journal article·2019-02

Wastewater treatment test by removal of the sulfamethoxazole antibiotic by a calcined layered double hydroxide

El Hassane Mourid, Mohamed Lakraimi, Lhaj Benaziz, El Hassan Elkhattabi, Ahmed Legrouri

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Abstract

Abstract In this study, we investigated the removal of the sulfamethoxazole drug (SMX) by calcined layered double hydroxides (CLDHs) at 500 °C. The characterization of the fresh CLDH solids and after removal of SMX, by X-ray diffraction, infrared spectroscopy and scanning electron microscopy, shows that the removal is carried out by reconstruction of LDH phases intercalated by SMX via the memory effect of mixed oxides. The thermodynamic parameters indicate that the adsorption is governed by physisorption. The removal capacity of SMX by CLDHs, under optimal conditions, reaches 4314 mg/g with an SMX/CLDH mass ratio of 1.6 and the elimination rate reaches 93%. This result is a good sign for fighting the development of bacterial resistance to such antibiotics because the quantity that may remain in natural environments is very low. Recycling of the intercalated phases remains efficient after six cycles.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Advanced Photocatalysis Techniques · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (76)

Show source-provided references
1. Modeling of photocatalytic mineralization of phthalic acid in TiO2 suspension using response surface methodology (RSM)10.13005/ojc/280302 ↗
2. Photocatalytic degradation of indigo carmine using [Zn-Al] LDH supported on PAN nanofibres10.1180/claymin.2015.050.2.03 ↗
3. Adsorptive removal of antibiotics from water and wastewater: Progress and challenges10.1016/j.scitotenv.2015.05.130 ↗
4. Metal-organic framework-derived carbons: Preparation from ZIF-8 and application in the adsorptive removal of sulfamethoxazole from water10.1016/j.cattod.2017.02.011 ↗
5. Removal of acid orange 7 dye from aqueous solution using the exchange resin amberlite FPA-98 as an efficient adsorbent: Kinetics, isotherms, and thermodynamics study
6. Investigating the removal of some pharmaceutical compounds in hospital wastewater treatment plants operating in Saudi Arabia10.1007/s11356-016-6389-7 ↗
7. Biodegradability of Cefotiam, Ciprofloxacin, Meropenem, Penicillin G, and Sulfamethoxazole and Inhibition of Waste Water Bacteria10.1007/s002449900501 ↗
8. Sorption of acid red 57 from aqueous solution onto sepiolite10.1016/j.jhazmat.2004.08.003 ↗
9. Synthesis and characterization of CoMo/Zn–Al mixed oxide catalysts for hydrodesulphuration of thiophene10.1007/s10562-010-0337-9 ↗
10. Ultrafiltration ceramic membrane performance during the treatment of model solutions containing dye and salt10.1016/j.seppur.2014.04.001 ↗
11. Balarak, D., Mostafapour, F.K., 2016. Batch equilibrium, kinetics and thermodynamics study of sulfamethoxazole antibiotics onto Azolla filiculoides as a novel biosorbent. Br. J. Pharm. Res. 13 (2), 1–14.10.9734/BJPR/2016/28521 ↗
12. Raman effect in relation to crystal structure
13. Layered double hydroxide stability. 1. Relative stabilities of layered double hydroxides and their simple counterparts10.1021/cm980523u ↗
14. Adsorptive removal of antibiotics from water and wastewater: Progress and challenges10.1016/j.scitotenv.2015.05.130 ↗
15. Effect of humic monomers on the adsorption of sulfamethoxazole sulfonamide antibiotic into a high silica zeolite Y: an interdisciplinary study10.1016/j.chemosphere.2016.04.008 ↗
16. Comparison of predicted and measured concentrations of selected pharmaceuticals, fragrances and hormones in Spanish sewage10.1016/j.chemosphere.2008.04.034 ↗
17. Adsorption of methyl tert-butyl ether using granular activated carbon: Equilibrium and kinetic analysis10.1007/BF03326133 ↗
18. Dosing regimens of cotrimoxazole (trimethoprim-sulfamethoxazole) for melioidosis10.1128/AAC.01301-08 ↗
19. Intraparticle diffusion processes during acid dye adsorption onto chitosan10.1016/j.biortech.2006.09.045 ↗
20. Basic properties of Mg2+1-xAl3+x layered double hydroxide intercalated by carbonate, hydroxide, chloride and sulfate anions10.1021/ic00108a020 ↗
21. Non-conventional low-cost adsorbents for dye removal: a review10.1016/j.biortech.2005.05.001 ↗
22. Adsorption of phosphate by layered double hydroxides in aqueous solutions10.1016/j.clay.2006.02.005 ↗
23. Résistance aux antibiotiques d'Escherichia coli uropathogène communautaire et consommation d'antibiotiques à Casablanca (Maroc)
24. Removal of indigo carmine dye from water to Mg–Al–CO3 calcined layered double hydroxides10.1016/j.jhazmat.2008.04.089 ↗
25. Visible-light-induced heterostructured Zn–Al–in mixed metal oxide nanocomposite photocatalysts derived from a single precursor10.1016/j.cej.2011.09.054 ↗
26. Effects of carbon nanotubes on physicochemical properties and sulfamethoxazole adsorption of sediments with or without aging processes10.1016/j.cej.2016.10.123 ↗
27. Competitive retention of sulfamethoxazole (SMX) and sulfamethazine (SMZ) from synthetic solutions in a strong anionic ion exchange resin10.1080/07366299.2014.940235 ↗
28. Insights into the modeling of adsorption isotherm systems10.1016/j.cej.2009.09.013 ↗
29. Characterization of zinc oxide nanorods loaded on activated carbon as cheap and efficient adsorbent for removal of methylene blue10.1016/j.jiec.2014.05.006 ↗
30. Removal of copper ions from aqueous solution by tree fern10.1016/S0043-1354(03)00002-2 ↗
31. The kinetics of sorption of divalent metal ions onto sphagnum moss peat10.1016/S0043-1354(99)00232-8 ↗
32. Removal of sulfamethoxazole from aqueous solution by sono-ozonation in the presence of a magnetic catalyst10.1016/j.seppur.2013.05.014 ↗
33. Deintercalation of carbonate ions from a hydrotalcite-like compound: Enhanced decarbonation using acid-salt mixed solution10.1021/cm049579g ↗
34. Jensen · 2009
35. Élimination des colorants des eaux résiduaires de l'industrie textile par la bentonite et des sels d'aluminium
36. The presence of pharmaceuticals in the environment due to human use – present knowledge and future challenges10.1016/j.jenvman.2009.01.023 ↗
37. Removal of the herbicide 2,4-dichlorophenoxyacetate from water to zinc–aluminium–chloride layered double hydroxides10.1016/j.watres.2005.03.036 ↗
38. Study on adsorption of glyphosate (N-phosphonomethyl glycine) pesticide on MgAl-layered double hydroxides in aqueous solution10.1016/j.jhazmat.2005.04.037 ↗
39. Determination of antibiotic substances in hospital sewage water using solid phase extraction and liquid chromatography/mass spectrometry and group analogue internal standards10.1016/j.chemosphere.2004.09.015 ↗
40. Defluoridation of drinking water by calcined MgAl-CO3 layered double hydroxides10.1016/j.desal.2006.03.587 ↗
41. Factors influencing the removal of fluoride from aqueous solution by calcined Mg–Al–CO3 layered double hydroxides10.1016/j.jhazmat.2005.10.012 ↗
42. Adsorption of eriochrome black dye from aqueous solution onto anionic layered double hydroxides
43. Etude physico-chimique, spectres de vibration et structure du sulfaméthoxazole10.1139/v85-500 ↗
44. The syntheses of hydrotalcite-like compounds and their structures and physico-chemical properties I: the systems Mg2+-Al3+-NO3−, Mg2+-Al3+-Cl−, Mg2+-Al3+-ClO4−, Ni2+-Al3+-Cl− and Zn2+-Al3+-Cl−10.1346/CCMN.1975.0230508 ↗
45. Anion-exchange properties of hydrotalcite-like compounds10.1346/CCMN.1983.0310409 ↗
46. Removal of lignin and tannin colour from aqueous solution by adsorption onto activated charcoal10.1016/S0269-7491(97)00025-0 ↗
47. Nakamoto · 1963
48. Adsorption characteristics of diclofenac and sulfamethoxazole to graphene oxide in aqueous solution10.1016/j.chemosphere.2015.03.061 ↗
49. Synthesis, characterization and applications of layered double hydroxides containing organic guests10.1039/a708319j ↗
50. Treatment of methyl orange by calcined layered double hydroxides in aqueous solution: Adsorption property and kinetic studies10.1016/j.jcis.2007.07.045 ↗
51. Etude par spectroscopie infrarouge des trois formes cristallines de la sulfanilamide10.1051/jphyscol:1966205 ↗
52. Evidence for a complex relationship between antibiotics and antibiotic-resistant Escherichia coli: from medical center patients to a receiving environment10.1021/es203399h ↗
53. Comparative adsorption isotherm study of the removal of Pb2+ and Zn2+ onto agricultural waste
54. Kinetics, isotherm and thermodynamic studies of adsorption of Acid Blue 193 from aqueous solutions onto natural sepiolite10.1016/j.colsurfa.2005.11.017 ↗
55. Adsorption of hazardous cationic dyes from aqueous solution onto Acacia nilotica leaves as an eco-friendly adsorbent
56. Synthesis and structural transformations of hydrotalcite like materials Mg-Al and Zn-Al10.1023/A:1014832530184 ↗
57. Degradation of sulfamethoxazole by microwave-activated persulfate: Kinetics, mechanism and acute toxicity10.1016/j.cej.2014.03.086 ↗
58. Etude physico-chimique comparée des formes I et II du sulfabenzamide10.1016/0378-5173(83)90143-6 ↗
59. Synthesis of magnetic biochar from pine sawdust via oxidative hydrolysis of FeCl2 for the removal sulfamethoxazole from aqueous solution10.1016/j.jhazmat.2016.10.006 ↗
60. Removal of malachite green from aqueous solution by activated carbon prepared from the epicarp of Ricinus communis by adsorption10.1016/j.jhazmat.2010.02.076 ↗
61. An investigation of the kinetics and thermodynamics of the adsorption of a cationic cobalt porphyrazine onto sepiolite10.1016/j.dyepig.2010.04.011 ↗
62. Kinetic assessment of the potassium ferrate (VI) oxidation of antibacterial drug sulfamethoxazole10.1016/j.chemosphere.2005.03.095 ↗
63. Organo/Zn-Al LDH nanocomposites for cationic dye removal from aqueous media10.1186/s11671-016-1402-0 ↗
64. Adsorption behavior of direct red 12B and rhodamine B from water onto surfactant-modified coconut coir pith10.1016/j.colsurfa.2007.10.026 ↗
65. Degradation of sulfamethoxazole in water by solar photo-Fenton. Chemical and toxicological evaluation10.1016/j.watres.2009.04.006 ↗
66. Sorption - desorption isotherms of dyes from aqueous solutions and wastewaters with different sorbent materials
67. Fluxes of 13 selected pharmaceuticals in the water cycle of Stockholm, Sweden10.2166/wst.2011.124 ↗
68. Wang, F., Sun, W., Pan, W., Xu, N., 2015. Adsorption of sulfamethoxazole and 17b-estradiol by carbon nanotubes/CoFe2O4 composites. Chem. Eng. J. 3 (2), 1223–1232.10.1016/j.cej.2015.03.113 ↗
69. Kinetics of adsorption carbon from solutions10.1061/JSEDAI.0000430 ↗
70. Comparing the effects of different oxygen-containing functional groups on sulfonamides adsorption by carbon nanotubes: experiments and theoretical calculation10.1016/j.cej.2016.11.133 ↗
71. Removal Efficiency and Mechanism of Sulfamethoxazole in Aqueous solution by Bioflocculant MFX10.1155/2013/568614 ↗
72. Effect of calcination on adsorption performance of Mg–Al layered double hydroxide prepared by a water in oil microemulsion method10.1039/C6RA05253C ↗
73. Polymorphism in sulfonamides10.1002/jps.2600610104 ↗
74. Removal of perchlorate from aqueous solution by cross-linked Fe(III)-chitosan complex10.1016/j.jhazmat.2012.01.026 ↗
75. Surfactant-enhanced adsorption of organic compounds by layered double hydroxides10.1016/S0927-7757(01)01137-2 ↗
76. The adsorption of Pb(II) on Mg2Al layered double hydroxide10.1016/j.cej.2011.03.082 ↗