journal article·2020-03Open access

Fenton-like degradation of methylene blue using Mg/Fe and MnMg/Fe layered double hydroxides as reusable catalysts

Rosembergue Gabriel Lima Gonçalves, Hana Moreira Mendes, Sibele Lima Bastos, Lídia Cristina D'Agostino, Jairo Tronto, Sandra Helena Pulcinelli, Celso Valentim Santilli, Jonas Leal Neto

Abstract

Abstract In this work, the Layered Double Hydroxide (LDH) containing magnesium (Mg) and iron (Fe) was modified with Mn to investigate the effect of the addition from the structural and catalytic point of view. These materials were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), N2 adsorption-desorption isotherms, X-ray photoelectron spectroscopy (XPS), thermogravimetric analyses, and evaluated as heterogeneous catalysts in Fenton-like reaction. The results showed that the Mn was incorporated in the LDH, promoting structural changes such as reduction of crystallographic parameters, decrease of crystallite size, and increase of surface area. The removal of methylene blue (MB) in aqueous solutions by LDH with and without Mn showed better results with increasing catalyst dosage, H2O2 volume, and temperature; and that under the best reaction conditions, the MnMgFe-LDH was the catalyst more efficient in removing MB, being reused for 5 reaction cycles with more than 80% removal.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Advanced Photocatalysis Techniques · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (61)

Show source-provided references
1. Graphene/Fe3O4 nanocomposite: Interplay between photo-Fenton type reaction, and carbon purity for the removal of methyl orange10.1016/j.ceramint.2017.08.157 ↗
2. Degradation of sulfamethazine antibiotics in Fenton-like system using Fe3O4 magnetic nanoparticles as catalyst10.1002/ep.12639 ↗
3. Catalytic activity of Fe3−xCuxO4 (0 ≤ x ≤ 0.25) nanoparticles for the degradation of Amaranth food dye by heterogeneous electro-Fenton process10.1016/j.apcatb.2015.06.048 ↗
4. Layered double hydroxides: new technology in phosphate fertilizers based on nanostructured materials10.1021/acssuschemeng.6b01784 ↗
5. Layered double hydroxides as hosting matrices for storage and slow release of phosphate analyzed by stirred-flow method
6. Synthesis and characterization of Mg-Fe layer double hydroxides and its application on adsorption of Orange G from aqueous solution10.1016/j.cej.2011.03.019 ↗
7. Characterization and evaluation of ZnO/CuO catalyst in the degradation of methylene blue using solar radiation10.1016/j.ceramint.2019.03.239 ↗
8. XAS/WAXS time-resolved phase speciation of chlorine LDH thermal transformation: emerging roles of isovalent metal substitution10.1021/cm401352t ↗
9. Co-Fe hydrotalcites for efficient removal of dye pollutants: Via synergistic adsorption and degradation10.1039/C7RA07417D ↗
10. Remarkable effect of Co and Mn on the activity of Fe3−xMxO4 promoted oxidation of organic contaminants in aqueous medium with H2O210.1016/j.catcom.2003.08.002 ↗
11. Efficient dye degradation catalyzed by manganese oxide nanoparticles and the role of cation valence
12. Carbonate–hydrogenocarbonate coexistence and dynamics in layered double hydroxides10.1021/acs.jpcc.6b12192 ↗
13. Facile synthesis of ZnAl-EDTA layered double hydroxide/poly (vinyl alcohol) nanocomposites as an efficient adsorbent of Cd(II) ions from the aqueous solution10.1016/j.clay.2019.01.007 ↗
14. Copper-doped akaganeite: application in catalytic Cupro-Fenton reactions for oxidation of methylene blue10.1016/j.molcata.2016.08.034 ↗
15. Adsorption of Acid Yellow 42 dye on calcined layered double hydroxide: effect of time, concentration, pH and temperature10.1016/j.clay.2017.02.005 ↗
16. Enhanced catalytic oxidation ability of ternary layered double hydroxides for organic pollutants degradation10.1039/C6DT00441E ↗
17. The effect of iron on the crystalline phases formed upon thermal decomposition of Mg-Al-Fe hydrotalcites10.1039/a804867c ↗
18. Thermal decomposition and structural reconstruction effect on Mg-Fe-based hydrotalcite compounds10.1016/j.jssc.2004.04.030 ↗
19. Performance of magnetite/layered double hydroxide composite for dye removal via adsorption, Fenton and photo-Fenton processes10.1016/j.clay.2019.105152 ↗
20. The iron oxidation state in Mg-Al-Fe mixed oxides derived from layered double hydroxides: an XPS study10.1016/j.apsusc.2008.01.063 ↗
21. Manganese substituted cobalt ferrites as efficient catalysts for H2O2 assisted degradation of cationic and anionic dyes: their synthesis and characterization10.1016/j.apcata.2014.08.020 ↗
22. Roles of Mg-Al layered double hydroxides and solution chemistry on P transport in soil10.1016/j.cej.2019.05.083 ↗
23. Manganese oxide nanorods as a robust Fenton-like catalyst at neutral pH: Crystal phase-dependent behavior10.1016/j.cattod.2016.03.034 ↗
24. Thermal behaviour of synthetic pyroaurite-like anionic clay10.1023/A:1023305605305 ↗
25. Structure and surface chemistry of manganese-doped copper-based mixed metal oxides derived from layered double hydroxides10.1016/j.colsurfa.2004.06.022 ↗
26. Ternary NiFeMn layered double hydroxides as highly-efficient oxygen evolution catalysts10.1039/C5CC08845C ↗
27. Investigation of thermal behavior of layered double hydroxides intercalated with carboxymethylcellulose aiming bio-carbon based nanocomposites
28. Boron as a promoter in the goethite (α-FeOOH) phase: organic compound degradation by Fenton reaction10.1016/j.apcatb.2016.03.051 ↗
29. Evaluation of advanced oxidation processes for water and wastewater treatment – a critical review10.1016/j.watres.2018.03.042 ↗
30. Preparation of magnetite-based catalysts and their application in heterogeneous Fenton oxidation - a review10.1016/j.apcatb.2015.04.003 ↗
31. Naturally-occurring iron minerals as inexpensive catalysts for CWPO10.1016/j.apcatb.2016.10.015 ↗
32. Sunlight photodecolorization of a mixture of Methyl Orange and Bromocresol Green by CuS incorporated in a clinoptilolite zeolite as a heterogeneous catalyst10.1016/j.jiec.2013.01.006 ↗
33. Magnetic LDH-based CoO–NiFe2O4 catalyst with enhanced performance and recyclability for efficient decolorization of azo dye via Fenton-like reactions10.1016/j.apcatb.2018.10.050 ↗
34. Incorporation of Fe3+ into Mg/Al layered double hydroxide framework: Effects on textural properties and photocatalytic activity for H2 generation10.1039/c2jm15658j ↗
35. Green fabrication of magnetic recoverable graphene/MnFe2O4 hybrids for efficient decomposition of methylene blue and the Mn/Fe redox synergetic mechanism10.1039/C6RA24320G ↗
36. Multipath fabrication of hierarchical CuAl layered double hydroxide/carbon fiber composites for the degradation of ammonia nitrogen10.1016/j.jenvman.2018.05.037 ↗
37. Heterogeneous photo-Fenton degradation of organics using highly efficient Cu-doped LaFeO3 under visible light10.1016/j.jiec.2017.11.046 ↗
38. Zn-Al layered double hydroxides as efficient photocatalysts for NOx abatement10.1016/j.cej.2018.04.022 ↗
39. Rouquerol · 1999
40. Mn-Fe layered double hydroxide nanosheets: a new photothermal nanocarrier for O2-evolving phototherapy10.1039/C8CC06033A ↗
41. Ca–Mg–Al ternary mixed oxides derived from layered double hydroxide for selective etherification of glycerol to short-chain polyglycerols10.1016/j.clay.2019.03.006 ↗
42. Antiproliferative effects of new magnetic pH-responsive drug delivery system composed of Fe3O4, CaAl layered double hydroxide and levodopa on melanoma cancer cells10.1016/j.msec.2019.04.004 ↗
43. Nb-containing hematites Fe2-xNbxO3: the role of Nb5+ on the reactivity in presence of the H2O2 or ultraviolet light10.1016/j.apcata.2009.01.014 ↗
44. The simultaneous anionic and cationic dyes removal with Zn–Al layered double hydroxides10.1016/j.clay.2019.105183 ↗
45. Highly enhanced photoelectrochemical water oxidation efficiency based on triadic quantum dot/layered double hydroxide/BiVO4 photoanodes10.1021/acsami.6b04937 ↗
46. Effect of manganese substitution on the physicochemical properties and catalytic toluene oxidation activities of Mg-Al layered double hydroxides10.1016/S1387-1811(99)00123-7 ↗
47. Heterogeneous activation of hydrogen peroxide using γ-Al2O3 supported bimetallic Fe, Mn for the degradation of reactive black 510.1039/C5RA22128E ↗
48. Effective degradation of phenol via Fenton reaction over CuNiFe layered double hydroxides10.1016/j.jhazmat.2018.03.053 ↗
49. Formation of copper hydroxy double salts derived from metal oxides and their catalytic activity in degradation of methyl orange10.1016/j.ceramint.2018.09.278 ↗
50. Ti-based layered double hydroxides: efficient photocatalysts for azo dyes degradation under visible light10.1016/j.apcatb.2013.07.060 ↗
51. Ternary MgO/ZnO/In2O3 heterostructured photocatalysts derived from a layered precursor and visible-light-induced photocatalytic activity10.1016/j.cej.2013.02.030 ↗
52. Adsorption behavior and mechanism of Mg/Fe layered double hydroxide with Fe3O4-carbon spheres on the removal of Pb (II) and Cu(II)10.1016/j.jcis.2018.10.066 ↗
53. TiO 2– x -modified ni nanocatalyst with tunable metal–support interaction for water–gas shift reaction10.1021/acscatal.7b01951 ↗
54. Water content and particle texture of synthetic hydrotalcite-like layered double hydroxides10.1021/cm00050a017 ↗
55. Copper hydroxyphosphate as catalyst for the wet hydrogen peroxide oxidation of azo dyes10.1016/j.jhazmat.2010.04.055 ↗
56. Formation of Fe3O4@MnO2 ball-in-ball hollow spheres as a high performance catalyst with enhanced catalytic performances
57. Degradation of bisphenol a by Fe-Al layered double hydroxides: a new synergy of homo- and heterogeneous Fenton systems10.1016/j.jcis.2019.05.040 ↗
58. A new hydrotalcite-like absorbent FeMnMg-LDH and its adsorption capacity for Pb2+ ions in water10.1016/j.clay.2017.11.033 ↗
59. Anti-metastatic and anti-angiogenic activities of core–shell SiO2@LDH Loaded with etoposide in non-small cell lung cancer10.1002/advs.201600229 ↗
60. Efficient degradation of organic pollutants by peroxymonosulfate activated with MgCuFe-layered double hydroxide10.1039/C8RA09841G ↗
61. Recent progress in layered double hydroxides (LDH)-containing hybrids as adsorbents for water remediation10.1016/j.clay.2017.04.002 ↗