journal article·2017-07

Development and characterization of porous membranes based on kaolin/chitosan composite

Sonia Bouzid Rekik, Sana Gassara, Jamel Bouaziz, André Deratani, Semia Baklouti

Publisher page

Abstract

Abstract Chitosan/kaolin composite porous membranes were successfully prepared by solvent casting and evaporation process. The suspensions with different concentration of kaolin and chitosan showed a Newtonian behaviour. Strong interaction between chitosan and kaolin was revealed by FTIR and thermogravimetric analysis. The effect of kaolin content on the morphology and properties of the obtained membranes was studied. It was found by SEM observation that the kaolin particles were well dispersed in the chitosan matrix generating a porous microstructure. Incorporation of kaolin particles also improved the mechanical and thermal properties of the membranes and reduced drastically the water washout of chitosan in moderate acidic medium. Owing to their porous structure, the water permeability of the composite chitosan/kaolin membrane was significantly enhanced. The better formulation of the dope suspension in the range studied was 4% chitosan and 5% kaolin in acetic acid. These membranes made from naturally occurring materials might play an important role in advanced research in water treatment and environmental science.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Membrane Separation Technologies · Hydrogels: synthesis, properties, applications · Polymer-Based Agricultural Enhancements

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Chitosan/clay films' properties as affected by biopolymer and clay micro/nanoparticles' concentrations10.1016/j.foodhyd.2009.02.007 ↗
2. Chitosan: an update on potential biomedical and pharmaceutical applications10.3390/md13085156 ↗
3. Chitosan-based nanofibrous membranes for antibacterial filter applications10.1016/j.carbpol.2012.08.114 ↗
4. New polyelectrolyte complex from pectin/chitosan and montmorillonite clay10.1016/j.carbpol.2016.03.025 ↗
5. Biopolymer-clay nanocomposites based on chitosan 489 intercalated in montmorillonite10.1021/cm0343047 ↗
6. Quaternized chitosan-layered silicate intercalated composites based nanofibrous mats and their antibacterial activity10.1016/j.carbpol.2012.02.009 ↗
7. pH induced fabrication of kaolinite-chitosan biocomposite10.18052/www.scipress.com/ILCPA.68.1 ↗
8. Rheological properties of PZT suspensions for stereolithography10.1016/S0955-2219(02)00036-5 ↗
9. Insightful understanding of the role of clay topology on the stability of biomimetic hybrid chitosan-clay thin films and CO2-dried porous aerogel microspheres10.1016/j.carbpol.2016.03.077 ↗
10. Pore size tailoring of poly (etherimide) membrane from UF to NF range by chemical post-treatment using aminated oligomers10.1016/j.memsci.2013.02.005 ↗
11. Industrial applications of crustacean by-products (chitin, chitosan, and chitooligosaccharides): a review10.1016/j.tifs.2015.11.007 ↗
12. Influence of particle properties on the viscosity of polymer–alumina composites10.1016/j.ceramint.2007.08.007 ↗
13. Preparation and characterization of tubular membrane supports using centrifugal casting10.5004/dwt.2009.646 ↗
14. Carboxymethyl chitosan/clay nanocomposites and their copper complexes: fabrication and property10.1016/j.carbpol.2015.07.089 ↗
15. Elaboration of membrane ceramic supports using aluminium powder10.1080/19443994.2013.871341 ↗
16. Chitosan/ modified montmorillonite beads and adsorption Reactive Red 12010.1016/j.clay.2009.12.017 ↗
17. Synthesis and characterization of novel water soluble derivative of chitosan as an additive for polysulfone ultrafiltration membrane10.1016/j.memsci.2013.03.013 ↗
18. MMT-supported Ag nanoparticles for chitosan nanocomposites: structural properties and antibacterial activity10.1016/j.carbpol.2013.11.026 ↗
19. Characterization of chitosan composites with various clays10.1016/j.ijbiomac.2014.01.069 ↗
20. Multifunctional cellulosic paper based on quaternized chitosan and gold nanoparticle-reduced graphene oxide via electrostatic self-assembly10.1039/C4TA07160C ↗
21. A novel chitosan base molecularly imprinted membrane for selective separation of chlorogenic acid10.1016/j.seppur.2016.03.020 ↗
22. Chitosan intercalated montmorillonite: preparation, characterization and cationic dye adsorption10.1016/j.clay.2008.04.013 ↗
23. Mulder · 1996
24. Nanochitins and nanochitosans, paving the way to eco-friendly and energy-saving exploitation of marine resources10.1016/B978-0-444-53349-4.00257-0 ↗
25. Physico-chemical study of coating formulation based on natural apatite for the elaboration of microfiltration membrane10.3311/PPch.7388 ↗
26. Correlation between physicochemical characteristics and binding capacities of chitosan products10.1111/j.1365-2621.2000.tb10252.x ↗
27. A comparative study on sorption of arsenate ions from water by crosslinked chitosan and crosslinked chitosan/MMT nanocomposite10.1016/j.jece.2016.09.027 ↗
28. A review of water treatment membrane nanotechnologies10.1039/c0ee00541j ↗
29. Solvent resistant chitosan/poly(ether-block-amide) composite membranes for pervaporation of n-methyl-2-pyrrolidone/water mixtures10.1016/j.carbpol.2015.10.037 ↗
31. Application of membrane separation processes in petrochemical industry: a review10.1016/j.desal.2007.10.042 ↗
32. Development of an asymmetric ultrafiltration membrane from naturally-occurring kaolin clays: application to the cuttlefish effluents tratments10.4172/2155-9589.1000159 ↗
33. Effect of clay contents on mechanical and water vapor barrier properties of agar-based nanocomposite films10.1016/j.carbpol.2011.05.010 ↗
34. Chitin and chitosan: properties and applications10.1016/j.progpolymsci.2006.06.001 ↗
35. Sintering characteristics of kaolin in the presence of phosphoric acid binder10.1016/j.ceramint.2011.06.058 ↗
36. A review on chitosan-based adsorptive membranes10.1016/j.carbpol.2016.07.033 ↗
37. Bionanocomposites formed by in situ charged chitosan with clay10.1039/b914548f ↗
38. Self-organization in the chitosan–clay nanoparticles system. Regulated through polysaccharide macromolecule charging10.1134/S1061933X12050109 ↗
39. Chitosan/(polyvinyl alcohol)/zeolite electrospun composite nanofibrous membrane for adsorption of Cr6+, Fe3+and Ni2+10.1016/j.jhazmat.2016.06.028 ↗
40. Adsorption characteristics of cadmium and lead heavy metals into locally synthesized chitosan biopolymer10.4038/tar.v26i2.8102 ↗
41. Pervaporative dehydration characteristics of an ethanol/water azeotrope through various chitosan membranes10.1016/j.carbpol.2014.11.032 ↗
42. Chitosan-grafted nonwoven geotextile for heavy metals sorption in sediments10.1016/j.reactfunctpolym.2012.09.002 ↗
43. Eco-friendly methanesulfonic acid and sodium salt of dodecylbenzene sulfonic acid doped cross-linked chitosan based green polymer electrolyte membranes for fuel cell applications10.1016/j.memsci.2016.09.058 ↗
44. Fabrication of zeolite/polymer composite membranes in a roller assembly10.1016/j.micromeso.2015.11.003 ↗
45. Adsorption of an anionic azo dye by chitosan/kaolin/γ-Fe2O3 composites10.1016/j.clay.2010.02.003 ↗