journal article·2023-10Open access

Processing porous architectures based on LDH: Synthesis and novel applications

Yasuaki Tokudome, Vanessa Prevot, Naoki Tarutani

Abstract

The processing of porous architectures based on Layered Double Hydroxides (LDH) is reviewed. Especially, a focus was put on porosity in nm and μm ranges that can be prepared via various post-treatments and templating techniques for the enhancement of the original properties. A challenge toward the desired porosity is control of structural ordering as well as crystal growth of LDH. The present review paper is mainly dedicated to summarizing the synthetic approaches to access the porous LDH that have found a wide range of applications such as adsorption/environment purification, catalysis, energy storage & production and bio-applications.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Advanced Photocatalysis Techniques · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Three dimensionally honeycomb layered double hydroxides framework as a novel fiber coating for headspace solid-phase microextraction of phenolic compounds10.1016/j.chroma.2014.04.018 ↗
2. Hierarchical co-based porous layered double hydroxide arrays derived via alkali etching for high-performance supercapacitors10.1038/srep13082 ↗
3. Controlled drug release from antibiotic-loaded layered double hydroxide coatings on porous titanium implants in a mouse model10.1002/jbm.a.35358 ↗
4. Rational design of sandwiched Ni–Co layered double hydroxides hollow nanocages/graphene derived from metal–organic framework for sustainable energy storage10.1021/acssuschemeng.7b01879 ↗
5. pH sensitive nanocomposite hydrogel beads based on carboxymethyl cellulose/layered double hydroxide as drug delivery systems10.1007/s10965-014-0454-z ↗
6. Enhancement of the catalytic activity of Mg/Al layered double hydroxide for glycerol oligomers production10.1039/D1DT03817F ↗
7. Highly conductive Ni steam reforming catalysts prepared by electrodeposition10.1039/b801645c ↗
8. Electrochemical synthesis of novel structured catalysts for H2 production10.1016/j.apcatb.2009.06.028 ↗
9. Bone tissue engineering electrospun scaffolds based on layered double hydroxides with the ability to release vitamin D3: Fabrication, characterization and in vitro study10.1016/j.clay.2019.105434 ↗
10. Role of coating-metallic support interaction in the properties of electrosynthesized Rh-based structured catalysts10.1021/cs501079k ↗
11. Facile preparation of organic-inorganic hydrogels containing silver or essential oil with antimicrobial effects10.1016/j.clay.2020.105567 ↗
12. Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors10.1038/nmat2612 ↗
13. Simple and cost effective fabrication of 3D porous core-shell Ni nanochains@NiFe layered double hydroxide nanosheet bifunctional electrocatalysts for overall water splitting10.1039/C9TA07282A ↗
14. Ag-loaded MgSrFe-layered double hydroxide/chitosan composite scaffold with enhanced osteogenic and antibacterial property for bone engineering tissue10.1002/jbm.b.33900 ↗
15. Template-directed synthesis of sulphur doped NiCoFe layered double hydroxide porous nanosheets with enhanced electrocatalytic activity for the oxygen evolution reaction10.1039/C7TA09734D ↗
16. Acid susceptible ultrathin mesoporous silica coated on layered double hydroxide nanoplates for pH responsive cancer therapy10.1021/acsabm.8b00343 ↗
17. Mn-doped Ni/Co LDH nanosheets grown on the natural N-dispersed PANI-derived porous carbon template for a flexible asymmetric supercapacitor10.1021/acssuschemeng.9b01343 ↗
18. Textural properties of layered double hydroxides: Effect of magnesium substitution by copper or iron10.1016/S1387-1811(01)00387-0 ↗
19. A general method for the synthesis of nanostructured large-surface-area materials through the self-assembly of functionalized nanoparticles10.1002/chem.200400535 ↗
20. Nickel–cobalt layered double hydroxide nanosheets for high-performance supercapacitor electrode materials10.1002/adfm.201301747 ↗
21. Tuneable ultra high specific surface area Mg/Al-CO3 layered double hydroxides10.1039/C5DT02641E ↗
22. Core–shell zeolite@aqueous miscible organic-layered double hydroxides10.1039/C5SC03208C ↗
23. MgAl layered double hydroxide/chitosan porous scaffolds loaded with PFTα to promote bone regeneration10.1039/C7NR00601B ↗
24. ZIF-67@Co-LDH yolk–shell spheres with micro−/meso-porous structures as vehicles for drug delivery10.1039/C9QI00801B ↗
25. A novel strategy to synthesize NiCo layered double hydroxide nanotube from metal organic framework composite for high-performance supercapacitor10.1016/j.jallcom.2020.154794 ↗
26. Synthesis, characterization, ion exchange, and catalytic properties of nanobinary and ternary metal oxy/hydroxides10.1021/cm0481123 ↗
27. New synthetic routes to hydrotalcite-like compounds - Characterisation and properties of the obtained materials10.1002/(SICI)1099-0682(199810)1998:10<1439::AID-EJIC1439>3.0.CO;2-1 ↗
28. Facile route to conformal hydrotalcite coatings over complex architectures: a hierarchically ordered nanoporous base catalyst for FAME production10.1039/C4GC01689K ↗
29. Mesoporous TiO 2 single crystals delivering enhanced mobility and optoelectronic device performance10.1038/nature11936 ↗
30. Heterogeneous photocatalytic degradation of pesticides using decatungstate intercalated macroporous layered double hydroxides10.1007/s11356-014-2971-z ↗
31. Cobalt oxide nanocomposites modified by NiCo-layered double hydroxide nanosheets as advanced electrodes for supercapacitors10.1007/s11581-019-03333-6 ↗
32. A review on the recent advances, challenges and future aspect of layered double hydroxides (LDH) – containing hybrids as promising adsorbents for dyes removal10.1016/j.molliq.2019.110989 ↗
33. Fuzzy nanoassemblies: toward layered polymeric multicomposites10.1126/science.277.5330.1232 ↗
34. Ultrathin porous NiFeV ternary layer hydroxide nanosheets as a highly efficient bifunctional electrocatalyst for overall water splitting10.1002/smll.201703257 ↗
35. Nitrogen-doped graphene quantum dots anchored on NiFe layered double-hydroxide nanosheets catalyze the oxygen evolution reaction10.1039/D0NJ03537H ↗
36. Reduction of graphite oxide using alcohols10.1039/C0JM02704A ↗
37. Duan · 2006
38. Effect of drying step on layered double hydroxides properties: Application in reactive dye intercalation
39. Layered double hydroxide modified WO3 nanorod arrays for enhanced photoelectrochemical water splitting10.1016/j.apcata.2016.09.014 ↗
40. New insights into the arrangement pattern of layered double hydroxide nanosheets and their ion-exchange behavior with phosphate10.1016/j.cej.2022.136057 ↗
41. Correlation among structure, microstructure, and electrochemical properties of NiAl-CO3 layered double hydroxide thin films10.1021/jp300780w ↗
42. A highly active CoFe layered double hydroxide for water splitting10.1002/cplu.201700005 ↗
43. Design of 3D multi-layered electrospun membranes embedding iron-based layered double hydroxide for drug storage and control of sustained release10.1016/j.eurpolymj.2020.109675 ↗
44. Layered double hydroxides (LDH)
45. Electrospun organic–inorganic nanohybrids as sustained release drug delivery systems10.1039/C7TB01825H ↗
46. Use of epoxides in the sol-gel synthesis of porous iron(III) oxide monoliths from Fe(III) salts10.1021/cm0007611 ↗
47. Macroscopically ordered hydrotalcite-type materials using self-assembled colloidal crystal template10.1021/cm051770i ↗
48. Three dimensionally ordered macroporous layered double hydroxides: preparation by templated impregnation/coprecipitation and pattern stability upon calcination10.1021/cm702755h ↗
49. In-syringe extraction using dissolvable layered double hydroxide-polymer sponges templated from hierarchically porous coordination polymers10.1016/j.chroma.2016.05.023 ↗
50. Application of layered double hydroxides for removal of oxyanions: a review10.1016/j.watres.2007.10.043 ↗
51. Layered double hydroxide/sepiolite heterostructured materials10.1016/j.clay.2015.12.011 ↗
52. Hierarchical layered double hydroxide nanocomposites: Structure, synthesis and applications10.1039/C4CC07715F ↗
53. A novel strategy to boost the oxygen evolution reaction activity of NiFe-LDHs with in situ synthesized 3D porous reduced graphene oxide matrix as both the substrate and electronic carrier10.1039/C9NJ00518H ↗
54. Synthesis of unusual coral-like layered double hydroxide microspheres in a nonaqueous polar solvent/surfactant system10.1039/b719817e ↗
55. Direct assembly of anisotropic layered double hydroxide (LDH) nanocrystals on spherical template for fabrication of drug-LDH hollow nanospheres10.1021/cm803203x ↗
56. Mesoporous layer-by-layer ordered nanohybrids of layered double hydroxide and layered metal oxide: Highly active visible light photocatalysts with improved chemical stability10.1021/ja203388r ↗
57. Preparation of CoAl layered double hydroxide nanoflake arrays and their high supercapacitance performance10.1016/j.clay.2014.10.003 ↗
58. Controlled crystal growth of two-dimensional layered nanomaterials in hydrogel via a modified electrical double migration method10.1021/acs.cgd.7b01252 ↗
59. Carbon cloth supported NiAl-layered double hydroxides for flexible application and highly sensitive electrochemical sensors10.1016/j.snb.2014.11.022 ↗
60. Immobilization of anionic iron(III) porphyrins into ordered macroporous layered double hydroxides and investigation of catalytic activity in oxidation reactions10.1016/j.molcata.2009.05.017 ↗
61. Three dimensional hierarchically porous ZIF-8 derived carbon/LDH core-shell composite for high performance supercapacitors10.1016/j.electacta.2017.12.175 ↗
62. Facile assembly of Co-Ni layered double hydroxide nanoflakes on carbon nitride coated N-doped graphene hollow spheres with high electrochemical capacitive performance10.1016/j.electacta.2017.08.158 ↗
63. In-situ optimizing the valence configuration of vanadium sites in NiV-LDH nanosheet arrays for enhanced hydrogen evolution reaction10.1016/j.jechem.2020.02.010 ↗
64. Deterioration of anion-adsorption abilities of layered double hydroxides synthesized in agarose gel10.1016/j.clay.2019.105435 ↗
65. Novel nanocomposite hydrogels consisting of layered double hydroxide with ultrahigh tensibility and hierarchical porous structure at low inorganic content10.1002/adma.201400179 ↗
66. Hierarchical porous Ni/Co-LDH hollow dodecahedron with excellent adsorption property for Congo red and Cr(VI) ions10.1016/j.apsusc.2019.02.008 ↗
67. Adsorption removal of Congo red over flower-like porous microspheres derived from Ni/Al layered double hydroxide10.1039/C5RA13922H ↗
68. Bioactive nanocomposite poly (ethylene glycol) hydrogels crosslinked by multifunctional layered double hydroxides nanocrosslinkers10.1002/mabi.201600054 ↗
69. Size-selective adsorption of anionic dyes induced by the layer space in layered double hydroxide hollow microspheres10.1039/C7QM00079K ↗
70. Rapid cationic defect and anion dual-regulated layered double hydroxides for efficient water oxidation10.1039/C8NR04402C ↗
71. High performance Ni catalysts prepared by freeze drying for efficient dry reforming of methane
72. An ordered mesoporous organosilica hybrid material with a crystal-like wall structure10.1038/416304a ↗
73. Efficient production of MgAl layered double hydroxide nanoparticle10.2109/jcersj2.18140 ↗
74. Synthesis of CuAl hydrotalcite-SBA-15 composites and CO2 capture using the sorbent10.1016/j.apsusc.2019.03.039 ↗
75. Preparation of borate anions intercalated MgAl-LDHs microsphere and its calcinated product with superior adsorption performance for Congo red10.1016/j.colsurfa.2019.05.032 ↗
76. Formation of hierarchical structure composed of (Co/Ni)Mn-LDH nanosheets on MWCNT backbones for efficient electrocatalytic water oxidation10.1021/acsami.6b02733 ↗
77. Self-templating synthesis of hollow NiFe hydroxide nanospheres for efficient oxygen evolution reaction10.1016/j.electacta.2020.136869 ↗
78. LDH nanocages synthesized with MOF templates and their high performance as supercapacitors10.1039/c3nr03829g ↗
79. Synthesis of mesoporous Silica@Co–Al layered double hydroxide spheres: layer-by-layer method and their effects on the flame retardancy of epoxy resins10.1021/am503412y ↗
80. Fabrication of layered double hydroxide microspheres by spray drying of nanoparticles: Effects of process conditions10.1016/j.matlet.2017.08.067 ↗
81. Surface engineering of graphene oxide shells using lamellar LDH nanostructures10.1021/acsami.8b21265 ↗
82. Preparation of pH-responsive hollow capsules via layer-by-layer assembly of exfoliated layered double hydroxide nanosheets and polyelectrolytes10.1166/jnn.2018.14590 ↗
83. Preparation of hydrotalcite thin films using an electrophoretic technique10.1021/ie071446s ↗
84. Effect of particle size and local disorder on specific surface area of layered double hydroxides upon calcination-reconstruction10.1016/j.jssc.2018.03.041 ↗
85. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism10.1038/359710a0 ↗
86. Controllable preparation of multi-dimensional hybrid materials of nickel-cobalt layered double hydroxide nanorods/nanosheets on electrospun carbon nanofibers for high-performance supercapacitors10.1016/j.electacta.2015.06.031 ↗
87. Functionalized layered double hydroxides for innovative applications10.1039/C9MH01494B ↗
88. Layered double hydroxide and polypeptide thermogel nanocomposite system for chondrogenic differentiation of stem cells10.1021/acsami.7b17173 ↗
89. Improved electrochemical performances of MOF-derived Ni–Co layered double hydroxide complexes using distinctive hollow-in-hollow structures10.1039/C9TA05138D ↗
90. Organic dye removal from aqueous solutions by hierarchical calcined Ni-Fe layered double hydroxide: Isotherm, kinetic and mechanism studies10.1016/j.jcis.2017.02.025 ↗
91. Delamination and restacking of layered double hydroxides10.1039/b002955f ↗
92. In situ assembly of layered double hydroxide nano-crystallites within silica mesopores and its high solid base catalytic activity10.1039/b717876j ↗
93. Structure and basicity of mesoporous materials from Mg/Al/In layered double hydroxides prepared by separate nucleation and aging steps method10.1007/s10934-005-5234-z ↗
94. Hollow nanoshell of layered double hydroxide10.1039/b605889b ↗
95. A novel approach to hierarchical sphere-like ZnAl-layered double hydroxides and their enhanced adsorption capability10.1039/c4ta01028k ↗
96. Fast electrosynthesis of Fe-containing layered double hydroxide arrays toward highly efficient electrocatalytic oxidation reactions10.1039/C5SC02417J ↗
97. Promoted VOC oxidation over homogeneous porous CoXNiAlO composite oxides derived from hydrotalcites: Effect of preparation method and doping10.1039/C6RA08394C ↗
98. Design and synthesis of Ni-Co and Ni-Mn layered double hydroxides hollow microspheres for supercapacitor10.1016/j.ijhydene.2017.10.019 ↗
99. Deep eutectic solvents assisted synthesis of MgAl layered double hydroxide with enhanced adsorption toward anionic dyes10.1016/j.colsurfa.2020.124507 ↗
100. Core-shell NiO/C@NiFe-LDH nanocomposite as an efficient electrocatalyst for oxygen evolution reaction