journal article·2016-11

Preparation, characterization and application on dye adsorption of a well-defined two-dimensional superparamagnetic clay/polyaniline/Fe3O4 nanocomposite

Bin Mu, Jie Tang, Long Zhang, Aiqin Wang

Applied Clay Science· Volume 132-133
Publisher page

Abstract

Abstract Well-defined two-dimensional superparamagnetic clay/polyaniline/Fe 3 O 4 nanocomposites were successfully prepared for dye adsorption based on montmorillonite and vermiculite via a one-pot method combining in-situ intercalation polymerization and coprecipitation technique. The results of XRD revealed that montmorillonite and vermiculite were well intercalated and even completely exfoliated by polyaniline and Fe 3 O 4 . Furthermore, the generated Fe 3 O 4 nanoparticles with a diameter of about 10 nm and polyaniline were well confined to the surface of clay without the free aggregates. The as-prepared two-dimensional superparamagnetic nanocomposites could be served as a recycled adsorbent for the removal of dyes from aqueous solution by magnetic separation. The adsorption ratio toward 100 ppm of Brilliant green, Methylene blue, and Congo red reached 96.2%, 99.6% and 98.1%, respectively. In addition, the adsorption kinetics and the adsorption isotherm well fitted pseudo second-order kinetic model and Langmuir isotherm model, respectively. It suggested that the two-dimensional superparamagnetic nanocomposites exhibited excellent adsorption ratio to cationic dyes as well as anionic dyes.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Nanomaterials for catalytic reactions · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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