journal article·2019-10

Performance of magnetite/layered double hydroxide composite for dye removal via adsorption, Fenton and photo-Fenton processes

Rosembergue Gabriel Lima Gonçalves, Paloma Aparecida Lopes, Júlia Alvarenga Resende, Frederico Garcia Pinto, Jairo Tronto, Mário César Guerreiro, Luiz Carlos Alves de Oliveira, Wallace de Castro Nunes, Jonas Leal Neto

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Abstract

Abstract In order to investigate the effect of the addition of magnetite in layered double hydroxide (LDH) from a structural and catalytic point of view, the synthesis of LDH containing cobalt and chromium (CoCr-LDH) was performed with or without Fe3O4. These materials were systematically characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), N2 adsorption Isotherms, Fourier transform infrared spectroscopy (FTIR), and evaluated as adsorbents and heterogeneous catalysts in Fenton-like and photo-Fenton-like reactions. The results showed that the magnetite was prepared and incorporated to the LDH with success, forming a composite providing magnetic properties and promoting alteration in the morphology, quantity and size of the LDH pores. The evaluation of the adsorption and oxidation processes utilizing the Fe3O4/LDH composite showed to be more efficient than for pure LDH. This better performance can be explained by higher surface area and larger pores for Fe3O4/LDH which allow a more effective contact with the dye solution and more proximity of large molecules like those of Reactive Black with the sites where the OH• radicals are formed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Magnesium Oxide Properties and Applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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