journal article·2008-12

Ettringite formation and behaviour in clayey soils

Vahid R. Ouhadi, Raymond N. Yong

Applied Clay Science· Volume 42· Issue 1-2
Publisher page

Abstract

Failures in soil stabilization have been reported previously as being due to the formation of ettringite, an expansive mineral which develops in the presence of sulfate, calcium, and aluminum compounds of clay fraction in high pH levels between 10.36 and 14. By comparing the pattern of formation of ettringite, formed from different possible sources and specifically in stabilized soil, it is expected that a clearer picture of the kinetics of ettringite formation from different sources will be obtained. In this paper, a set of physico-chemical experiments and XRD tests were performed to investigate the process of ettringite formation and to explore its possible performance in clayey soils. The growth of the ettringite XRD peaks was used as a measure of the rate and its formation pattern. It is shown that the rate of ettringite formation in soil stabilization is much slower than that of artificial ettringite. Furthermore, it is shown that ettringite swells to the order of 50% and its fluid retention is significantly higher (by as much as 400%) than that of the soil sample studied in this research.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Soil and Unsaturated Flow · Clay minerals and soil interactions · Iron oxide chemistry and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. American Society for Testing and Materials, ASTM · 1992
2. The kinetics of ettringite formation10.1016/0008-8846(89)90100-2 ↗
3. Highway research report, lime soil stabilization study, phase II, laboratory investigation of California soils for lime reactivity
4. Theories of expansion in sulfoaluminate-type expansive cements: school of thought10.1016/0008-8846(83)90082-0 ↗
5. Cullity · 1976
6. EPS · 1979
7. Concerning the diffusion kinetics of reactions in spherical particles
8. The formation of ettringite at elevated temperature10.1016/0008-8846(93)90052-B ↗
9. Lime induced heave in sulfate-bearing clay soils
10. Hunter, D., 1989, The geochemistry of lime-induced heave in sulfate-bearing clay soils, PhD Thesis, University of Nevada, 270p.
11. Solid state reactions at high temperature10.1002/zaac.19271630102 ↗
12. Combining industrial wastes with lime for soil stabilization
13. Keller, W.D., 1964, The origin of high alumina clay minerals, a review, Clay and Clay Minerals, Proceedings of the Twelfth National Conference, Monograph No. 19, Earth Science Series, Pergamon Press, New York, pp. 129–151.10.1346/CCMN.1963.0120115 ↗
14. The formation and role of ettringite in Iowa highway concrete deterioration10.1016/j.cemconres.2004.05.029 ↗
15. Thaumasite formation in a tunnel of Bapanxia Dam in Western China10.1016/j.cemconres.2005.10.011 ↗
16. Role of detrimental salts in soil stabilization with and without cement, I. The effect of sodium sulfate
17. Mechanism of expansion associated with ettringite formation10.1016/0008-8846(73)90056-2 ↗
18. Scanning electron micrographic studies of ettringite formation10.1016/0008-8846(76)90115-0 ↗
19. Mehta · 1966 · 328
20. Practical problems from surprising soil behaviour10.1061/(ASCE)0733-9410(1986)112:3(255) ↗
21. Clay soil heave caused by lime–sulfate reactions
22. Moore · 1989
23. Supplementary Paper II-73, effect of the temperature on the early hydration of the system 3CaO×Al2O3–CaSO4×2H2O–Ca(OH)2–H2O
24. Neville · 1983
25. Possibilities of quantitative determination of the AFt-(ettringite) and AFm-(monosulfate) phases in hydrated cement pastes10.1016/0008-8846(84)90089-9 ↗
26. Ouhadi, V.R., 1997. The role of marl components and ettringite on the stability of stabilized marl, PhD Thesis, McGill University, Canada, 236p.
27. The role of clay fractions of marly soils on their post stabilization failure10.1016/S0013-7952(03)00104-2 ↗
28. Impact of clay microstructure and mass absorption coefficient on the quantitative mineral identification by XRD analysis10.1016/S0169-1317(03)00096-6 ↗
29. Factors impacting on the electro-conductivity variations of clayey soils
30. Mechanism and kinetics of hydration of C3A and C4AF extracted from cement10.1016/0008-8846(84)90110-8 ↗
31. Sulphate attack and ettringite formation in the lime and cement stabilized marine clay10.1016/j.oceaneng.2004.08.012 ↗
32. Effect of chlorides and sulphates on lime treated marine clays10.3208/sandf.37.2_105 ↗
33. Schwiete · 1966 · vol. 90 · 353
34. Effect of sulfates on cement stabilized clay
35. Effect of sulfates on cement and lime treated soils
36. The solubility of ettringite at 25 C10.1016/0008-8846(94)90166-X ↗
37. Yong · 1975 · 451
38. Reaction factors impacting on instability of bases on natural and lime-stabilized marls
39. Experimental study on instability of bases on natural and lime/cement-stabilized clayey soils10.1016/j.clay.2006.08.009 ↗