journal article·2014-11

para-Toluene sulfonic acid treated clay loaded sodium alginate membranes for enhanced pervaporative dehydration of isopropanol

D.P. Suhas, T.M. Aminabhavi, A.V. Raghu

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Abstract

Abstract The para -toluene sulfonic acid ( p -TSA) treated clay (5, 10 and 15 wt.% loadings) particles were inserted into sodium alginate (NaAlg) matrix to derive the composite membranes that showed enhanced pervaporation performance for isopropanol separation. The 10 wt.% modified clay-loaded NaAlg membranes showed the highest selectivity of 5781 with a permeance of 3423 GPU for 10 wt.% water containing isopropanol feed mixture at 30 °C, showing a 140% higher selectivity compared to pristine clay-loaded NaAlg composite membrane. This effect is ascribed to an enhanced surface area and hydrophilicity after p -TSA treatment of clay, as verified by BET and TGA studies. The membranes were characterized by a variety of physico-chemical techniques and their pervaporation performance was assessed in terms of selectivity, permeance, with extent of variations in filler loading, temperature and feed water composition.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Membrane Separation and Gas Transport · Membrane-based Ion Separation Techniques · Membrane Separation Technologies

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