Recent advances in layered double hydroixdes@MXene (LDHs@MXene) composites: Synthesis, properties, and catalytic applications
Source abstract
Abstract
The overuse of fossil fuels has led to severe energy shortages and environmental pollution, raising global concern. Photocatalysis has emerged as a promising technology for addressing global energy and environmental challenges. By harnessing solar energy to drive chemical reactions, photocatalytic processes enable clean energy production and the degradation of environmental pollutants. The development of new materials featuring layered structures, low cost, and large surface areas offers a promising strategy to address these challenges and promote sustainable development. Therefore, it is necessary to design active, dependable, and reasonably priced catalysts or photocatalysts in order to achieve the intended photocatalytic outcomes. 2D nanomaterials may generally be identified as efficient photocatalysts in various fields. Two of the best 2D nanomaterials are layered double hydroxides (LDHs) and MXene, complement each other in several ways because of their distinct properties. The lack of research on LDHs/MXene nanocomposites is filled by this comprehensive review, which focuses on techniques, structural morphologies, and their applications such as supercapacitors, water splitting and photocatalytic reduction of pollutants. Various factors influencing the composite`s morphology in order to give more understanding of the morphology control mechanism were also discussed in details. Finally, the current challenges for using LDHs/MXene nanocomposites for photocatalysis and future prospects in this field were also explored.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: MXene and MAX Phase Materials · Nanomaterials for catalytic reactions · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. NiFe-LDH/MoS2/MXene Nanocomposites as an Electrode Material for Battery-Type Supercapacitors10.1021/acsanm.3c03779 ↗
2. Ti2N MXene/Zn-Fe layered double hydroxide nanocomposite for efficient tetracycline removal from environmental waters: Thermodynamic and kinetic insights10.1016/j.jece.2024.114733 ↗
3. Recent advances of MXene@MOF composites for catalytic water splitting and wastewater treatment approaches10.1016/j.chemosphere.2024.143194 ↗
4. Rising of MXenes: Novel 2D-functionalized nanomaterials as a new milestone in corrosion science-a critical review10.1016/j.cis.2022.102730 ↗
5. Principles and mechanisms of photocatalytic dye degradation on TiO2 based photocatalysts: a comparative overview10.1039/C4RA06658H ↗
6. Recent developments in titanium carbide (Ti3C2)-based layered double hydroxide (LDH) nanocomposites for energy storage and conversion applications: a minireview and perspectives10.1021/acs.energyfuels.2c01752 ↗
7. The crystal structure of pyroaurite
8. Recent advances in layered double hydroxides (LDH)-based materials: Fabrications, modification strategies, characterization, promising environmental catalytic applications, and prospective aspects10.1039/D4YA00272E ↗
9. Hierarchical Cobalt-Nickel double Hydroxide Arrays Assembled on naturally Sedimented Ti3C2Tx for High-Performance Flexible Supercapacitors10.1002/adsu.202100371 ↗
10. MOF/MXene Composites: Synthesis, Application and Future Perspectives
11. Recent advances in highly active nanostructured NiFe LDH catalyst for electrochemical water splitting10.1039/D0TA10712C ↗
12. Hydrothermal technology for nanotechnology10.1016/j.pcrysgrow.2007.04.001 ↗
13. In situ assemble Ti3C2Tx MXene@ MgAl-LDH heterostructure towards anticorrosion and antiwear application10.1016/j.cej.2021.130050 ↗
14. Electronic structure engineering on two-dimensional (2D) electrocatalytic materials for oxygen reduction, oxygen evolution, and hydrogen evolution reactions10.1016/j.nanoen.2020.105080 ↗
15. Vertically-interlaced NiFeP/MXene electrocatalyst with tunable electronic structure for high-efficiency oxygen evolution reaction10.1016/j.scib.2021.02.033 ↗
16. Ni-Co-Fe layered double hydroxide coated on Ti3C2 MXene for high-performance asymmetric supercapacitor10.1016/j.apsusc.2021.150116 ↗
17. Facile self-assembly of sandwich-like MXene/graphene oxide/nickel–manganese layered double hydroxide nanocomposite for high performance supercapacitor10.1016/j.est.2021.103456 ↗
18. Three-dimensional honeycomb composites consist of metal carbides and layered double hydroxides for high-performance supercapacitor electrode materials10.1016/j.jpowsour.2024.234306 ↗
19. Rational design of Schottky heterojunction with modulating surface electron density for high-performance overall water splitting10.1016/j.apcatb.2021.120660 ↗
20. Layered double hydroxide (LDH)–MXene nanocomposite for electrocatalytic water splitting: current status and perspective
21. Synthesis of MXene-based single-atom catalysts for energy conversion applications10.1016/j.cej.2023.145700 ↗
22. Recent development in exfoliated two-dimensional gC3N 4 nanosheets for photocatalytic applications10.1039/C5TA07374J ↗
23. Structural aspects of layered double hydroxides
24. Advances in Titanium Carbide (Ti3C2Tx) MXenes and their Metal–Organic Framework (MOF)-Based nanotextures for Solar Energy Applications: A review10.1021/acsomega.2c05030 ↗
25. NiCoFe-layered double hydroxides/MXene/N-doped carbon nanotube composite as a high performance bifunctional catalyst for oxygen electrocatalytic reactions in metal-air batteries10.1016/j.jelechem.2021.115797 ↗
26. Acknowledgement of the double hydroxide and base double salt III Manesium-aluminium double hydroxide10.1002/hlca.19420250115 ↗
27. Self-assembling 2D/2D (MXene/LDH) materials achieve ultra-high adsorption of heavy metals Ni2+ through terminal group modification10.1016/j.seppur.2020.117525 ↗
28. Designing high electrochemical surface area between polyaniline and hydrogel polymer electrolyte for flexible supercapacitors10.1016/j.apsusc.2019.145135 ↗
29. Novel composite of Zn/Ti-layered double hydroxide coupled with MXene for the efficient photocatalytic degradation of pharmaceuticals10.1016/j.chemosphere.2022.136191 ↗
30. Zeolite-imidazole framework derived nickel-cobalt hydroxide on ultrathin MXene nanosheets for long life and high performance supercapacitance10.1016/j.jallcom.2021.161250 ↗
31. Double layers combined with MXene and in situ grown NiAl-LDH arrays on nickel foam for enhanced asymmetric supercapacitors10.1007/s11581-022-04520-8 ↗
32. Activated biochar loaded CuAl-layered double hydroxide composite for the removal of aniline aerofloat in wastewater: Synthesis, characterization, and adsorption mechanism10.1016/j.jece.2023.109293 ↗
33. In situ hybridization of an MXene/TiO2/NiFeCo-layered double hydroxide composite for electrochemical and photoelectrochemical oxygen evolution10.1039/C8RA02349B ↗
34. Α-Fe2O3 nanorods on CoFe-LDH@MX via interfacial interactions for Congo red removal: Experimental and mechanistic studies10.1016/j.jece.2024.113059 ↗
35. MXene-induced electronic optimization of metal-organic framework-derived CoFe LDH nanosheet arrays for efficient oxygen evolution10.1016/j.apcatb.2021.120599 ↗
36. Exceeding 50 000 cycle durability of layered hydroxide-based hybrid supercapacitor through scandium doping-induced superlong activation process
37. Development of binder-free three-dimensional honeycomb-like porous ternary layered double hydroxide-embedded MXene sheets for bi-functional overall water splitting reactions10.3390/nano12162886 ↗
38. 2D MXenes for electromagnetic shielding: a review10.1002/adfm.202000883 ↗
39. Synthesis and characterisation of MXene based-LDH photocatalytic materials for the removal of toxic pharmaceutical effluents10.1016/j.molliq.2024.125066 ↗
40. Interfacial Superassembly of Mo2C@NiMn-LDH Frameworks for Electrochemical monitoring of Carbendazim Fungicide10.1021/acssuschemeng.1c05056 ↗
41. The new emerging MXene/LDHs nanocomposites: a critical review of synthesis strategies, morphological regulation, and application prospects
42. Nanostructured modified layered double hydroxides (LDHs)-based catalysts: a review on synthesis, characterization, and applications in water remediation by advanced oxidation processes10.1016/j.cossms.2021.100965 ↗
43. Electrostatically self-assembled zeolitic imidazolate framework-67 templated cobalt tungsten layered double hydroxide@MXene nanosheets for superior biocompatible energy storage system
44. Superlattice Stacking by Confinement of the Layered double Hydroxide/Vanadium Carbide Hybrid Composite. The effect on Interlayer Anions (SO42– and CO32–) for comparing the Electrochemical Sensing of a Food Adulterant10.1021/acssuschemeng.2c04457 ↗
45. Methods of synthesis, characteristics, and environmental applications of MXene: a comprehensive review10.1016/j.chemosphere.2021.131607 ↗
46. A three-dimensional flower-like NiCo-layered double hydroxide grown on nickel foam with an MXene coating for enhanced oxygen evolution reaction electrocatalysis10.1039/D1RA01368H ↗
47. NiFe LDH/Ti3C2Tx/nickel foam as a binder-free electrode with enhanced oxygen evolution reaction performance10.1016/j.ijhydene.2021.11.048 ↗
48. Electrostatic self-assembly sandwich-like 2D/2D NiFe-LDH/MXene heterostructure for strong microwave absorption10.1016/j.jcis.2023.06.061 ↗
49. Effect of microstructure on electrochemical performance of electrode materials for microsupercapacitor10.1016/j.matlet.2023.134481 ↗
50. Doping effect and oxygen vacancy engineering in nickel-manganese layered double hydroxides for high-performance supercapacitors10.1016/j.nanoen.2024.109690 ↗
51. CoMn-LDH/Ti-MXene for asymmetric supercapacitor positive electrode10.1007/s11581-025-06100-y ↗
52. Insights into the impact of interlayer spacing on MXene-based electrodes for supercapacitors: a review10.1016/j.est.2023.107341 ↗
53. Metal-ion-assisted in-situ fabrication of large-size CoNi-LDH@MXene for robust high-energy supercapacitors10.1016/j.apsusc.2024.160346 ↗
54. Fundamentals of MXene synthesis10.1038/s44160-022-00104-6 ↗
55. Research progress of MXenes and layered double hydroxides for supercapacitors10.1039/D3QI00819C ↗
56. Recent progress in MXene-based materials: potential high-performance electrocatalysts10.1002/adfm.202003437 ↗
57. Adjusting surface electron density of heterostructured NiCo LDH/MXene/NF material to improve its electrocatalytic performance in hydrogen evolution reaction10.1016/j.ijhydene.2024.04.171 ↗
58. Interface design based on Ti3C2 MXene atomic layers of advanced battery-type material for supercapacitors10.1016/j.ensm.2019.11.021 ↗
59. Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides10.1038/nenergy.2017.105 ↗
60. Monolayer Ti2C MXene: Manipulating magnetic properties and electronic structures by an electric field10.1039/D0CP00507J ↗
61. Rapid simultaneous removal of toxic anions [HSeO3]−,[SeO3] 2–, and [SeO4] 2–, and metals Hg2+, Cu2+, and Cd2+ by MoS42–intercalated layered double hydroxide10.1021/jacs.7b07123 ↗
62. MnO2 nanowires@NiCo-LDH nanosheet core–shell heterostructure: a slow irreversible transition of hydrotalcite phase for high-performance pseudocapacitance electrode10.1021/acsaem.1c00314 ↗
63. Oxygen-vacancy-embedded 2D/2D NiFe-LDH/MXene Schottky heterojunction for boosted photodegradation of norfloxacin10.1016/j.apsusc.2021.151432 ↗
64. Synthesis and photocatalytic degradation efficiency of MgFeO@CuO nanocomposite for Bromophenol blue dye removal10.1002/jccs.70000 ↗
65. Removing anionic dyes from wastewater based on in-situ formation of Fe3O4@Zn-Al layered double hydroxides by self-assembly10.1016/j.clay.2019.01.012 ↗
66. DFT study of layered double hydroxides with cation exchange capacity:(A+ (H2O)6)[M62+Al3 (OH)18(SO4)2]·6H2O (M2+= Mg, Zn and A+= Na, K)10.1021/acs.jpcc.9b00470 ↗
67. Recent progress in chemically functionalized heterogeneous catalysts for CO2 conversion by electro and photocatalysis: a review10.1002/adsu.202400852 ↗
68. Nanostructure engineering by surficial induced approach: Porous metal oxide-carbon nanotube composite for lithium-ion battery10.1016/j.mseb.2021.115417 ↗
69. Surface induced growth of ZIF-67 at Co-layered double hydroxide: Removal of methylene blue and methyl orange from water10.1016/j.clay.2020.105564 ↗
70. Kinetics, isothermal and mechanistic insight into the adsorption of eosin yellow and malachite green from water via tri-metallic layered double hydroxide nanosheets10.1007/s11814-021-0892-3 ↗
71. Highly Efficient Mg0.75Ce0.25Fe12O19 @ZIF-67 Heterojunction Co-catalyst for Photo-reduction of Rhodamine B10.1007/s11814-024-00162-w ↗
72. Tuning the photocatalytic hydrogen production via co-catalyst engineering10.1016/j.jallcom.2024.174378 ↗
73. Recent advances in MXene nanomaterials: Fundamentals to applications in environment sector10.1002/ece2.60 ↗
74. Copper- and manganese-based bimetallic layered double hydroxides for catalytic reduction of methylene blue10.3390/catal14070430 ↗
75. Layered Ni(OH) 2-Co(OH)2 films prepared by electrodeposition as charge storage electrodes for hybrid supercapacitors10.1038/srep39980 ↗
76. 650 nm-driven syngas evolution from photocatalytic CO2 reduction over CO-containing ternary layered double hydroxide nanosheets10.1016/j.cej.2020.128362 ↗
77. Electrostatic self-assembly of MXene and edge-rich CoAl layered double hydroxide on molecular-scale with superhigh volumetric performances10.1016/j.jechem.2019.10.023 ↗
78. Hydrothermal ion exchange synthesis of CoM (M= Fe or Mn)/MXene 2D/2D hierarchal architectures for enhanced energy storage10.1016/j.jallcom.2021.162385 ↗
79. Designed formation of 2D/2D hierarchical V2CTx MXene/NiV layered double hydroxide heterostructure with boosted electrochemical performance for asymmetric supercapacitors10.1016/j.est.2022.105415 ↗
80. Enhanced photocatalytic performance of MXene-Modified cation-exchanged CoFe-LDH/CoFeCrO4 heterostructure for Antibiotic degradation and hydrogen production through synergistic charge dynamics10.1016/j.compositesb.2024.111416 ↗
81. Recent advancement in synthesis and applications of layered double hydroxides (LDHs) composites
82. Transition metal chalcogenides and phosphides for photocatalytic H2 generation via water splitting: a critical review10.1016/j.ijhydene.2024.03.139 ↗
83. 3D interweaving MXene–graphene network–confined Ni–Fe layered double hydroxide nanosheets for enhanced hydrogen evolution10.1016/j.electacta.2022.139913 ↗
84. MXene quantum dot rivet reinforced Ni–Co LDH for boosting electrochemical activity and cycling stability10.1039/D1MA00474C ↗
85. Eutectic Solvent-Mediated Synthesis of NiFe-LDH/Sulfur-Doped Carbon Nitride Arrays: Investigation of Electrocatalytic activity for the Dimetridazole Sensor in Human Sustenance10.1021/acssuschemeng.0c06070 ↗
86. Surfactant-Assisted Synthesis of Praseodymium Orthovanadate Nanofiber-Supported NiFe-Layered double Hydroxide Bifunctional Catalyst: the Electrochemical Detection and Degradation of Diphenylamine10.1021/acs.inorgchem.2c00052 ↗
87. Hierarchical 3D architecture NiCo–layered double hydroxide decorated functionalized halloysite nanotubes composite. An efficient electrocatalyst for ractopamine detection10.1016/j.clay.2023.107028 ↗
88. Two-Dimensional CuMn-Layered double Hydroxides: a Study of Interlayer Anion Variants on the Electrochemical Sensing of Trichlorophenol10.1021/acs.inorgchem.3c04568 ↗
89. Rational confinement of ternary layered double hydroxide within three-dimensional graphene aerogel: an electrochemical tool for propyl gallate sensing10.1016/j.cej.2024.149682 ↗
90. Preserving food quality: Electrochemical detection of synthetic food antioxidant, propyl gallate in processed foods using ternary component layered double hydroxide/graphene aerogel synergy
91. Super-stable mineralization of Cu, Cd, Zn and Pb by CaAl-layered double hydroxide: Performance, mechanism, and large-scale application in agriculture soil remediation10.1016/j.jhazmat.2023.130723 ↗
92. Synthesis and characterization of two-faced brush-like MXene anchored NiCo-LDH electrode for high-performance supercapacitors10.1016/j.apenergy.2024.122944 ↗
93. Ti3C2 mediates the NiFe-LDH layered electrocatalyst to enhance the OER performance for water splitting
94. Hydrothermal synthesis of flower-like NiCo2-LDH/MXene-Ti3C2 composites for high-performance capacitors10.1007/s10008-023-05609-4 ↗
95. Electrostatically directed assembly of two-dimensional ultrathin Co2Ni-MOF/Ti3C2Tx nanosheets for electrocatalytic oxygen evolution10.1016/j.jcis.2022.10.109 ↗
96. MXene derived TiS2 nanosheets for high-rate and long-life sodium-ion capacitors10.1016/j.ensm.2019.11.028 ↗
97. MXene-Supported FeCo-LDHs as Highly Efficient Catalysts for Enhanced Electrocatalytic Oxygen Evolution Reaction10.1002/cnma.201900613 ↗
98. MXene nanomaterials: Synthesis, properties and applications in energy and environment sector10.1016/j.jallcom.2024.175172 ↗
99. Next generation MXene based materials for electrochemical sensor: a critical review10.1016/j.molstruc.2024.139830 ↗
100. Synergistic MXene/LDH heterostructures with extensive interfacing as emerging energy conversion and storage materials10.1039/D3TA01992F ↗