1016/j.micromeso.2007.04.020 ↗
52. Flexible core-shell/bead-like alginate@PEI with exceptional adsorption capacity, recycling performance toward batch and column sorption of Cr(VI)10.1016/j.cej.2016.12.099 ↗
53. Core-shell attapulgite@polypyrrole composite with well-defined corn cob-like morphology via self-assembling and in situ oxidative polymerization10.1016/j.synthmet.2009.07.022 ↗
54. Physical and chemical properties of magnetite and magnetite-polymer nanoparticles and their colloidal dispersions10.1006/jcis.1998.5993 ↗
55. Phosphate adsorption on lanthanum hydroxide-doped activated carbon fiber10.1016/j.cej.2012.01.066 ↗
56. Highly dispersed sepiolite-based organic modified nanofibers for enhanced adsorption of Congo red10.1016/j.clay.2018.02.031 ↗
57. Synthesis and characterization of prussian blue modified magnetite nanoparticles and its application to the electrocatalytic reduction of H2O210.1021/cm048078s ↗
58. Polymer-supported nanocomposites for environmental application: a review10.1016/j.cej.2011.02.071 ↗
59. Branched polyethylenimine grafted electrospun polyacrylonitrile fiber membrane: a novel and effective adsorbent for Cr(VI) remediation in wastewater10.1039/C6TA09784G ↗
60. Polymeric Fe/Zr pillared montmorillonite for the removal of Cr(VI) from aqueous solutions10.1016/j.cej.2010.07.016 ↗