journal article·2017-09

Light scattering by boron oxide in a nonuniform temperature field and upon varying temperature

N. A. Bokov

Glass Physics and Chemistry· Volume 43· Issue 5
Publisher page

Abstract

It is established that the time dependence of the intensity of the polarized component of visible light scattering by boron oxide under the influence of a constant temperature gradient is characterized by the same features as in the case of temperature variation. Based on this analogy, the relaxation times of the process of increasing the intensity in a nonuniform temperature field for different temperature intervals are determined. The activation energy of the process of increasing the intensity for different experimental conditions is calculated using the Arrhenius equation, and it is found that the calculated activation energy values are in satisfactory agreement with each other and with the data of other studies. The uniform behavior of the time dependence of the intensity of visible light scattering and close activation energy values point to common physical reasons for the structural changes occurring on the boron oxide structure approaching the equilibrium and stationary states.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Laser-Ablation Synthesis of Nanoparticles · Field-Flow Fractionation Techniques · Optical Imaging and Spectroscopy Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (6)

Show source-provided references
1. Bokov, N.A., Experimental investigation of the influence of a temperature gradient on the intensity of light scattering in borate melts, Glass Phys. Chem., 2010, vol. 36, no. 2, pp. 158–165.10.1134/S1087659610020021 ↗
2. Bokov, N.A., Universal character of relaxation of the intensity of light scattering by boron oxide melt in the temperature range 300–340°C, Glass Phys. Chem., 2016, vol. 42, no. 6, pp. 525–529.10.1134/S1087659616060031 ↗
3. Bokov, N.A., Light scattering by boron oxide in the temperature range of 225–330°C, Glass Phys. Chem., 2017, vol. 43, no. 1, pp. 17–22.10.1134/S1087659617010047 ↗
4. Macedo, P.B., Montrose, C.J., Moynihan, C.T., and Lai, C.C., Viscoelastic relaxation in B2O3, in Proceedings of the Conference on Boron Glass and Glass Ceramics, Alfred, New York, June 5–8, 1977, New York: Plenum, 1978, pp. 463–476.
5. Nemilov, S.V., Viscosity of borate glass-forming melts: specific features of the BO4 tetrahedron as a kinetic unit, Glass Phys. Chem., 1997, vol. 23, no. 1, pp. 1–26.
6. Bokov, N.A., Specifics of light scattering and optical anisotropy of boron oxide melt, Glass Phys. Chem., 2017, vol. 43, no. 2, pp. 185–187.10.1134/S1087659617020055 ↗