Layered clay minerals, synthetic layered double hydroxides and hydroxide salts applied as pickering emulsifiers
Source abstract
Abstract
Abstract Clay mineral particles have longstanding applications in many semisolid formulations produced by the cosmetic and pharmaceutical industries, due to the good physical-chemical properties of the particles in dispersion. They are usually in the colloidal size range and can be easily intercalated/grafted with organic species, modulating the dispersion viscosity, with the added advantage of being eco-friendly. However, despite the longstanding application of clay minerals such as kaolinite and montmorillonite, the number of studies focused on understanding the behavior of such particles when dispersed in emulsions is scarce. Furthermore, studies of the application of synthetic layered double hydroxides and layered hydroxide salts are even rarer than those of clay minerals. Therefore, this short review presents the state of the art of the use of clay minerals and the former species in Pickering emulsions and provides perspectives for future research.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Pickering emulsions and particle stabilization · Clay minerals and soil interactions · Layered Double Hydroxides Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Bentonite and double hydroxides as emulsifying agents10.1180/0009855013640009 ↗
2. Stabilization of emulsions by heterocoagulation of clay minerals and layered double hydroxides10.1007/s003960050303 ↗
3. The crystal structure of gordaite NaZn4(SO4)(OH)6Cl • 6 H2O
4. Effect of kaolinite on water-in-oil emulsion formed by steam injection during tertiary oil recovery: a case study of an omani heavy oil sandstone reservoir with a high kaolinite sludge content10.1021/acs.energyfuels.6b01822 ↗
5. Shape-anisotropic colloids at interfaces
6. Layered hydroxide salts: synthesis, properties and potential applications10.1016/j.ssi.2007.04.016 ↗
7. Cu2+ ions as a paramagnetic probe to study the surface chemical modification process of layered double hydroxides and hydroxide salts with nitrate and carboxylate anions10.1016/j.jcis.2007.12.025 ↗
8. Pickering emulsions stabilised by laponite clay particles10.1039/b007098j ↗
9. Proton adsorption and electrokinetics of an argentinean montmorillonite10.1006/jcis.1998.5402 ↗
10. Emulsions stabilised solely by colloidal particles10.1016/S0001-8686(02)00069-6 ↗
11. Aspects of the Stabilisation of Emulsions by Solid Particles: Effects of line tension and monolayer curvature energy10.1039/b210687f ↗
12. Kaolinite in Pharmaceutics and Biomedicine10.1016/j.ijpharm.2017.09.056 ↗
13. The Pristine Oil/Water Interface: Surfactant-Free Hydroxide-Charged Emulsions10.1002/anie.200453916 ↗
14. Particles as Surfactants—Similarities and differences10.1016/S1359-0294(02)00008-0 ↗
15. Binks · 2006
16. Rheological Behavior of Water-in-Oil Emulsions Stabilized by Hydrophobic Bentonite Particles10.1021/la050255w ↗
17. Pickering miniemulsion polymerization using laponite clay as a stabilizer10.1021/la701150q ↗
18. High solids content, soap-free, film-forming latexes stabilized by laponite clay platelets10.1002/marc.201000305 ↗
19. Molecular controls on kaolinite surface charge10.1006/jcis.1996.0557 ↗
20. The thermal Stability of mixed Phenylphosphonic Acid/Water Intercalates of Kaolin and Halloysite. A TG-EGA and VT-DRIFTS study10.1039/b104254h ↗
21. Clay Minerals and their Beneficial Effects upon Human Health. A review10.1016/S0169-1317(01)00085-0 ↗
22. Clay and Non-Clay Minerals in the Pharmaceutical and Cosmetic Industries Part II. Active ingredients10.1016/j.clay.2009.10.016 ↗
23. Pickering stabilized miniemulsion polymerization: preparation of clay armored latexes10.1021/ma051070z ↗
24. Synthesis and UV absorption properties of 2-naphthylamine-1,5-disulfonic acid intercalated zn-al layered double hydroxides10.1021/ie071043s ↗
25. Nanoclay stabilized pickering miniemulsion of fluorinated copolymer with improved hydrophobicity via raft polymerization10.1039/C5RA25808A ↗
26. Emulsions stabilized with solid nanoparticles: pickering emulsions10.1016/j.colsurfa.2013.02.054 ↗
27. Synthesis and UV Absorption Properties of 5,5′-Methylenedisalicylic Acid intercalated Zn-Al Layered double Hydroxides10.1021/ie901151c ↗
28. Optimizing Organoclay Stabilized Pickering Emulsions10.1016/j.jcis.2011.01.046 ↗
29. Layered double Hydroxides Intercalated with Anionic Surfactants/Benzophenone as potential Materials for Sunscreens10.1016/j.jcis.2013.01.059 ↗
30. Rare earth and zinc layered hydroxide salts intercalated with the 2-aminobenzoate anion as organic luminescent sensitizer10.1016/j.materresbull.2015.04.055 ↗
31. Layered Zinc Hydroxide Salts Intercalated with Anionic Surfactants and Adsolubilized with UV Absorbing Organic Molecules
32. Unusual incorporation of neutral and low water-soluble guest molecules into layered double hydroxides: the case of cucurbit[6 and 7]uril inclusion hosts10.1021/cm102962g ↗
33. Davies, G.B., Krüger, T., Coveney, P., Harting, J., 2014. Detachment Energies of Spheroidal Particles from Fluid-Fluid Interfaces.10.1063/1.4898071 ↗
34. Hydrophobic Layered double Hydroxides (LDHs): Selective Adsorbents for Liquid Mixtures10.1007/s003960050135 ↗
35. Synthesis of Clay-Armored Poly(vinylidene chloride-co-methyl acrylate) Latexes by Pickering Emulsion Polymerization and their Film-Forming Properties10.1039/C7PY00902J ↗
36. Stability of Particles Adsorbed at liquid/Fluid Interfaces: Shape effects Induced by Line Tension10.1063/1.1559728 ↗
37. Adsolubilization of drugs onto Natural Clinoptilolite Modified by Adsorption of Cationic Surfactants10.1016/j.colsurfb.2009.11.018 ↗
38. The Theory of Emulsification10.1021/ja01665a002 ↗
39. Forano · 2006
40. Galimberti · 2011
41. Steady-state droplet size in montmorillonite stabilised emulsions10.1039/C6SM01377E ↗
42. Controlling the rheology of montmorillonite stabilized oil-in-water emulsions10.1021/acs.langmuir.6b04161 ↗
43. Stabilisation of water-in-water emulsions by montmorillonite platelets10.1016/j.jcis.2017.05.062 ↗
44. Rheological, morphological and thermal properties of pickering-like eva/organoclay nanocomposites
45. Synthesis, Characterization of Layered double Hydroxide-Poly(methylmethacrylate) Graft Copolymers via Activators Regenerated by Electron transfer for Atom transfer Radical Polymerization and its effect on the Performance of Poly(lactic acid)10.1002/pat.4283 ↗
46. Adsorption of aqueous crude oil components on the basal surfaces of clay minerals: molecular simulations including salinity and temperature effects10.1021/acs.jpcc.7b06454 ↗
47. Influence of water-soluble and water-insoluble natural surface active components on the stability of water-in-toluene-diluted bitumen emulsion10.1016/S0016-2361(02)00113-8 ↗
48. Isolation and characterization of interfacial materials in bitumen emulsions10.1021/ef050408n ↗
49. Internally structured pickering emulsions stabilized by clay mineral particles10.1016/j.jcis.2009.01.026 ↗
50. Covalent grafting of ethylene glycol into the zn–al–co3 layered double hydroxide10.1006/jcis.2000.6873 ↗
51. Günter · 2017
52. Harry · 2000
53. Layered hydroxide anion exchanger and their applications related to pesticides: a brief review10.1080/14328917.2016.1192717 ↗
54. Grafting of swelling clay materials with 3-aminopropyltriethoxysilane10.1016/j.jcis.2005.02.092 ↗
55. Stabilization of O/W emulsion with hydrophilic/hydrophobic clay particles10.1007/s00396-014-3353-2 ↗
56. Characterization of kaolinite ζ potential for interpretation of wettability alteration in diluted bitumen emulsion separation10.1021/ef900999h ↗
57. Effects of clay wettability and process variables on separation of diluted bitumen emulsion10.1021/ef101085j ↗
58. Wettability alteration of clay in solid-stabilized emulsions10.1021/ef2000079 ↗
59. Preparation of janus colloidal particles via pickering emulsion: an overview10.1016/j.colsurfa.2013.01.004 ↗
60. Photostability of sunscreens10.1016/j.jphotochemrev.2011.12.001 ↗
61. Microwave-hydrothermal processing of layered anion exchangers10.1557/JMR.1996.0236 ↗
62. Capillary forces and structuring in layers of colloid particles10.1016/S1359-0294(01)00105-4 ↗
63. Capillary interactions between particles bound to interfaces, liquid films and biomembranes10.1016/S0001-8686(99)00016-0 ↗
64. On the thermodynamics of particle-stabilized emulsions: curvature effects and catastrophic phase inversion10.1021/la047793d ↗
65. Structure and formation of a gel of colloidal disks10.1023/A:1022651208666 ↗
66. Laba, D., 1993. Laba, D. Rheological Properties of Cosmetics and Toiletries, 1 Ed ed. Marcel Dekker, New York.10.1201/9780203740651-2 ↗
67. Smectites as colloidal stabilizers of emulsions: i. preparation and properties of emulsions with smectites and nonionic surfactants10.1016/S0169-1317(98)00051-9 ↗
68. Electrostatics at the oil-water interface, stability, and order in emulsions and colloids10.1073/pnas.0610589104 ↗
69. Stabilisation of emulsion droplets by fine powders10.1002/cjce.5450630211 ↗
70. Applications of layered double hydroxides
71. Effective interaction of charged platelets in aqueous solution: investigations of colloid laponite suspensions by static light scattering and small-angle X-ray scattering10.1103/PhysRevE.72.051504 ↗
72. Oil-in-water emulsions stabilized by laponite particles modified with short-chain aliphatic amines10.1016/j.colsurfa.2012.02.044 ↗
73. Alkyl ketene dimer emulsions stabilized by layered double hydroxide particles modified with glutamic acid10.1021/acs.iecr.7b02532 ↗
74. Rational design and synthesis of janus composites10.1002/adma.201305415 ↗
75. Lieberman · 1998
76. Bitumen–clay interactions in aqueous media studied by zeta potential distribution measurement10.1006/jcis.2002.8471 ↗
77. Structural and morphological characterization of the PP-0559 kaolinite from the brazilian amazon region10.1590/S0103-50532002000200021 ↗
78. One-pot exfoliation of kaolinite by solvothermal cointercalation10.1016/j.clay.2017.05.042 ↗
79. Exfoliation of layered double hydroxide solids into functional nanosheets10.1016/j.clay.2017.04.021 ↗
80. Modification of the interlayer surface of layered copper(ii) hydroxide acetate with benzoate groups: submicrometer fiber generation10.1006/jcis.2001.7691 ↗
81. Charging of oil-water interfaces due to spontaneous adsorption of hydroxyl ions10.1021/la950928i ↗
82. Immobilization of a cationic manganese(III) porphyrin on lithium gordaite (LiZn4(OH)6(SO4)Cl·6H2O), a layered hydroxide salt with cation exchange capacity10.1016/j.clay.2017.01.010 ↗
83. Particle—fluid interactions with application to solid-stabilized emulsions part i. the effect of asphaltene adsorption10.1016/0166-6622(86)80039-7 ↗
84. Anion-exchange reactions of layered double hydroxides10.1021/ic00351a013 ↗
85. Preparation of a novel silica-stabilized oil/water emulsion10.1016/S0927-7757(97)00094-0 ↗
86. Layered double hydroxides: a brief review from fundamentals to application as evolving biomaterials10.1016/j.clay.2017.12.021 ↗
87. Use of organoclay as a stabilizer for water-in-oil emulsions under high-temperature high-salinity conditions10.1016/j.petrol.2017.10.077 ↗
88. Influence of pyrophosphate or polyethylene oxide on the aggregation and gelation of aqueous laponite dispersions10.1016/j.jcis.2004.01.037 ↗
89. Clay minerals: properties and applications to dermocosmetic products and perspectives of natural raw materials for therapeutic purposes—a review10.1016/j.ijpharm.2017.10.031 ↗
90. Polystyrene-montmorillonite core–shell particles via pickering emulsion polymerization and their use as reinforcing additives for polypropylene and ethylene vinyl acetate10.1002/pen.24094 ↗
91. Synergistic stabilization of pickering emulsions by in situ modification of kaolinite with non ionic surfactant10.1016/j.clay.2017.07.038 ↗
92. Gordaite [Zn4Na(OH)6(SO4)Cl·6H2O] second occurrence in the juan de fuca ridge, and new data10.2138/am-1998-9-1020 ↗
93. Influence of clay addition on the properties of olive oil in water emulsions10.1016/j.clay.2008.11.006 ↗
94. Rheological studies in the bulk and at the interface of pickering oil/water emulsions10.1007/s00397-010-0471-8 ↗
95. Comparative study of some layered hydroxide salts containing exchangeable interlayer anions10.1006/jssc.1999.8330 ↗
96. Stabilization of water-in-water emulsions by addition of protein particles10.1021/la402131e ↗
97. Niazi · 2009
98. Pickering emulsion as a template to synthesize janus colloids with anisotropy in the surface potential10.1021/la101502e ↗
99. Adsorption of charged colloid particles to charged liquid surfaces10.1021/la0203584 ↗
100. Surface chemistry and rheology of laponite dispersions — zeta potential, yield stress, ageing, fractal dimension and pyrophosphate10.1016/j.clay.2015.01.033 ↗