Solid-state intercalation of 8-Hydroxyquinoline into Li(I)-, Zn(II)- and Mn(II)-montmorillonites
Source abstract
Abstract
Abstract Formation of three fluorescent complexes, Li(I)-, Zn(II)- and Mn(II)-8-hydroxyquinoline complexes (Mq n ), was investigated in the interlayer spaces of montmorillonites by solid–solid reactions between homoionic (Li(I), Zn(II) and Mn(II)) montmorillonites and neat 8-hydroxyquinoline at room temperature. The intercalation of 8-hydroxyquinoline molecules into the interlayer spaces of Li(I)-, Zn(II)- and Mn(II)-montmorillonites was confirmed by powder XRD, FT-IR, TG-DTA and chemical analysis. The in-situ complex formation was proved by FT-IR, UV–vis, and photoluminescence spectroscopies. The absorption and luminescence bands of the complexes shifted slightly compared to the corresponding neat complexes, suggesting the different microstructures including molecular packing of the complexes in the interlayer spaces of montmorillonites as a result of host–guest interactions.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Mesoporous Materials and Catalysis · Conducting polymers and applications · Lanthanide and Transition Metal Complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (50)
Show source-provided references
1. The reaction of montmorillonite with octadecylamine in solid and melted state10.1016/0169-1317(92)90014-E ↗
2. Metal chelates as emitting materials for organic electroluminescence10.1016/S0010-8545(98)90027-3 ↗
3. Ion exchange between solids10.1021/j100706a033 ↗
4. Stereochemistry of hydrate copper(II) ions on the interlamellar surface of layer silicates. An electron spin resonance study
5. Thermal stability of transition-metal complexes10.1016/S0040-6031(98)00472-9 ↗
6. Thermal and structural properties of Ca-rich montmorillonite mechanically deformed by compaction and shear10.1016/j.clay.2005.09.006 ↗
7. Sorption of 8-hydroxyquinoline by some clays and oxides10.1346/CCMN.1988.0360108 ↗
8. Redox properties of bis (8-hydroxyquinoline) manganese(II) encapsulated in various zeolites10.1016/j.molcata.2004.03.055 ↗
9. Adsorption of quinoline from aqueous solutions by some clays and oxides10.1346/CCMN.1983.0310105 ↗
10. Substituted aluminum and zinc quinolates with blue-shifted absorbance/luminescence bands: synthesis and spectroscopic, photoluminescence, and electroluminescence characterization10.1021/cm9503442 ↗
11. Themal decomposition of the magnesium, zinc, lead and niobium chelates derived from 8-quinolinol10.1007/BF01979034 ↗
12. Solid state intercalation of 4,4′-bipyridine into the interlayer space of montmorillonites10.1080/10587250008026165 ↗
13. Solid-state intercalation of 4,4′-bipyridine and 1,2-di(4-pyridine)ethylene into the interlayer spaces of Co(II)-Ni(II)-, and Cu(II)-montmorillonites10.1016/S0169-1317(01)00055-2 ↗
14. Incorporation of thioacetamide into the interlayer space of montmorillonite by solid–solid reactions
15. Intercalation of 8-hydroxyquinoline into Al-smectites by solid–solid reactions10.1346/000986002320514154 ↗
16. Intercalation compounds of Cu2+ and Ni2+-exchanged montmorillonite clay with 8-hydroxyquinoline10.1002/jccs.199500011 ↗
17. Solid-state ion exchange in zeolites10.1039/FT9949001329 ↗
18. Systematic atomic number effects in complexes exhibiting ligand luminescence10.1016/0584-8539(73)80199-0 ↗
19. Vibrational study of 8-quinolinol and 7-(4-ethyl-1-methyloctyl)-8-quinolinol (Kelex 100), two representative members of an important chelating agent family10.1016/0584-8539(86)80051-4 ↗
20. The infrared spectra of chelate compounds-I: a study of some metal chelate compounds of 8-hydroxyquinoline in the region 625 to 5000 cm−110.1016/0039-9140(63)80245-3 ↗
21. Photofunctions of intercalation compounds10.1021/cr00034a005 ↗
22. Preparation of inorganic–organic nanocomposites through intercalation of organoammonium ions into layered silicates10.1246/bcsj.70.2593 ↗
23. Preparation of montmorillonite-organic intercalation compounds by solid–solid reactions10.1246/cl.1989.1659 ↗
24. Formation of organoammonium-montmorillonites by solid–solid reactions10.1246/cl.1990.71 ↗
25. Preparation of montmorillonite-alkylamine intercalation compounds by solid–solid reactions
26. Preparation of montmorillonite-p-aminoazobenzene intercalation compounds and their photochemical behavior10.1557/PROC-233-89 ↗
27. Intercalation of 2,2′-bipyridine and complex formation in the interlayer space of montmorillonite by solid–solid reactions10.1021/ic00003a050 ↗
28. Selective solid-state intercalation of cis-trans isomers into montmorillonite10.1246/cl.1992.365 ↗
29. Solid-state intercalation of acrylamide into smectites and Na-taeniolite10.1016/0169-1317(92)90016-G ↗
30. Solid-state intercalation of naphthalene and anthracene into alkylammonium-montmorillonites10.1346/CCMN.1992.0400501 ↗
31. Photophysical probe study of alkylammonium-montmorillonites10.1021/la00030a018 ↗
32. Intercalation of pyrene into alkylammonium-exchanged swelling layered silicates: the effects of the arrangements of the interlayer alkylammonium ions on the states of adsorbates10.1021/la00011a068 ↗
33. Intercalation and the photochromism of azo dye in the hydrophobic interlayer spaces of organoammonium-fluor-tetrasilicic micas
34. Intercalation of a crow-ether into layered silicates
35. Thermal behaviour of intercalated 8-hydroxyquinoline (oxine) in montmorillonite clay10.1023/B:JTAN.0000027160.19388.0c ↗
36. Solid-state formation of quinhydrones from their components. Use of solid–solid reactions to prepare compounds not accessible from solution10.1021/ja00314a017 ↗
37. Organic solid-state reactions10.1016/0022-4596(77)90067-6 ↗
38. Design of conjugated molecular materials for optoelectronics10.1039/a903239h ↗
39. Lithium–quinolate complexes as emitter and interface materials in organic light-emitting diodes10.1021/cm0010248 ↗
40. Turning down the heat: design and mechanism in solid-state synthesis10.1126/science.259.5101.1558 ↗
41. Synthesis of β-sialon from a montmorillonite-polyacrylonitrile intercalation compound by carbothermal reduction10.1111/j.1151-2916.1984.tb19499.x ↗
42. Properties and infrared spectra in the potassium bromide region of 8-quinolinol and its metal chelates10.1021/ic50015a021 ↗
43. Theng · 1974
44. Host–guest complex formation by a solid–solid reaction10.1039/C39870000279 ↗
45. Van Olphen · 1977 · 254
46. Whittingham · 1982 · 1
47. Zn(II) based mixed complex with 8-hydroxyquinoline end group functionalized PSt and the study of fluorescent properties10.1016/j.optmat.2004.09.016 ↗
48. X-ray diffraction studies of intercalation compounds prepared from aniline salts and montmorillonite by a mechanochemical processing10.1016/j.ssc.2005.08.017 ↗
49. Synthesis and vibrational spectra of metal halide complexes of 8-hydroxyquinoline in relation to their structures10.1016/j.molstruc.2003.11.014 ↗
50. Effect of metal cation on absorption and fluorescence spectra of metal complexes of 8-hydroxyquinoline10.1080/00387019608007266 ↗