journal article·2012-02

Preparation of mesoporous MCM-41 from natural sepiolite and its catalytic activity of cracking waste polystyrene plastics

Shengming Jin, Kuixin Cui, Haoyuan Guan, Min Yang, Li Liu, Chunfeng Lan

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Abstract

Abstract Mesoporous MCM-41 was prepared by leaching of sepiolite and sequent hydrothermal synthesis in NaOH solution with hexadecyltrimethylammonium bromide as template. Small-angle X-ray diffraction patterns, Scanning electron microscopy, transmission electron microscopy and Brunauer–Emmett–Teller were performed to characterize the resulting compounds. The results showed that the crystallinity and pore size of MCM-41 increased with increase of crystallization time, ratios of surfactant to SiO2 and decrease of Mg content. The experimental results of catalytic cracking of polystyrene waste showed that the MCM-41 with MgO from natural sepiolite had high catalytic activity and good selectivity to monomer styrene for the catalytic cracking of polystyrene when the ratio of waste plastics to MCM-41 was 200. The side reactions yielded ethylbenzene, isopropylbenzene, isopropenylbenzene and secondary cross-linking were suppressed by basic species MgO in MCM-41.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Zeolite Catalysis and Synthesis · Mesoporous Materials and Catalysis · Clay minerals and soil interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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