journal article·2010-03

Hydrotalcite-type precursors of active catalysts for hydrogen production

F. Basile, P. Benito, G. Fornasari, A. Vaccari

Applied Clay Science· Volume 48· Issue 1-2
Publisher page

Abstract

Abstract The effects that the composition of hydrotalcite (HT)-type precursors and their method of preparation have on the chemical–physical properties and catalytic performances of systems which are active in the partial oxidation and steam reforming of methane to produce H 2 were investigated. The key role of the structure of the HT compounds in the development of active catalysts is reported for Ni- and noble metal-based catalysts, which were prepared by controlled thermal decomposition of carbonate- or silicate-containing precursors. We highlight specific features which appear to be a function of the divalent to trivalent atomic ratio and/or nature of the anion present. Furthermore, we also report the advantages of coating ceramic and metallic supports with HT phases using coprecipitation and a novel type of electrochemical synthesis, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Catalysts for Methane Reforming · Inorganic Chemistry and Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (83)

Show source-provided references
1. Catalytic properties of layered double hydroxides
2. Effect of silicates on the structure of Ni-containing catalysts obtained from hydrotalcite-type precursors10.1016/j.cattod.2007.06.067 ↗
3. Durability of a Ni based monolithic catalyst in the autothermal reforming of biogas10.1016/j.ijhydene.2009.03.041 ↗
4. Role of the hydrotalcite-type precursor on the properties of CPO catalysts10.1016/j.cattod.2004.09.028 ↗
5. New catalysts with low amounts of active phase for CPO processes10.1016/j.cattod.2006.06.022 ↗
6. New hydrotalcite-type anionic clays containing noble metals10.1039/CC9960002435 ↗
7. Ni/Mg/Al anionic clay derived catalysts for the catalytic partial oxidation of methane10.1006/jcat.1997.1942 ↗
8. Catalytic partial oxidation and CO2-reforming on Rh- and Ni-based catalysts obtained from hydrotalcite-type precursors10.1016/S0169-1317(98)00031-3 ↗
9. Synthesis and thermal evolution of hydrotalcite-type compounds containing noble metals10.1016/S0169-1317(99)00053-8 ↗
10. Application of hydrotalcite-type anionic clays (layered double hydroxides) in catalysis
11. Catalytic activity of layered double hydroxides or hydrotalcite-type anionic clays
12. Rh, Ru and Ir catalysts obtained by HT precursors: effect of the thermal evolution and composition on the material structure and use10.1039/B205146J ↗
13. Rh–Ni synergy in the catalytic partial oxidation of methane: surface phenomena and catalyst stability10.1016/S0920-5861(02)00247-X ↗
14. Preparation and characterisation of a stable Rh catalyst for the partial oxidation of methane10.1016/S0021-9517(03)00021-6 ↗
15. Effect of the Mg/Al ratio of the hydrotalcite-type precursor on the dispersion and activity of Rh and Ru catalysts for the partial oxidation of methane10.1016/j.cattod.2004.03.047 ↗
16. Basile · 2004
17. Basile · 2005
18. Microwave-assisted catalysts for the CPO of methane10.1016/S0167-2991(06)80978-X ↗
19. Highly conductive Ni steam reforming catalysts prepared by electrodeposition10.1039/b801645c ↗
20. Electrochemical synthesis of novel structured catalysts for H2 production10.1016/j.apcatb.2009.06.028 ↗
21. Ni-catalysts obtained from silicate intercalated HTlcs active in the catalytic partial oxidation of methane: Influence of the silicate content10.1016/j.cattod.2009.01.013 ↗
22. Basini, L., Fornasari, G., Trifirò, F., Vaccari, A., 1996. Material having layered structure of hydrotalcite type, and use thereof. Eur. Patent Appl. 101,059 to Snamprogetti.
23. Influence of microwave radiation on the textural properties of layered double hydroxides10.1016/j.micromeso.2006.03.038 ↗
24. Testing in annular micro-reactor and characterization of supported Rh nanoparticles for the catalytic partial oxidation of methane: effect of the preparation procedure10.1016/j.apcatb.2008.02.007 ↗
25. CO2 reforming of methane to syngas I: evaluation of hydrotalcite clay-derived catalysts10.1016/S0169-1317(98)00030-1 ↗
26. Catalytic walls and micro-devices for generating hydrogen by low temperature steam reforming of ethanol10.1016/j.cattod.2008.08.040 ↗
27. Hydrotalcite-type anionic clays: preparation, properties and applications10.1016/0920-5861(91)80068-K ↗
28. Catalysis by layered materials: a review10.1016/j.micromeso.2007.03.011 ↗
29. Nickel catalyst prepared via glycine nitrate process for partial oxidation of methane to syngas10.1016/j.catcom.2007.12.009 ↗
30. Catalytic applications of hydrotalcite-like materials and their derived forms10.1016/j.clay.2006.07.007 ↗
31. Effect of supports and Ni crystal size on carbon formation and sintering during steam methane reforming10.1016/j.apcata.2006.07.028 ↗
32. Interactions of pesticides with clays and layered double hydroxides: a review10.1180/claymin.2008.043.2.01 ↗
33. Polymerization of silicates in layered double hydroxides10.1021/cm950533k ↗
34. Duan · 2006 · vol. 11910.1007/b100426 ↗
35. A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts10.1016/j.apcata.2008.05.018 ↗
36. Modified cobalt catalysts in the partial oxidation of methane at moderate temperatures10.1016/j.jcat.2008.12.014 ↗
37. Preparation of layered double hydroxides and their applications as additives in polymers, as precursors to magnetic materials and in biology and medicine10.1039/B510313B ↗
38. Precious metal catalysts supported on ceramic and metal monolithic structures for the hydrogen economy10.1080/01614940701220496 ↗
39. Enhanced metal dispersion and hydrodechlorination properties of a Ni/Al2O3 catalyst derived from layered double hydroxides10.1016/j.jcat.2009.07.001 ↗
40. Gary, D., Del Gallo, P., Basile, F., Fornasari, G., Rosetti, V., Vaccari, A., Scavetta E., Tonelli, D., 2007. Process for the preparation of a catalytic specie using electro-deposition. Eur. Patent Appl. EP 1 808 229 A1.
41. Neutron diffraction studies of polycrystalline Ni/Mg/Al mixed oxides obtained from hydrotalcite-like precursors10.1021/jp963761q ↗
42. LDH nanocomposites with different guest entities as precursors of supported Ni catalysts10.1021/cm071194l ↗
43. Monolithic structures as alternatives to particulate catalysts for the reforming of hydrocarbons for hydrogen generation10.1016/j.apcatb.2004.07.013 ↗
44. An overview of hydrogen production technologies10.1016/j.cattod.2008.08.039 ↗
45. Catalytic partial oxidation of methane over Ni-based catalysts derived from Ni-Mg/Al ternary hydrotalcites10.1021/ef800933j ↗
46. Preparation of supported Ni catalysts with a core/shell structure and their catalytic tests of partial oxidation of methane10.1016/j.ijhydene.2009.02.036 ↗
47. Fine tuning between organic and inorganic host structure: new trends in layered double hydroxide hybrid assemblies and so on10.1039/b505014f ↗
48. Effect of Rh loading on the performance of Rh/Al2O3 for methane partial oxidation to synthesis gas10.1016/j.cattod.2007.10.040 ↗
49. Production of hydrogen by ethanol steam reforming over catalysts from reverse microemulsion-derived nanocompounds10.1016/j.ijhydene.2008.04.021 ↗
50. Cobalt catalysts prepared from hydrotalcite precursors and tested in methane steam reforming, J10.1016/j.jpowsour.2005.10.108 ↗
51. Nickel catalysts promoted with cerium and lanthanum to reduce carbon formation in partial oxidation of methane reactions10.1016/j.apcata.2007.09.009 ↗
52. Cobalt catalysts promoted with cerium and lanthanum applied to partial oxidation of methane reactions10.1016/j.apcatb.2008.03.008 ↗
53. Ni(II)–Al(III) layered double hydroxide as catalyst precursor for ethanol steam reforming: activation treatments and kinetic studies10.1016/j.cattod.2007.11.032 ↗
54. Review on methods to deposit catalysts on structured surfaces10.1016/j.apcata.2006.08.031 ↗
55. Synthesis, characterization and catalytic behaviour of NiMgAl mixed oxides as catalysts for hydrogen production by naphtha steam reforming10.1016/j.cattod.2007.12.070 ↗
56. Embedded Rh(1wt.%)@Al2O3: effects of high temperature and prolonged aging under methane partial oxidation conditions10.1016/j.apcatb.2006.06.008 ↗
57. Partial oxidation of methane to synthesis gas over supported Ni catalysts prepared from Ni–Ca/Al-layered double hydroxide10.1016/S0926-860X(01)00525-7 ↗
58. Methane autothermal reforming with and without ethane over mono- and bimetal catalysts prepared from hydrotalcite precursors10.1016/j.jcat.2004.10.006 ↗
59. Promoting effect of Co addition on the catalytic partial oxidation of methane at short contact time over a Rh/MgO catalyst10.1016/j.jcat.2008.08.002 ↗
60. Hydrogen production reactions from carbon feedstocks: fossil fuels and biomass10.1021/cr0501994 ↗
61. Light alkanes CO2 reforming to synthesis gas over Ni based catalysts10.1016/j.cattod.2006.02.053 ↗
62. Synthesis of anionic clay minerals (mixed metal hydroxides, hydrotalcite)10.1016/0167-2738(86)90067-6 ↗
63. Hydrogen production by ethanol steam reforming over Ni catalysts derived from hydrotalcite-like precursors: catalyst characterization, catalytic activity and reaction path10.1016/j.apcata.2008.11.029 ↗
64. Steam reforming
65. Rives · 2001
66. Steam reforming of hydrocarbons10.1039/9781847556974-00034 ↗
67. Rostrup-Nielsen · 1984 · vol. 5 · 1
68. Large-scale hydrogen production10.1023/A:1020163012266 ↗
69. Hydrogen and synthesis gas by steam and CO2-reforming10.1016/S0360-0564(02)47006-X ↗
70. Nickel doped hydrotalcites as catalyst precursors for the partial oxidation of light paraffins10.1016/S0169-1317(00)00031-4 ↗
71. Partial oxidation of methane over Ni/Mg–Al oxide catalysts prepared by solid phase crystallization method from Mg–Al hydrotalcite-like precursors10.1016/S0926-860X(01)00732-3 ↗
72. Partial oxidation of methane to syngas over Ni/Al2O3 catalysts prepared by a modified sol–gel method10.1021/ef800954a ↗
73. Highly dispersed and stable supported metal catalysts prepared by solid phase crystallization method10.1023/A:1020589132547 ↗
74. Steam reforming of CH4 over supported Ni catalysts prepared from a Mg–Al hydrotalcite-like anionic clay10.1039/B304261H ↗
75. Autothermal reforming of CH4 over supported Ni catalysts prepared from Mg–Al hydrotalcite-like anionic clay10.1016/j.jcat.2003.07.001 ↗
76. Mechanism of reconstitution of hydrotalcite leading to eggshell-type Ni loading on Mg–Al mixed oxide10.1016/j.jcat.2005.01.025 ↗
77. Layered double hydroxides: precursors for multifunctional catalysts10.1007/s11244-006-0041-6 ↗
78. Hydrotalcite-like anionic clays (layered double hydroxides)
79. Dry reforming of methane over catalysts derived from nickel-containing Mg–Al layered double hydroxides10.1016/S0021-9517(02)00047-7 ↗
80. Combined partial oxidation and dry reforming of methane to synthesis gas over noble metals supported on Mg–Al mixed oxide10.1016/j.apcata.2004.07.030 ↗
81. Preparation and catalytic properties of cationic and anionic clays10.1016/S0920-5861(98)00038-8 ↗
82. Catalytic partial oxidation of methane to synthesis gas over γ-Al2O3-supported rhodium catalysts10.1023/A:1019045210412 ↗
83. Effects of calcination temperatures on the catalytic performance of Rh/Al2O3 for methane partial oxidation to synthesis gas10.1016/j.cattod.2006.05.011 ↗