Functional nanohybrid materials derived from kaolinite
Source abstract
Abstract
Abstract The first studies reporting the intercalation of organic compounds in kaolinite appeared in the 1960's. From that time, many advances have been achieved in this field. They are mainly concerned with the mastering and control of the intercalation processes, with the elucidation of various structural interactions between the intercalated compounds and the functionalities of the interlayer spaces, and with the covalent grafting of a variety of compounds on the internal surfaces. A new type of nanohybrid materials was developed, which displayed several potential interesting applications in various research area as clay polymer nanocomposites, adsorbents, electrochemical sensors or catalysts, among others.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Clay minerals and soil interactions · Adsorption and biosorption for pollutant removal · Mesoporous Materials and Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (70)
Show source-provided references
1. New synthesis strategies for effective functionalization of kaolinite and saponite with silylating agents10.1016/j.jcis.2009.08.041 ↗
2. Handbook of Clay Science10.1016/B978-0-08-098258-8.00028-6 ↗
3. Intercalation and interlamellar grafting of polyols in layered aluminosilicates. d-Sorbitol and adonitol derivatives of kaolinite10.1039/b306468a ↗
4. Hybrid materials prepared by interlayer functionalization of kaolinite with pyridine-carboxylic acids10.1016/j.jcis.2009.03.067 ↗
5. Novel reactive amino-compound: tris(hydroxymethyl)aminomethane covalently grafted on kaolinite10.1016/j.clay.2010.02.017 ↗
6. New highly luminescent hybrid materials: terbium pyridine picolinate covalently grafted on kaolinite10.1021/am2001086 ↗
7. Green and selective oxidation reactions catalyzed by kaolinite covalently grafted with Fe(III) pyridine-carboxylate complexes10.1016/j.cattod.2011.11.029 ↗
8. Decarreau · 1990
9. Ionic liquid–kaolinite nanohybrid materials for the amperometric detection of trace levels of iodide10.1039/C2AN36618E ↗
10. Intercalation of two phenolic acids in an ionic liquid–kaolinite nanohybrid material and desorption studies10.1016/j.clay.2014.04.038 ↗
11. Kaolinite–ionic liquid nanohybrid materials as electrochemical sensors for size-selective detection of anions10.1039/c2jm34772e ↗
12. Effect of structural stress on the intercalation rate of kaolinite10.1006/jcis.2001.8208 ↗
13. Kaolinite–polymer nanocomposites10.1016/B978-0-08-098258-8.00022-5 ↗
14. From platy kaolinite to nanorolls10.2113/gselements.10.3.201 ↗
15. Aluminosilicate nanohybrid materials. Intercalation of polystyrene in kaolinite10.1016/j.jpcs.2006.01.008 ↗
16. Kaolinite-poly(methacrylamide) intercalated nanocomposite via in situ polymerization10.1139/v08-142 ↗
17. Intercalation of a block co-polymer in kaolinite10.1016/j.jcis.2015.03.025 ↗
18. Adsorption of indole on kaolinite in nonaqueous media: organoclay preparation and characterization, and 3D-RISM-KH molecular theory of solvation investigation10.1021/jp4064142 ↗
19. Grafted organic derivative of kaolinite: I. Synthesis, chemical and rheological characterization10.1180/0009855054040190 ↗
20. Grafted organic derivative of kaolinite: II. Intercalation of primary n-alkylamines and delamination10.1180/0009855054040191 ↗
21. Covalent grafting to μ-hydroxy-capped surfaces? A kaolinite case study10.1021/cm200235x ↗
22. Theoretical study of the intercalation behavior of ethylene glycol on kaolinite10.1021/jp506628n ↗
23. Molecule−surface recognition between heterocyclic aromatic compounds and kaolinite in toluene investigated by molecular theory of solvation and thermodynamic and kinetic experiments10.1021/jp507393u ↗
24. Organic modification of the interlayer surface of kaolinite with propanediols by transesterification10.1039/b211844k ↗
25. Thermally induced grafting reactions of ethylene glycol and glycerol intercalates of kaolinite10.1021/cm061481+ ↗
26. A kaolinite-NMF-methanol intercalation compound as a versatile intermediate for further intercalation reaction of kaolinite10.1557/JMR.1998.0128 ↗
27. Direct intercalation of poly(vinylpyrrolidone) into kaolinite by a refined guest displacement method10.1021/cm9804721 ↗
28. Modification of the interlayer surface of kaolinite with methanol groups10.1021/la991453o ↗
29. Di- and triethanolamine grafted kaolinites of different structural order as adsorbents of heavy metals10.1016/j.jcis.2015.05.027 ↗
30. One-step exfoliation of kaolinites and their transformation into nanoscrolls10.1021/la1047134 ↗
31. Intercalation reactions of kaolinite10.1016/B978-0-08-098258-8.00015-8 ↗
32. Functionalized nanohybrid materials obtained from the interlayer grafting of aminoalcohols on kaolinite
33. Interlayer grafting of glycidol (2,3-epoxy-1-propanol) on kaolinite10.1139/v07-130 ↗
34. Clay–polymer nanocomposite material from the delamination of kaolinite in the presence of sodium polyacrylate10.1021/la901196f ↗
35. Functionalization of the interlayer surfaces of kaolinite by alkylammonium groups from ionic liquids10.1346/CCMN.2009.0570510 ↗
36. Application of thermal analysis for the characterisation of intercalated and grafted organo-kaolinite nanohybrid materials10.1007/s10973-010-1269-8 ↗
37. Ionic conductivity of nanostructured hybrid materials designed from imidazolium ionic liquids and kaolinite10.1021/cm800758c ↗
38. Nanohybrid materials from interlayer functionalization of kaolinite. Application to the electrochemical preconcentration of cyanide10.1016/j.clay.2007.12.007 ↗
39. Single kaolinite nanometer layers prepared by an in situ polymerization exfoliation process in the presence of ionic liquids10.1021/la203492m ↗
40. Deposition of gold nanoparticles on organo-kaolinite—application in electrocatalysis for carbon monoxide oxidation10.1139/v11-028 ↗
41. Cation exchange capacity of kaolinite10.1346/CCMN.1999.0470207 ↗
42. Simulation assisted characterization of kaolinite–methanol intercalation complexes synthesized using cost-efficient homogenization method10.1016/j.apsusc.2015.09.081 ↗
43. Preparation of a kaolinite-nylon 6 intercalation compound10.1246/bcsj.74.1153 ↗
44. Arsenate, orthophosphate, sulfate, and nitrate sorption equilibria and kinetics for halloysite and kaolinites with an induced positive charge10.1016/j.cej.2014.03.004 ↗
45. Immobilization and reduction of hexavalent chromium in the interlayer space of positively charged kaolinites10.1016/j.jcis.2013.02.015 ↗
46. Behaviour of kaolinite intercalation compounds with selected ammonium salts in aqueous chromate and arsenate solutions10.1016/j.molstruc.2014.04.063 ↗
47. Matusik, J. Scholtzová, E. and, D.T., 2012. Influence of synthesis conditions on the formation of a kaolinite–methanol complex and simulation of its vibrational spectra. Clay Clay Miner. 60, 227–239.10.1346/CCMN.2012.0600301 ↗
48. The effect of structural order on nanotubes derived from kaolin-group minerals10.1346/CCMN.2009.0570406 ↗
49. Cassava starch–kaolinite composite film. Effect of clay content and clay modification on film properties10.1016/j.carbpol.2011.11.091 ↗
50. Sensors and biosensors based on clay-modified electrodes-new trends10.1016/j.clay.2004.06.005 ↗
51. Synthesis of kaolinite–organic nanohybrids with butanediols10.1016/j.ssi.2004.02.048 ↗
52. Applied clay mineralogy
53. Murray · 1993
54. Intercalated supramolecular compounds of kaolinite with ethanolamine and ethylene glycol: structures and dielectric properties10.1039/c3dt52930d ↗
55. Evidence for the formation of interlayer polyacrylonitrile in kaolinite10.1346/CCMN.1988.0360408 ↗
56. Methoxy-modified kaolinite as a novel carrier for high-capacity loading and controlled-release of the herbicide amitrole10.1038/srep08870 ↗
57. Thiol-functionalized porous clay heterostructures (PCHs) deposited as thin films on carbon electrode: towards mercury(II) with organic chelating groups10.1016/j.snb.2006.09.005 ↗
58. Preconcentration and voltammetric analysis of mercury(II) at a carbon paste electrode modified with natural smectite-type clays grafted with organic chelating groups10.1016/j.snb.2005.01.027 ↗
59. Nanohybrid kaolinite-based materials obtained from the interlayer grafting of 3-aminopropyltriethoxysilane and their potential use as electrochemical sensors10.1021/cm702206z ↗
60. Nanohybrid materials from the grafting of imidazolium cations on the interlayer surfaces of kaolinite. Application as electrode modifier10.1039/b907401e ↗
61. Square wave voltammetric determination of lead(II) ions using a carbon paste electrode modified by a thiol-functionalized kaolinite10.1002/elan.201000467 ↗
62. Interlamellar covalent grafting of organic units on kaolinite10.1021/cm00030a002 ↗
63. Preparation and characterization of two distinct ethylene glycol derivatives of kaolinite10.1346/CCMN.1994.0420506 ↗
64. Chemically modified kaolinite. Grafting of methoxy groups on the interlamellar aluminol surface of kaolinite10.1039/jm9960601679 ↗
65. Aluminosilicate nanocomposite materials. Poly(ethyleneglycol)-kaolinite intercalates10.1021/cm9505299 ↗
66. Poly(vinyl chloride)/kaolinite nanocomposites: characterization and thermal and optical properties10.1021/ie901384x ↗
67. Lattice expansion of kaolin minerals by treatment with potassium acetate
68. Eine Schichteinschlußverbindung von Kaolinit mit Harnstoff10.1002/ange.19610732205 ↗
69. Effect of reaction temperature on grafting of γ-aminopropyl triethoxysilane (APTES) onto kaolinite
70. Influence of interlayer functionalization of kaolinite on property profile of copolymer nanocomposites10.1016/j.clay.2015.04.010 ↗