journal article·2019-12

Fabrication of a sustained release delivery system for pesticides using interpenetrating polyacrylamide/alginate/montmorillonite nanocomposite hydrogels

Furui He, Qingfeng Zhou, Longzheng Wang, Gaobo Yu, Jiacheng Li, Yuhong Feng

Publisher page

Abstract

Abstract In pest control field, the sustained release of pesticides plays significant roles in effectiveness and environment friendly. In this study, the sodium alginate (SA), polyacrylamide (PAM) and montmorillonite (MMT) were utilized to fabricate the stretchable double-network nanocomposite hydrogel, which apply in a sustained release system of acetamiprid. These nanocomposite hydrogels were fully characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The results indicate that adding MMT could significantly improve the sustained release performances of the hydrogels. The swelling behavior of all the hydrogels well fits into the Fickian diffusion model. The hydrogel with 5.0% MMT content shows the maximum pesticides loading rate of 13.32% and minimum pesticides release rate of 76.11%. The nanocomposite hydrogels take advantages of both the gelation property of alginate and the adsorption capacity of clays, has great potential in the application of pesticides carrier to improve the utilization efficiency of water-insoluble pesticides.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer-Based Agricultural Enhancements · Hydrogels: synthesis, properties, applications · Polymer Surface Interaction Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. Comparing physico-mechanical and thermal properties of alginate nanocomposite films reinforced with organic and/or inorganic nanofillers10.1016/j.foodhyd.2013.02.006 ↗
2. Adsorption of the tallow amine ethoxylate surfactant Ethomeen T/15 on montmorillonite10.1016/j.clay.2018.03.026 ↗
3. Nanocomposite PAAm/methyl cellulose/montmorillonite hydrogel: evidence of synergistic effects for the slow release of fertilizers10.1021/jf401273n ↗
4. Macro-and micronutrient simultaneous slow release from highly swellable nanocomposite hydrogels10.1021/acs.jafc.6b00190 ↗
5. Montmorillonite functionalized with pralidoxime as a material for chemical protection against organophosphorous compounds10.1021/am200041e ↗
6. Montmorillonite nanodevices for the colon metronidazole delivery10.1016/j.ijpharm.2013.09.017 ↗
7. Clay-biosurfactant materials as functional drug delivery systems: slowing down effect in the in vitro release of cinnamic acid10.1016/j.clay.2016.10.039 ↗
8. Alginate gel beads filled with halloysite nanotubes10.1016/j.clay.2012.12.001 ↗
9. Application and rheology of anisotropic particle stabilized emulsions: effects of particle hydrophobicity and fractal structure10.1016/j.colsurfa.2017.02.088 ↗
10. Effect of particle size on the mechanism controlling n-hexane sorption in glassy polystyrene microspheres10.1016/0032-3861(77)90183-5 ↗
11. X-ray diffraction study of aqueous montmorillonite emulsions10.1346/CCMN.1984.0320410 ↗
12. Self-healable, tough, and ultrastretchable nanocomposite hydrogels based on reversible polyacrylamide/montmorillonite adsorption10.1021/acsami.5b00704 ↗
13. Polyionic hydrocolloids for the intestinal delivery of protein drugs: alginate and chitosan—a review10.1016/j.jconrel.2006.04.017 ↗
14. Nanocomposite hydrogels10.1016/j.cossms.2008.05.001 ↗
15. Nanocomposite hydrogels: a unique organic–inorganic network structure with extraordinary mechanical, optical, and swelling/de-swelling properties10.1002/1521-4095(20020816)14:16<1120::AID-ADMA1120>3.0.CO;2-9 ↗
16. Advances in targeted pesticides with environmentally responsive controlled release by nanotechnology10.3390/nano8020102 ↗
17. Alginate/bacterial cellulose nanocomposite beads prepared using Gluconacetobacter xylinus and their application in lipase immobilization10.1016/j.carbpol.2016.09.074 ↗
18. Development and evaluation of alginate–chitosan nanocapsules for controlled release of acetamiprid10.1016/j.ijbiomac.2015.08.062 ↗
19. Controlled release of herbicide acetochlor from clay/carboxylmethylcellulose gel formulations10.1021/jf072530l ↗
20. Preparation and characterization of PAM/SA tough hydrogels reinforced by IPN technique based on covalent/ionic crosslinking
21. Adsorption of dyes from aqueous solutions or suspensions with clay nano-adsorbents10.1016/j.seppur.2007.07.007 ↗
22. Structure and slow release property of chlorpyrifos/graphene oxide-ZnAl-layered double hydroxide composite10.1016/j.clay.2017.05.023 ↗
23. Analysis of acetamiprid in vegetables using gas chromatography-tandem mass spectrometry10.2116/analsci.19.701 ↗
24. Enzyme-free electrochemical detection of nanomolar levels of the organophosphorus pesticide paraoxon-ethyl by using a poly (N-isopropyl acrylamide)-chitosan microgel decorated with palladium nanoparticles10.1007/s00604-018-3206-7 ↗
25. A study on the adsorption of chromium (VI) from aqueous solutions on the alginate-montmorillonite/polyaniline nanocomposite10.1080/19443994.2013.794711 ↗
26. Preparation and characterization of phosphonium montmorillonite with enhanced thermal stability10.1016/j.clay.2006.09.012 ↗
27. Hydrogels in biology and medicine: from molecular principles to bionanotechnology10.1002/adma.200501612 ↗
28. Enhanced swelling and methylene blue adsorption of polyacrylamide-based superabsorbents using alginate modified montmorillonite10.1002/app.40013 ↗
29. Rahim · 2016 · 12020
30. Mathematical model for the prediction of the overall profile of in vitro solute release from polymer networks10.1016/j.jcis.2006.12.058 ↗
31. Physical and mechanical properties of water resistant sodium alginate films10.1016/j.lwt.2003.09.008 ↗
32. A simple equation for description of solute release I. Fickian and non-fickian release from non-swellable devices in the form of slabs, spheres, cylinders or discs10.1016/0168-3659(87)90034-4 ↗
33. Dynamics of controlled release of chlorpyrifos from swelling and eroding biopolymeric microspheres of calcium alginate and starch10.1016/j.carbpol.2008.10.013 ↗
34. Synthesis, characterization, swelling and drug release behavior of semi-interpenetrating network hydrogels of sodium alginate and polyacrylamide10.1016/j.carbpol.2013.09.004 ↗
35. Study on crosslinked gelatin–montmorillonite nanoparticles for controlled drug delivery applications10.1007/s10853-015-9287-3 ↗
36. A facile route to fabricate a biodegradable hydrogel for controlled pesticide release10.1039/C4RA15139A ↗
37. The usability of (sodium alginate/acrylamide) semi-interpenetrating polymer networks on removal of some textile dyes10.1002/app.27945 ↗
38. Evaluation of cross-linked chitosan microparticles containing acyclovir obtained by spray-drying10.1016/j.msec.2008.07.030 ↗
39. Tough, resilient and pH-sensitive interpenetrating polyacrylamide/alginate/montmorillonite nanocomposite hydrogels10.1016/j.carbpol.2018.05.082 ↗
40. Highly stretchable and tough hydrogels10.1038/nature11409 ↗
41. Controlled pesticide release from porous composite hydrogels based on lignin and polyacrylic acid10.15376/biores.11.1.2361-2371 ↗
42. Polydopamine microcapsules from cellulose nanocrystal stabilized Pickering emulsions for essential oil and pesticide encapsulation10.1016/j.colsurfa.2019.03.049 ↗
43. Development of an alginate hydrogel to deliver aqueous bait for pest ant management10.1002/ps.4616 ↗
44. Clays, nanoclays, and montmorillonite minerals10.1007/s11661-008-9603-5 ↗
45. Synthesis and characterization of carboxymethyl cellulose/organic montmorillonite nanocomposites and its adsorption behavior for Congo Red dye
46. Response surface modeling and optimization of microcystin-LR removal from aqueous phase by polyacrylamide/sodium alginate–montmorillonite superabsorbent nanocomposite10.1080/19443994.2015.1006261 ↗
47. Fabrication of a pH-responsively controlled-release pesticide using an attapulgite-based hydrogel10.1021/acssuschemeng.7b03469 ↗
48. A near-infrared and temperature-responsive pesticide release platform through core–shell polydopamine@ PNIPAm nanocomposites10.1021/acsami.6b15393 ↗
49. Mechanochemical modification of kaolin surfaces for immobilization and delivery of pesticides in alginate-chitosan composite beads10.1007/s00289-014-1231-1 ↗
50. Modification of montmorillonite by ball-milling method for immobilization and delivery of acetamiprid based on alginate/exfoliated montmorillonite nanocomposite10.1007/s00289-015-1542-x ↗
51. Influence of mineral characteristics on the retention of low molecular weight organic compounds: a batch sorption–desorption and ATR-FTIR study10.1016/j.jcis.2014.06.036 ↗
52. Effects of nanocellulose on sodium alginate/polyacrylamide hydrogel: Mechanical properties and adsorption-desorption capacities10.1016/j.carbpol.2018.10.105 ↗
53. Semi-quantitative analysis of microbial production of oxalic acid by montmorillonite sorption and ATR-IR10.1016/j.clay.2018.07.006 ↗
54. Self-aggregation behavior of hydrophobic sodium alginate derivatives in aqueous solution and their application in the nanoencapsulation of acetamiprid10.1016/j.ijbiomac.2017.08.038 ↗
55. Construction and characterization of a novel sustained-release delivery system for hydrophobic pesticides using biodegradable polydopamine-based microcapsules10.1021/acs.jafc.8b00877 ↗