journal article·2015-09Open access

Hydrotalcite derived (Cu, Mn)–Mg–Al metal oxide systems doped with palladium as catalysts for low-temperature methanol incineration

Magdalena Jabłońska, Lucjan Chmielarz, Agnieszka Węgrzyn, Kinga Góra-Marek, Zofia Piwowarska, Stefan Witkowski, Ewa Bidzińska, Piotr Kuśtrowski, Anna Wach, Dorota Majda

Abstract

Abstract Hydrotalcite derived (Cu, Mn)–Mg–Al mixed metal oxides, synthesized by coprecipitation method, were found to be effective catalysts for methanol incineration. Copper and/or manganese oxides deposited on commercial γ-Al 2 O 3 and MgO were used as the reference catalysts. Cu–Mg–Al–O mixed oxide system was found to be the most active catalysts in a series of the hydrotalcite originated metal oxides and supported samples. On the other hand, copper deposited on Al 2 O 3 and MgO supports were significantly less active than the hydrotalcite derived catalysts. Activity of the catalysts was improved by deposition of small amount of palladium (0.5 wt.%). Temperature-programmed surface reaction method (CH 3 OH-TPSR) and in situ Fourier-transform infrared spectroscopy (FT-IR) were employed to study the species formed on the catalyst surface during the process of methanol oxidation.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Magnesium Oxide Properties and Applications · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (46)

Show source-provided references
1. Cu–Mn and Co–Mn catalysts synthesized from hydrotalcites and their use in the oxidation of VOCs10.1016/j.apcatb.2011.02.019 ↗
2. Study of MgO and Pt/MgO systems by XRD, TPR, and 1H MAS NMR10.1021/la9808972 ↗
3. LDH-derived catalysts for complete oxidation of volatile organic compounds10.1180/claymin.1999.034.1.08 ↗
4. A study of Mn-Ti oxide powders and their behaviour in propane oxidation catalysis10.1039/a803994a ↗
5. Influence of thermal treatments on the basic and catalytic properties of Mg, Al-mixed oxides derived from hydrotalcites10.1590/S0104-66322004000200008 ↗
6. Evaluation of manganese (II) framework substitution in MnAPO-11 and Mn-impregnated AlPO4-11 molecular sieves by electron spin resonance and electron spin-echo modulation spectroscopy10.1021/ja00036a022 ↗
7. Mixed manganese oxide/platinum catalysts for total oxidation of model gas from wood boilers10.1016/S0926-860X(97)80129-9 ↗
8. Adsorption and reactivity of NO on copper-on-alumina catalysts: I. Formation of nitrate species and their influence on reactivity in NO and NH3 conversion10.1006/jcat.1995.1062 ↗
9. Novel CH4 combustion catalysts derived from Cu–Co/X-Al (X=Fe, Mn, La, Ce) hydrotalcite-like compounds10.1021/ef8000168 ↗
10. Influence of Cu, Co and Ni cations incorporated in brucite-type layers on thermal behaviour of hydrotalcites and reducibility of the derived mixed oxide systems10.1016/S0040-6031(02)00214-9 ↗
11. Selective catalytic oxidation (SCO) of ammonia to nitrogen over hydrotalcite originated Mg–Cu–Fe mixed metal oxides10.1007/s10562-011-0653-8 ↗
12. Total oxidation of selected mono-carbon VOCs over hydrotalcite originated metal oxide catalysts10.1016/j.catcom.2011.10.030 ↗
13. Oxidation of volatile organic compounds on Al2O3, Pd/Al2O3 and PdO/Al2O3 catalysts10.1006/jcat.1996.0264 ↗
14. Characterization of Al–Cu and Al–Cu–Mg mixed oxides and their catalytic activity in dehydrogenation of 2-octanol10.1016/j.cattod.2005.07.168 ↗
15. Mn-containing catalytic materials for the total combustion of toluene: the role of Mn localisation in the structure of LDH precursor10.1016/j.cattod.2006.08.060 ↗
16. Complete oxidation of acetone over manganese oxide catalysts supported on alumina- and zirconia-pillared clays10.1016/S0926-3373(02)00058-9 ↗
17. Dispersion stability and methylcyclopentane hydrogenolysis in Pd/Al2O3 catalysts10.1016/S0926-860X(00)00442-7 ↗
18. Palladium and platinum-based catalysts in the catalytic reduction of nitrate in water: effect of copper, silver, or gold addition10.1016/S0021-9517(03)00252-5 ↗
19. Regenerable MgO-based sorbents for high-temperature CO2 removal from syngas: 1. Sorbent development, evaluation, and reaction modeling10.1016/j.fuel.2009.11.017 ↗
20. Total oxidation of VOCs on Pd and/or Au supported on TiO2/ZrO2 followed by “operanto” DRIFT10.1016/j.crci.2008.09.032 ↗
21. Metal–support interactions in Pt/Al2O3 and Pd/Al2O3 catalysts for CO oxidation10.1016/j.apcatb.2010.03.024 ↗
22. Preparation and characterization of activated Ni (Mn)/Mg/Al hydrotalcites for combustion catalysis10.1016/S0920-5861(02)00203-1 ↗
23. Characterization of Al2O3-supported manganese oxides by electron spin resonance and diffuse reflectance spectroscopy10.1021/jp962343i ↗
24. In situ FT-IR spectroscopic study of CO2 and CO adsorption on Y2O3, ZrO2, and yttria-stabilized ZrO210.1021/jp405625x ↗
25. State of manganese atoms during the mechanochemical synthesis of LiMn2O410.1006/jssc.1999.8329 ↗
26. Supported mixed oxide catalysts for the total oxidation of volatile organic compounds10.1016/j.cattod.2011.02.002 ↗
27. Supported layered double hydroxide-related mixed oxides and their application in the total oxidation of volatile organic compounds10.1016/j.clay.2010.12.030 ↗
28. Characterization of activated Cu/Mg/Al hydrotalcites and their catalytic activity in toluene combustion10.1016/S0169-1317(00)00032-6 ↗
29. Thermal behaviour of Cu–Mg–Mn and Ni–Mg–Mn layered double hydroxides and characterization of formed oxides
30. Mixed oxides obtained from Co and Mn containing layered double hydroxides: preparation, characterization, and catalytic properties10.1016/j.jssc.2005.12.004 ↗
31. Catalytic removal of toluene in air over Co–Mn–Al nano-oxides synthesized by hydrotalcite route10.1007/s10562-007-9196-4 ↗
32. ESR and electron spin-echo studies of MnAlPO510.1021/j100173a051 ↗
33. Liquid-phase oxidation of toluene by molecular oxygen over copper manganese oxides10.1007/s10562-006-0103-1 ↗
34. Mixed oxides of transition metals as catalysts for total ethanol oxidation10.2478/s11696-011-0127-x ↗
35. Physicochemical properties of copper oxide loaded alumina in methane combustion10.1039/ft9908603027 ↗
36. The cyclohexanol dehydrogenation on Rh-Cu/Al2O3 catalysts Part 1. Characterization of the catalyst10.1016/S0926-860X(96)00316-X ↗
37. Calcined Ni–Al layered double hydroxide as a catalysts for total oxidation of volatile organic compounds: effect of precursor crystallinity10.2478/s11696-007-0006-7 ↗
38. Time-resolved in situ X-ray diffraction of the liquid-phase reconstruction of Mg–Al-carbonate hydrotalcite-like compounds10.1039/b002827o ↗
39. Toluene combustion over palladium supported on various metal oxide supports10.1016/S0926-3373(03)00101-2 ↗
40. Total oxidation of toluene over calcined trimetallic hydrotalcites type catalysts10.1016/j.jhazmat.2009.12.048 ↗
41. The reduction and oxidation behaviour of manganese oxides10.1016/S0920-5861(98)00296-X ↗
42. Origination of N2O from NO reduction by NH3 over β-MnO2 and α-Mn2O310.1016/j.apcatb.2010.06.012 ↗
43. Effect of manganese substitution on the physicochemical properties and catalytic toluene oxidation activities of Mg–Al layered double hydroxides10.1016/S1387-1811(99)00123-7 ↗
44. The influence of mixed anionic composition of Mg–Al hydrotalcites on the thermal decomposition mechanism based on in situ study10.1007/s10973-009-0190-5 ↗
45. ESR and ESEM studies of Mn-containing MCM-41 materials10.1016/S1387-1811(98)00103-6 ↗
46. Catalytic combustion of toluene over Cu–Mn oxides10.1016/j.cattod.2006.08.022 ↗