journal article·2021-01

Synthesis of NaA-zeolite microspheres by conversion of geopolymer and their performance of Pb (II) removal

Qiaoqiao Su, Yan He, Sijie Yang, Hengyu Wan, Shan Chang, Xuemin Cui

Publisher page

Abstract

Abstract A simple and sustainable preparation process for converting metakaolin-based geopolymers into NaA-zeolite microspheres (NaA-ZMs) via suspension dispersion method under mild condition was explored. Then NaA-ZMs used for static and dynamic Pb (II) removal. The maximum adsorbed amount (Qmax) and removal rate (Rmax) of the static removal were 584 mg/g and 99.99% respectively. The Qmax and Rmax of the dynamic removal were 880 mg/g and 74.5% respectively. It could be concluded that NaA-ZMs could be excellent Pb (II) adsorbents whether in the static or the dynamic removals. Because the ions exchange between Na (I) and Pb (II) is the main removal mechanism, the morphology of NaA-ZMs damaged slightly after Pb (II) adsorption. Moreover, the specific surface area, average pore diameter and pore volume of the NaA-ZMs between before and after Pb (II) adsorption changed from 3.82 m2/g, 4.62 nm and 0.004 cm3/g to 163.79 m2/g, 2.42 nm and 0.099 cm3/g, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Concrete and Cement Materials Research · Chemical Synthesis and Characterization · Recycling and utilization of industrial and municipal waste in materials production

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Adsorption thermodynamics of trichloroacetic acid herbicide on polypyrrole Th(IV) phosphate composite cation-exchanger10.1016/j.cej.2011.02.046 ↗
2. Excellent adsorptive performance of a new nanocomposite for removal of toxic Pb(II) from aqueous environment: adsorption mechanism and modeling analysis10.1016/j.jhazmat.2019.121896 ↗
3. Nitrogen doped graphene as potential material for hydrogen storage10.4236/graphene.2017.62004 ↗
4. Adsorption of lead on lentil husk in fixed bed column bioreactor10.1016/j.biortech.2019.02.133 ↗
5. Ion exchange removal of Cu(II), Fe(II), Pb(II) and Zn(II) from acid extracted sewage sludge - Resin screening in weak acid media10.1016/j.watres.2019.04.042 ↗
6. Effect of contact time, pH, humic acid and temperature on the sorption of radionuclide Am(III) onto attapulgite10.1007/s10967-011-1573-1 ↗
7. Experimental and modelling studies on fixed bed adsorption for Cu(II) removal from aqueous solution by carboxyl modified jute fiber10.1016/j.powtec.2018.06.015 ↗
8. Continuous fixed-bed adsorption of Mo(VI) from aqueous solutions by Mo(VI)-IIP: breakthrough curves analysis and mathematical modeling10.1016/j.jece.2020.104079 ↗
9. Graphene oxide wrapped melamine sponge as an efficient and recoverable adsorbent for Pb(II) removal from fly ash leachate10.1016/j.jhazmat.2018.12.053 ↗
10. Adsorption studies of molasse’s wastewaters on activated carbon: modelling with a new fractal kinetic equation and evaluation of kinetic models10.1016/j.jhazmat.2008.04.006 ↗
11. Highly-effective removal of Pb by co-pyrolysis biochar derived from rape straw and orthophosphate10.1016/j.jhazmat.2019.02.079 ↗
12. Facile fabrication of green geopolymer/alginate hybrid spheres for efficient removal of Cu(II) in water: batch and column studies10.1016/j.cej.2016.11.079 ↗
13. Selective adsorption of toxic heavy metal ions using guanine-functionalized mesoporous silica [SBA-16-g] from aqueous solution10.1016/j.micromeso.2019.109577 ↗
14. Preparation and characterization of amino/thiol bifunctionalized magnetic nanoadsorbent and its application in rapid removal of Pb (II) from aqueous system10.1016/j.jhazmat.2019.01.035 ↗
15. Study on the performance of metakaolin based geopolymer for Mn(II) and Co(II) removal10.1016/j.clay.2018.04.027 ↗
16. In situ preparation of magnetic hydrochar by co-hydrothermal treatment of waste vinasse with red mud and its adsorption property for Pb(II) in aqueous solution10.1016/j.jhazmat.2020.122391 ↗
17. Synthesis of geopolymer-supported zeolites via robust one-step method and their adsorption potential10.1016/j.jhazmat.2018.04.049 ↗
18. Development of synthetic zeolites from bio-slag for cesium adsorption: kinetic, isotherm and thermodynamic studies10.1016/j.jwpe.2019.101055 ↗
19. Removal of Pb (II) and Cu (II) from aqueous solutions by NaA zeolite coated magnetic nanoparticles and optimization of method using experimental design10.1016/j.micromeso.2017.04.032 ↗
20. Zeolite-supported nanoscale zero-valent iron: new findings on simultaneous adsorption of Cd(II), Pb(II), and as(III) in aqueous solution and soil10.1016/j.jhazmat.2017.09.036 ↗
21. Hydrothermal synthesis of needle-like nanocrystalline zeolites from metakaolin and their applications for efficient removal of organic pollutants and heavy metals10.1016/j.micromeso.2018.06.015 ↗
22. Mechanical strength and cationic dye adsorption ability of metakaolin-based geopolymer spheres10.1016/j.clay.2020.105678 ↗
23. A new strategy for the electrolytic removal of organics based on adsorption onto granular activated carbon10.1016/j.elecom.2018.04.003 ↗
24. Geopolymer-zeolite composites: A review10.1016/j.jclepro.2019.05.152 ↗
25. Multi-component adsorption of Pb(II), Cd(II) and Ni(II) onto microwave functionalized cellulose: Kinetics, isotherms, thermodynamics, mechanisms and application for electroplating wastewater purification10.1016/j.jhazmat.2019.121718 ↗
26. Co-precipitation strategy for engineering pH-tolerant and durable ZnO@MgO nanospheres for efficient, room-temperature, chemisorptive removal of Pb(II) from water10.1016/j.jece.2019.103019 ↗
27. Fly ash based geopolymer for the adsorption of anionic surfactant from aqueous solution10.1016/j.jclepro.2019.04.384 ↗
28. Prepared self-growing supported nickel catalyst by recovering Ni (II), from metal wastewater using geopolymer microspheres10.1016/j.jhazmat.2019.121919 ↗
29. Prepared self-growth supported copper catalyst by recovering Cu (II) from wastewater using geopolymer microspheres10.1016/j.jclepro.2020.122571 ↗
30. Preparation and characterization of porous metakaolin-based inorganic polymer spheres as an adsorbent10.1016/j.matdes.2015.09.126 ↗
31. Study on synthesis and characterization of ZSM-20 zeolites from metakaolin-based geopolymers10.1016/j.clay.2016.05.011 ↗
32. Synthesis of highly efficient porous inorganic polymer microspheres for the adsorptive removal of Pb2+ from wastewater10.1016/j.jclepro.2018.05.094 ↗
33. Study of Cu (II), Co (II), Ni (II) and Pb (II) removal from aqueous solutions using magnetic Prussian blue nano-sorbent10.1016/j.jhazmat.2019.02.039 ↗
34. Treatment of acid mine drainage by forward osmosis: Heavy metal rejection and reverse flux of draw solution constituents10.1016/j.cej.2017.09.034 ↗
35. One-pot preparation of NaA zeolite microspheres for highly selective and continuous removal of Sr(II) from aqueous solution10.1021/acssuschemeng.8b05349 ↗
36. Early mechanical properties and microstructural evolution of slag/metakaolin-based geopolymers exposed to karst water10.1016/j.cemconcomp.2019.03.009 ↗
37. Accelerated crystallization of magnetic 4A-zeolite synthesized from red mud for application in removal of mixed heavy metal ions10.1016/j.jhazmat.2018.07.007 ↗
38. Investigation on the efficiency and mechanism of Cd(II) and Pb(II) removal from aqueous solutions using MgO nanoparticles10.1016/j.jhazmat.2015.08.008 ↗
39. An integrated process of chemical precipitation and sulfate reduction for treatment of flue gas desulphurization wastewater from coal-fired power plant10.1016/j.jclepro.2019.04.227 ↗
40. Facile preparation of hierarchically porous diatomite/MFI-type zeolite composites and their performance of benzene adsorption: the effects of NaOH etching pretreatment10.1016/j.jhazmat.2014.11.034 ↗
41. Fixed bed column and artificial neural network model to predict heavy metals adsorption dynamic on surfactant decorated graphene10.1016/j.colsurfa.2019.124076 ↗
42. Selective removal of Pb(II), Cd(II), and Zn(II) ions from waters by an inorganic exchanger Zr(HPO3S)210.1016/j.jhazmat.2009.05.038 ↗
43. Computational study of particle packing process and fluid flow inside Polydisperse cylindrical particles fixed beds10.1016/j.powtec.2019.05.061 ↗
44. Effect of water-binding ability of amorphous gel on the rheology of geopolymer fresh pastes with the different NaOH content at the early age10.1016/j.conbuildmat.2020.120529 ↗
45. A high-flux and anti-interference dual-functional membrane for effective removal of Pb(II) from natural water10.1016/j.jhazmat.2019.121492 ↗