journal article·2013-08Open access

Removal of Acid Green 68:1 from aqueous solutions by calcined and uncalcined layered double hydroxides

Rodrigo Morais Menezes dos Santos, Rosembergue Gabriel Lima Gonçalves, Vera Regina Leopoldo Constantino, Liovando Marciano da Costa, Luis Henrique Mendes da Silva, Jairo Tronto, Frederico Garcia Pinto

Applied Clay Science· Volume 80-81

Abstract

Abstract Magnesium aluminum layered double hydroxide (LDH) was synthesized by the co-precipitation method followed by calcination. The resulting materials were characterized by X-ray diffraction (PXRD) and attenuated total reflectance with Fourier transform infrared spectroscopy (FTIR/ATR) and simultaneous thermogravimetric analysis/differential scanning calorimetry coupled to mass spectrometry (TGA–DSC–MS). Calcined and non-calcined LDHs were used as adsorbents to remove azo dye Acid Green 68:1 in an aqueous solution. Adsorption experiment results indicated that calcined LDH possesses greater adsorption capacity (154.8 mg g− 1) than non-calcined LDH (99.1 mg g− 1). Isotherms showed that adsorption of the dye was more consistent with the Langmuir model. Kinetic experiments of calcined LDH adsorption showed that for low concentration (50, 100 and 200 mg L− 1), the system reached the adsorption equilibrium in 1, 2, and 4 h, and for higher concentration after 10 h. The best kinetic model was the pseudo-second order. Adsorption studies also showed that the capacity for adsorption of the dye by calcinated LDH does not significantly diminish with pH level variation.
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Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Nanomaterials for catalytic reactions · Adsorption and biosorption for pollutant removal

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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