journal article·2023-03

Enhanced bifunctional adsorption of anionic and cationic pollutants by MgAl LDH nanosheets modified montmorillonite via acid-salt activation

Xingjian Dai, Chuan Jing, Kailin Li, Xiaotian Zhang, Dan Song, Li Feng, Xiaoying Liu, Hui Ding, Haodi Ran, Kangwen Zhu, Nan Dai, Shuang Yi, Jinsong Rao, Yuxin Zhang

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Abstract

A novel H + and Cl − intercalated montmorillonite@MgAl LDH (MMT-N) nanocomposite was prepared by a one-step hydrothermal method following acid-salt treatment. The MMT-N prepared by the advanced modification method contains low CO2–3contamination, high specific surface area, and high porosity. By enhancing the ion exchange of montmorillonite and LDH, efficient removal of anionic and anionic dyes was achieved without the introduction of another cation contamination. The adsorption kinetics of methyl orange (MO) and methylene blue (MB) are in accordance with the pseudo-second-order model, and the maximum adsorption amounts of methylene blue and methyl orange reached 815.998 mg g −1 and 399.836 mg g −1, respectively. The coefficient of determination (R 2 ) and the corrected Akaike Information Criterion (AICc) revealed that the adsorption isotherm data of MO and MB on MMT-80 fitted well with Freundlich isotherm, signifying that the adsorption process was dominated by chemisorption. And the adsorption of MO and MB by MMA-80 was endothermic and exothermic, respectively. The “intercalation-split mechanism” and “ion exchange” mechanisms of MO and MB in MMA-80 were also investigated. This study provides an efficient method for the synthesis of high-performance bifunctional adsorbents for cationic and anionic pollutants and offers potential applications for practical wastewater purification.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Layered Double Hydroxides Synthesis and Applications · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (57)

Show source-provided references
1. Adsorption of anionic and cationic dyes from aqueous solution on non-calcined Mg-Al layered double hydroxide: experimental and theoretical study10.1080/01496395.2013.804837 ↗
2. Adsorption of methyl orange from aqueous solution on hydrothermal synthesized Mg-Al layered double hydroxide10.1021/je200743u ↗
3. Removal of methylene blue from aqueous solution by montmorillonite/CoFe2O4 composite with magnetic separation performance10.1016/j.desal.2010.08.004 ↗
4. Experimental adsorption water desalination system utilizing activated clay for low grade heat source applications10.1016/j.est.2021.103219 ↗
5. Adsorption of reactive dyes from aqueous solutions by layered double hydroxides10.1002/jctb.2755 ↗
6. Heteropoly blue-intercalated layered double hydroxides for cationic dye removal from aqueous media10.1016/j.clay.2011.09.003 ↗
7. Modifying the composition and adsorption properties of a montmorillonite surface layer by acidic activation
8. Acid-salt treated CoAl layered double hydroxide nanosheets with enhanced adsorption capacity of methyl orange dye10.1016/j.jcis.2019.03.107 ↗
9. Adsorption characteristics of montmorillonite clay modified with iron oxide with respect to methylene blue in aqueous media10.1016/j.clay.2014.03.023 ↗
10. 2D-3D graphene-coated diatomite as a support toward growing ZnO for advanced photocatalytic degradation of methylene blue10.1039/D1RA07708B ↗
11. Magnetic double-core@shell MnO2@NiFe@DE as a multifunctional scavenger for efficient removal of tetracycline, anionic and cationic dyes10.1016/j.jcis.2022.07.187 ↗
12. 2D-3D magnetic NiFe layered double hydroxide decorated diatomite as multi-function material for anionic, cationic dyes, arsenate, and arsenite adsorption10.1016/j.clay.2022.106664 ↗
13. One-step coprecipitation synthesis of Cl− intercalated Fe3O4@SiO2@MgAl LDH nanocomposites with excellent adsorption performance toward three dyes
14. Investigation of the initial stages of the montmorillonite acid-activation process using DFT calculations10.1016/j.clay.2018.08.012 ↗
15. A facile approach to prepare porous cup-stacked carbon nanotube with high performance in adsorption of methylene blue10.1016/j.jcis.2014.12.078 ↗
16. Adsorption performance and mechanistic study of heavy metals by facile synthesized magnetic layered double oxide/carbon composite from spent adsorbent10.1016/j.cej.2019.123331 ↗
17. Preparation and characterization of magnetic Fe3O4@sulfonated -cyclodextrin intercalated layered double hydroxides for methylene blue removal10.1080/19443994.2016.1155173 ↗
18. Deintercalation of carbonate ions and anion exchange of an Al-rich MgAl-LDH (layered double hydroxide)10.1016/j.clay.2008.01.016 ↗
19. Effects of anion species on deintercalation of carbonate ions from hydrotalcite-like compounds10.1246/cl.2005.932 ↗
20. Deintercalation of carbonate ions from carbonate-type layered double hydroxides (LDHs) using acid-alcohol mixed solutions10.1016/j.clay.2011.07.017 ↗
21. 2D-2D growth of NiFe LDH nanoflakes on montmorillonite for cationic and anionic dye adsorption performance10.1016/j.jcis.2019.01.022 ↗
22. Low Carbonate Contaminative and Ultrasmall NiAl LDH prepared by Acid Salt Treatment with High Adsorption Capacity of Methyl Orange10.1021/acs.iecr.9b01706 ↗
23. Synthesis of an efficient hydroxyapatite-chitosan-montmorillonite thin film for the adsorption of anionic and cationic dyes: adsorption isotherm, kinetic and thermodynamic study10.1007/s42452-020-2848-3 ↗
24. Treatment of hydrochloric acid using Mg-Al layered double hydroxide intercalated with carbonate10.1016/j.jiec.2016.04.018 ↗
25. Preparation of Zn-Al layered double hydroxide intercalated with carboxymethyl-beta-cyclodextrin by anion exchange method and its Ni2+ adsorption property10.1080/1539445X.2020.1779088 ↗
26. Novel Al-doped carbon nanotubes with adsorption and coagulation promotion for organic pollutant removal10.1016/j.jes.2016.04.022 ↗
27. Dyes adsorption using clay and modified clay: a review10.1016/j.molliq.2018.02.034 ↗
28. Chemical and thermal properties of organoclays derived from highly stable bentonite in sulfuric acid10.1016/j.clay.2013.07.022 ↗
29. Organic dye removal from aqueous solutions by hierarchical calcined Ni-Fe layered double hydroxide: isotherm, kinetic and mechanism studies10.1016/j.jcis.2017.02.025 ↗
30. Superb adsorption capacity of hierarchical calcined Ni/Mg/Al layered double hydroxides for Congo red and Cr(VI) ions10.1016/j.jhazmat.2016.09.070 ↗
31. Fulvic acid anchored layered double hydroxides: a multifunctional composite adsorbent for the removal of anionic dye and toxic metal10.1016/j.jhazmat.2017.09.006 ↗
32. Biosynthesis based membrane filtration coupled with iron nanoparticles reduction process in removal of dyes10.1016/j.cej.2020.124202 ↗
33. MOFs meet wood: Reusable magnetic hydrophilic composites toward efficient water treatment with super-high dye adsorption capacity at high dye concentration10.1016/j.cej.2022.136851 ↗
34. Synthesis, characterization, and application of Co-Al-Zn layered double hydroxide/hydrochar composite for simultaneous removal of cationic and anionic dyes
35. Anomalous but massive removal of two organic dye pollutants simultaneously10.1016/j.jhazmat.2016.06.044 ↗
36. Simultaneous removal process of divalent metal and anionic and cationic dyes by layered reconstruction with hydrocalumite intercalated with dodecyl sulfate
37. Carboxymethyl chitosan modified montmorillonite for efficient removal of cationic dye from waste water10.14429/dsj.64.7318 ↗
38. Application of zirconium modified layered double hydroxide and calcination product for adsorptive removal of phosphate from aqueous solution10.1002/ep.13744 ↗
39. Natural core-shell structure activated carbon beads derived from Litsea glutinosa seeds for removal of methylene blue: Facile preparation, characterization, and adsorption properties
40. Surface induced growth of ZIF-67 at Co-layered double hydroxide: removal of methylene blue and methyl orange from water
41. The effect of the molecular structure of a cationic azo dye on the photoinduced intercalation of phenol in a montmorillonite10.1016/j.clay.2007.09.001 ↗
42. Removal of colorants from wastewater: a review on sources and treatment strategies10.1016/j.jiec.2019.02.011 ↗
43. Adsorptive removal of cationic and anionic dyes on a novel mesoporous adsorbent prepared from diatomite and anionic cellulose nanofibrils: experimental and theoretical investigations10.1016/j.molliq.2022.119670 ↗
44. Statistical analysis of adsorption isotherm models and its appropriate selection10.1016/j.chemosphere.2021.130176 ↗
45. X-ray photoelectron spectroscopic study of montmorillonite containing exchangeable divalent cations10.1039/f19848000237 ↗
46. Magnetic Fe3O4/MgAl-LDH composite for effective removal of three red dyes from aqueous solution10.1016/j.cej.2014.04.105 ↗
47. Microwave-enhanced advanced oxidation processes for the degradation of dyes in water10.1007/s10311-018-0739-2 ↗
48. Rational design and synthesis of monodispersed hierarchical SiO2@layered double hydroxide nanocomposites for efficient removal of pollutants from aqueous solution10.1016/j.cej.2017.03.158 ↗
49. Synthesis of novel amine modified hollow mesoporous silica@Mg-Al layered double hydroxide composite and its application in CO2 adsorption10.1016/j.micromeso.2017.02.077 ↗
50. Novel Two-Dimensional magnetic Titanium Carbide for Methylene Blue Removal over a Wide pH Range: Insight into Removal Performance and Mechanism10.1021/acsami.9b04222 ↗
51. Systematic screening of layered double hydroxides for phosphate removal and mechanism insight10.1016/j.clay.2019.03.030 ↗
52. Preparation of acid-activated montmorillonite and its application10.1080/1064119X.2015.1080335 ↗
53. Hierarchical flower-like nickel(II) oxide microspheres with high adsorption capacity of Congo red in water10.1016/j.jcis.2017.06.014 ↗
54. The integrated utilization of typical clays in removal of organic dyes and polymer nanocomposites10.1016/j.jclepro.2014.06.038 ↗
55. Recent progress in layered double hydroxides (LDH)-containing hybrids as adsorbents for water remediation10.1016/j.clay.2017.04.002 ↗
56. Starch-NiFe-layered double hydroxide composites: efficient removal of methyl orange from aqueous phase10.1016/j.molliq.2017.11.022 ↗
57. Sustainable wastewater treatment by biochar/layered double hydroxide composites: progress, challenges, and outlook10.1016/j.biortech.2020.124128 ↗