Halloysite nanotubes for food packaging application: A review
Source abstract
Abstract
Halloysite nanotube (Hal) is an alumina silicate-based multilayer nanoclay with a large surface area and a unique hollow tubular structure. It has abilities to improve the overall performance of the packaging material, including physical stability, mechanical strength, optical characteristics, thermal and rheological behaviors, barriers to moisture and gases, and improving the active functions of the biopolymers. In this review the authors aimed to provide a broad perspective on the various food packaging applications established for Hal, specifically ethylene scavengers, antimicrobial materials carriers, and fillers for packaging material. Effects of Hal on the mechanical, thermal, microstructural, functional, biodegradable, and barrier properties of biopolymers were reviewed thoroughly. It covered various incorporation techniques for Hal into the polymer matrix. This review also provides information about application concerns including migration of Hal, toxicity, consumer health aspects, and the future perspective of Hal`s application in developing biodegradable-based food packaging solutions. Nonetheless, the other potential food applications covered by Hal are flourishing as they are non-toxic materials documented by various organizations.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Clay minerals and soil interactions · Therapeutic Uses of Natural Elements · Iron oxide chemistry and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Recent advances and perspectives on starch nanocomposites for packaging applications10.1007/s10853-018-2613-9 ↗
2. Preparation and characterisation of poly(vinyl) alcohol (PVA)/starch (ST)/Halloysite nanotube (HAL) nanocomposite films as renewable materials10.1007/s10853-017-1812-0 ↗
3. Biodegradable and water resistant poly(vinyl) alcohol (PVA)/starch (ST)/glycerol (GL)/Halloysite nanotube (HAL) nanocomposite films for sustainable food packaging10.3389/fmats.2019.00058 ↗
4. Water and gas barrier properties of polyvinyl alcohol (PVA)/starch (ST)/glycerol (GL)/Halloysite nanotube (HAL) bionanocomposite films: experimental characterisation and modelling approach10.1016/j.compositesb.2019.107033 ↗
5. Synergistic effect of bacterial cellulose and Halloysite nanotubes on the properties of the sodium caseinate-based nanobiocomposites10.1016/j.clay.2022.106493 ↗
6. Migration of silver and copper nanoparticles from food coating10.3390/coatings11040380 ↗
7. Development of reinforced aldehyde-modified kappa-carrageenan/gelatin film by incorporation of Halloysite nanotubes for biomedical applications10.1016/j.ijbiomac.2020.05.222 ↗
8. Public and environmental health effects of plastic wastes disposal: a review
9. Thermal properties of PLA/HALs composites: effect of different Halloysite nanotube10.1063/1.5066693 ↗
10. Synergistic effect of halloysite and cellulose nanocrystals on the functional properties of pva based nanocomposites10.1021/acssuschemeng.5b00806 ↗
11. Potentials of polysaccharides, lipids and proteins in biodegradable food packaging applications10.1016/j.ijbiomac.2021.05.182 ↗
12. Incorporation of silver nanoparticles into active antimicrobial nanocomposites: Release behavior, analyzing techniques, applications and safety issues10.1016/j.cis.2021.102440 ↗
13. Physico-mechanical and antimicrobial properties of tragacanth/hydroxypropyl methylcellulose/beeswax edible films reinforced with silver nanoparticles10.1016/j.ijbiomac.2018.09.045 ↗
14. Halloysite nanotubes loaded with peppermint essential oil as filler for functional biopolymer film10.1016/j.carbpol.2016.07.041 ↗
15. Polysaccharides-based bio-nanostructures and their potential food applications10.1016/j.ijbiomac.2021.02.107 ↗
16. Toxicological hazards of inHaled nanoparticles - potential implications for drug delivery10.1166/jnn.2004.081 ↗
17. Active cardboard box with a coating including essential oils entrapped within cyclodextrins and/or Halloysite nanotubes. A case study for fresh tomato storage
18. Core-Shell Biopolymer Nanoparticles for Co-delivery of Curcumin and Piperine: Sequential Electrostatic Deposition of Hyaluronic Acid and Chitosan Shells on the Zein Core10.1021/acsami.9b11782 ↗
19. Halloysite nanotubes in polymer science: Purification, characterization, modification and applications10.1515/ntrev-2020-0024 ↗
20. Development of a sodium alginate-based active package with controlled release of cinnamaldehyde loaded on halloysite nanotubes10.3390/foods10061150 ↗
21. Morphology and properties of thermoplastic starch blended with biodegradable polyester and filled with Halloysite nanoclay10.1016/j.carbpol.2020.116392 ↗
22. De Silva · 2013 · 48 · 3705
23. ZnO deposited/encapsulated Halloysite–poly (lactic acid) (PLA) nanocomposites for high performance packaging films with improved mechanical and antimicrobial properties10.1016/j.clay.2015.03.024 ↗
24. Natural antimicrobial and antioxidant compounds for active food packaging applications
25. Guar gum/carboxymethyl cellulose based antioxidant film incorporated with Halloysite nanotubes and litchi shell waste extract for active packaging10.1016/j.ijbiomac.2021.12.198 ↗
26. Development and in vitro characterization of chitosan/starch/Halloysite nanotubes ternary nanocomposite films10.1016/j.ijbiomac.2019.01.047 ↗
27. Safety Aspects of Nanotechnology applications in Food packaging10.1016/j.profoo.2015.09.015 ↗
28. Possible applications of metal nanoparticles in antimicrobial food packaging10.1111/jfs.12617 ↗
29. Recent advances and cHallenges on applications of nanotechnology in food packaging. A literature review10.1016/j.fct.2019.110814 ↗
30. High adsorption of ethylene by alkali-treated Halloysite nanotubes for food-packaging applications10.1007/s10311-018-0718-7 ↗
31. Natural phenolic compound coated oxygen scavenging active polyolefin film for preserving quality of fish cake
32. Nanostructured materials utilized in biopolymer-based plastics for food packaging applications10.1080/10408398.2012.731023 ↗
33. Kinetics of release and antibacterial activity of salicylic acid loaded into Halloysite nanotubes10.1016/j.clay.2017.11.041 ↗
34. Effect of packaging and Coating Technique on Postharvest Quality and Shelf Life of Raphanus sativus L. and Hibiscus sabdariffa L. Microgreens10.3390/foods9050653 ↗
35. Structural, electronic, and mechanical properties of single-walled halloysite nanotube models10.1021/jp100902e ↗
36. World Health Organization Global estimates and Regional Comparisons of the Burden of Foodborne Disease in 201010.1371/journal.pmed.1001923 ↗
37. Modified natural Halloysite/potato starch composite films10.1016/j.carbpol.2011.11.057 ↗
38. Antibacterial sustained-release coatings from Halloysite nanotubes/waterborne polyurethanes10.1016/j.porgcoat.2016.09.005 ↗
39. Nanoparticles - known and unknown health risks10.1186/1477-3155-2-12 ↗
40. Synergistic effect of chitosan and Halloysite nanotubes on improving agar film properties10.1016/j.foodhyd.2019.105471 ↗
41. Idumah · 2018 · 26 · 751
42. Antimicrobial and biodegradable chitosan/cellulose acetate phtHalate/ZnO nano composite films with optimal oxygen permeability and hydrophobicity for extending the shelf life of black grape fruits10.1016/j.ijbiomac.2019.03.171 ↗
43. Influence of nanofillers on biodegradable composites: a comprehensive review10.1002/pc.26291 ↗
44. Kamal · 2021 · 236 · 4843
45. Kozlowski · 2018 · 465
46. Edible films and coatings for food packaging applications: a review
47. Quality preservation in banana fruits packed in pine needle and Halloysite nanotube-based ethylene gas scavenging paper during storage
48. Antimicrobial packaging film from cactus (Cylindropuntia fulgida) mucilage and gelatine10.1016/j.ijbiomac.2022.06.162 ↗
49. Alginate and pectin films covering Halloysite with encapsulated salicylic acid as food packaging components10.1016/j.clay.2021.106270 ↗
50. Thyme Oil Encapsulated in Halloysite Nanotubes for Antimicrobial packaging System10.1111/1750-3841.13675 ↗
51. Effect of Halloysite nanoclay on the physical, mechanical, and antioxidant properties of chitosan films incorporated with clove essential oil10.1016/j.foodhyd.2018.05.048 ↗
52. Poly(L-lactide)/Poly(D-lactide)/clay nanocomposites: Enhanced dispersion, crystallization, mechanical properties, and hydrolytic degradation10.1002/pen.23620 ↗
53. Applications of Halloysite nanotubes in food packaging for improving film performance and food preservation10.1016/j.foodcont.2021.107876 ↗
54. Recent advance in research on Halloysite nanotubes-polymer nanocomposite10.1016/j.progpolymsci.2014.04.004 ↗
55. Simultaneously toughening and strengthening soy protein isolate-based composites via carboxymethylated chitosan and halloysite nanotube hybridization10.3390/ma10060653 ↗
56. Designing and utilizing 3D printed chitosan/Halloysite nanotubes/tea polyphenol composites to maintain the quality of fresh blueberries10.1016/j.ifset.2021.102808 ↗
57. New biodegradable polyhydroxybutyrate/layered silicate nanocomposites10.1021/bm700500t ↗
58. Effect of morphology and size of Halloysite nanotubes on functional pectin bionanocomposites for food packaging applications10.1021/acsami.7b04297 ↗
59. Halloysite nanotubes: a green resource for materials and life sciences10.1007/s12210-020-00886-x ↗
60. Starch-Halloysite nanocomposites containing nisin: Characterization and inhibition of Listeria monocytogenes in soft cheese10.1016/j.lwt.2015.12.006 ↗
61. A novel active packaging material based on starch-Halloysite nanocomposites incorporating antimicrobial peptides10.1016/j.foodhyd.2016.10.013 ↗
62. Active packaging for lipid foods and development cHallenges for marketing10.1016/j.fbio.2021.101370 ↗
63. Nair · 2017 · 739–755
64. Nanoclay-based active food packaging systems: a review10.1016/j.fpsl.2021.100803 ↗
65. Nielsen · 2006 · 1 · 929
66. Nanotechnologies in food science: applications, recent trends, and future perspectives10.1007/s40820-020-0383-9 ↗
67. OECD · 2022
68. Nanoclay effect into the biodegradation and processability of poly(lactic acid) nanocomposites for food packaging10.3390/polym13162741 ↗
69. Production of Nanocomposites via Extrusion Techniques
70. Polylactide/montmorillonite nanocomposites: study of the hydrolytic degradation10.1016/j.polymdegradstab.2004.10.011 ↗
71. PlasticsEurope · 2019
72. New EU regulation aspects and global market of active and intelligent packaging for food industry applications10.1016/j.foodcont.2010.04.028 ↗
73. Effect of the processing methods on the performance of polylactide films: Thermocompression versus solvent casting10.1002/app.23403 ↗
74. Characterization of polylactic acid/Halloysite nanotubes bionanocomposite films for food packaging10.1016/j.fpsl.2019.100450 ↗
75. Tailoring the properties of thermo-compressed polylactide films for food packaging applications by individual and combined additions of lactic acid oligomer and halloysite nanotubes10.3390/molecules25081976 ↗
76. Effect of chitosan modified Halloysite on the physical and functional properties of pullulan/chitosan biofilm integrated with rutin10.1016/j.clay.2021.106205 ↗
77. Antimicrobial activity of chitosan film containing nanocomposite of Trachyspermum ammi (ajwain) seed oil loaded Halloysite nanotubes against foodborne pathogenic microorganisms10.1016/j.clay.2022.106554 ↗
78. Preparation and characterization of bionanocomposite films based on potato starch/Halloysite nanoclay10.1016/j.ijbiomac.2014.04.009 ↗
79. Preparation of carrageenan-based nanocomposite films incorporated with functionalized Halloysite using AgNP and sodium dodecyl sulfate10.1016/j.foodhyd.2020.105934 ↗
80. Santos · 2019 · 16 · 1169
81. Effect of the intensive plasticizing zone design on the effectiveness of corotating twin-screw extrusion10.1155/2019/8518341 ↗
82. Risk assessment of engineered nanomaterials and nanotechnologies—a review10.1016/j.tox.2010.01.013 ↗
83. Alginate-based nanocomposite films reinforced with Halloysite nanotubes functionalized by alkali treatment and zinc oxide nanoparticles10.1016/j.ijbiomac.2018.07.026 ↗
84. Incorporation of zinc oxide nanoparticles improved the mechanical, water vapor barrier, UV-light barrier, and antibacterial properties of PLA-based nanocomposite films10.1016/j.msec.2018.08.002 ↗
85. Antimicrobial applications of clay nanotube-based composites10.3390/nano9050708 ↗
86. The effect of chemical modification on the physico-chemical characteristics of Halloysite: FTIR, XRF, and XRD studies10.1016/j.molstruc.2014.12.008 ↗
87. UNEP
88. Cytocompatibility and uptake of Halloysite clay nanotubes10.1021/bm9014446 ↗
89. Functionalization of Halloysite nanotubes for the preparation of carboxymethyl cellulose-based nanocomposite films10.1016/j.clay.2017.09.023 ↗
90. Halloysite nanotubes-induced Al accumulation and oxidative damage in liver of mice after 30-day repeated oral administration10.1002/tox.22543 ↗
91. Soy protein and Halloysite nanotubes-assisted preparation of environmentally friendly intumescent flame retardant for poly(butylene succinate)10.1016/j.polymertesting.2019.106174 ↗
92. Water barrier properties of carboxymethyl cellulose/Halloysite nanotubes nanocomposite to be used in food packaging applications10.31357/vjs.v24i02.5414 ↗
93. Wu · 2020 · 14 · 1017
94. Multifunctional and robust polyhydroxyalkanoate nanocomposites with superior gas barrier, heat resistant and inherent antibacterial performances10.1016/j.cej.2019.122864 ↗
95. Nano-biocomposite films fabricated from cellulose fibers and Halloysite nanotubes10.1016/j.clay.2020.105565 ↗
96. Antibacterial nanobiocomposite based on Halloysite nanotubes and extracted xylan from bagasse pith10.1016/j.ijbiomac.2020.05.209 ↗
97. Functionalization of halloysite clay nanotubes by grafting with γ-aminopropyltriethoxysilane10.1021/jp805657t ↗
98. Properties and applications of Halloysite nanotubes: recent research advances and future prospects10.1016/j.clay.2015.05.001 ↗
99. Use of encapsulated natural compounds as antimicrobial additives in food packaging: a brief review10.1016/j.tifs.2018.09.003 ↗
100. Applications and interfaces of Halloysite nanocomposites10.1016/j.clay.2015.06.034 ↗