journal article·2017-10

Degradation mechanism of amoxicillin using clay supported nanoscale zero-valent iron

Xiulan Weng, Wanling Cai, Shen Lin, Zuliang Chen

Publisher page

Abstract

Abstract Antibiotics such as amoxicillin (AMX) have been considered emerging pollutants due to their persistence in the aquatic ecosystem even at low concentrations. Thus, it is an emerging issue to develop materials effective for removal of antibiotics pharmaceuticals from wastewaters. Bentonite supported nanoscale zero-valent iron (B-nZVI) as one of the alternatives was used to remove amoxicillin. Batch experiments revealed that the degradation of amoxicillin depended on pH value of the solution, initial concentration of B-nZVI, initial concentration of amoxicillin and reaction temperature. The removal of AMX was based on an integration of adsorption and reductive degradation, which was confirmed by either adsorption or reductive kinetics. The potential AMX degradation pathway was proposed by analysis of the degraded products using high performance liquid chromatography-mass spectrometry (HPLC-MS). The removal mechanism of amoxicillin using B-nZVI includes: (1) the adsorption of amoxicillin onto iron corrosion products; and (2) reduction of AMX by nZVI on B-nZVI. Finally, the reusability of B-nZVI for degradation of amoxicillin was tested.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Environmental remediation with nanomaterials · Nanomaterials for catalytic reactions · Advanced oxidation water treatment

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Adsorption of amoxicillin on chitosan beads: kinetics, equilibrium and validation of finite batch models10.1016/j.bej.2005.08.010 ↗
2. Antibiotic removal from wastewaters: the ozonation of amoxicillin10.1016/j.jhazmat.2005.03.004 ↗
4. Iron-nickel bimetallic nanoparticles for reductive degradation of azo dye Orange G in aqueous solution10.1016/j.apcatb.2007.10.033 ↗
5. Removal of methyl orange from aqueous solution using bentonite-supported nanoscale zero-valent iron10.1016/j.jcis.2011.07.057 ↗
6. Multifunctional kaolinite-supported nanoscale zero-valent iron used for the adsorption and degradation of crystal violet in aqueous solution10.1016/j.jcis.2013.02.020 ↗
7. Swelling deformation of compacted GMZ bentonite experiencing chemical cycles of sodium-calcium exchange and salinization-desalinization effect10.1016/j.clay.2017.02.016 ↗
8. Rapid decolorization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles10.1016/j.jhazmat.2008.11.091 ↗
9. Antibiotic removal from water: elimination of amoxicillin and ampicillin by microscale and nanoscale iron particles10.1016/j.envpol.2008.12.024 ↗
10. Degradation and removal methods of antibiotics from aqueous matrices - a review10.1016/j.jenvman.2011.05.023 ↗
11. Insights into the mechanism of persulfate activation with nZVI/BC nanocomposite for the degradation of nonylphenol10.1016/j.cej.2016.11.085 ↗
12. Impact of iron-based nanoparticles on microbial denitrification by Paracoccus sp. strain YF110.1016/j.aquatox.2013.09.005 ↗
13. Membrane (RO-UF) filtration for antibiotic wastewater treatment and recovery of antibiotics10.1016/S1383-5866(03)00184-9 ↗
14. Enhanced nitrate removal by novel bimetallic Fe/Ni nanoparticles supported on biochar10.1016/j.jclepro.2017.03.042 ↗
15. An exposure assessment for selected pharmaceuticals within a watershed in Southern Ontario10.1016/j.chemosphere.2005.11.015 ↗
16. Entrapment of nanoscale zero-valent iron in chitosan beads for hexavalent chromium removal from wastewater10.1016/j.jhazmat.2010.08.099 ↗
17. Influence of zero-valent iron nanoparticles on nitrate removal by Paracoccus sp10.1016/j.chemosphere.2014.02.045 ↗
18. The influence of polyelectrolyte modification on nanoscale zero-valent iron (nZVI): aggregation, sedimentation, and reactivity with Ni(II) in water10.1016/j.cej.2016.05.132 ↗
19. Nanoscale zero valent iron and bimetallic particles for contaminated site remediation10.1016/j.advwatres.2012.02.005 ↗
20. Toxic effects of amoxicillin on the photosystem II of synechocystis sp. characterized by a variety of in vivo chlorophyll fluorescence tests10.1016/j.aquatox.2008.06.018 ↗
21. Performance of activated carbon and bentonite for adsorption of amoxicillin from wastewater: mechanisms, isotherms and kinetics10.1016/j.watres.2009.02.039 ↗
22. Removal of Chromium (VI) from wastewater using bentonite-supported nanoscale zero-valent iron10.1016/j.watres.2010.09.025 ↗
23. Reduction of hexachlorobenzene by nanoscale zero-valent iron: kinetics, pH effect, and degradation mechanism10.1016/j.seppur.2010.10.015 ↗
24. Dechlorination of p-chlorophenol from aqueous solution using bentonite supported Fe/Pd nanoparticles: synthesis, characterization and kinetics10.1016/j.desal.2011.06.067 ↗
25. Removal characteristics of ammonium nitrogen from wastewater by modified Ca-bentonites10.1016/j.clay.2015.02.003 ↗
26. Chitosan stabilized bimetallic Fe/Ni nanoparticles used to remove mixed contaminants-amoxicillin and Cd (II) from aqueous solutions10.1016/j.cej.2013.05.096 ↗
27. Enhancement of catalytic degradation of amoxicillin in aqueous solution using clay supported bimetallic Fe/Ni nanoparticles10.1016/j.chemosphere.2013.11.033 ↗
28. Enhanced heterogeneous Fenton degradation of Methylene Blue by nanoscale zero valent iron (nZVI) assembled on magnetic Fe3O4/reduced graphene oxide10.1016/j.jwpe.2015.01.006 ↗
29. Kaolinite-supported nanoscale zero-valent iron for removal of Pb2+ from aqueous solution: reactivity, characterization and mechanism10.1016/j.watres.2011.04.010 ↗
30. Strong adsorption of chlorotetracycline on magnetite nanoparticles10.1016/j.jhazmat.2011.06.015 ↗