journal article·2018-02Open access

Photocatalytic decolorization of cationic and anionic dyes over ZnO nanoparticle immobilized on natural Tunisian clay

Haithem Bel Hadjltaief, Sameh Ben Ameur, Patrick Da Costa, Mourad Ben Zina, Maria Elena Galvez

Abstract

Abstract In the present work we describe a simple and low-cost method for the decolorization of textile dyeing and printing wastewaters, using ZnO as photocatalyst supported on natural Tunisian clay (ZnO/Clay). This composite ZnO/Clay material was synthesized through a sol–gel method. X-ray diffraction (XRD), Nitrogen Physisorption (BET), Infrared Spectroscopy (FTIR), Scanning Electronic Microscopy (SEM) and High-Resolution Transmission Electron Microscopy (HRTEM) linked with Energy Dispersive X-ray (EDX), were performed in order to explain the characteristics of the ZnO/Clay photocatalyst. The XRD patterns, pointing to the presence of ZnO of very small crystal sizes, i.e. highly dispersed on the clay surface. The photocatalytic activity of ZnO/Clay was assayed in the decolorization of a cationic dye (Malachite Green, MG) and anionic dyes (Red Congo, RC) in aqueous solution as models pollutants under UV irradiation. In addition, the effects of different parameters such as pH of the solution, catalyst dosage, concentration of the dyes, irradiation source, as well as the influence of the presence of inorganic ions were investigated. The ZnO/Clay photocatalyst exhibited high photocatalytic activity of MG and CR decolorization under simulated solar compared to UV irradiation. The recyclability of the ZnO/Clay photocatalyst was as well validated.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Decomposition of chlorinated volatile organic compounds (CVOCs) using NTP coupled with TiO2/GAC, ZnO/GAC, and TiO2-ZnO/GAC in a plasma-assisted catalysis system10.1016/j.elstat.2014.10.008 ↗
2. Photocatalytic decouloration of malachite green dye by application of TiO2 nanotubes10.1016/j.jhazmat.2009.03.076 ↗
3. Photocatalytic degradation of methylene blue dye by zinc oxide nanoparticles obtained from precipitation and sol-gel methods10.1007/s11356-016-7750-6 ↗
4. Bel Hadjltaief H, Da Costa P, Elena Galvez M, Ben Zina M (2013) Influence of operational parameters in the heterogeneous photo-fenton 435 discoloration of wastewaters in the presence of an iron- pillared clay. Ind. Eng. Chem. Res. 52:16656–16665. doi: https://doi.org/10.1021/ie4018258.10.1021/ie4018258 ↗
5. Fe-clay-plate as a heterogeneous catalyst in photo-Fenton oxidation of phenol as probe molecule for water treatment10.1016/j.clay.2014.01.020 ↗
6. Bel Hadjltaief H, Galvez ME, Ben Zina M, Da Costa P (2014b) TiO2/clay as a heterogeneous catalyst in photocatalytic/photochemical oxidation of anionic reactive blue 19. Arab. J. Chem. doi: https://doi.org/10.1016/j.arabjc.2014.11.006.10.1016/j.arabjc.2014.11.006 ↗
7. Photocatalytic degradation of methyl green dye in aqueous solution over natural clay-supported ZnO–TiO2 catalysts10.1016/j.jphotochem.2015.09.008 ↗
8. Efficient removal of cadmium and 2-chlorophenol in aqueous systems by natural clay: adsorption and photo-Fenton degradation processes
9. Microwave assisted synthesis of CuS-reduced graphene oxide nanocomposite with efficient photocatalytic activity towards azo dye degradation10.1016/j.jece.2016.10.023 ↗
10. A study on removal characteristics of copper from aqueous solution by sewage sludge and pomace ashes10.1016/j.jhazmat.2007.07.092 ↗
11. Clay encapsulated ZnO nanoparticles as efficient catalysts for N-benzylation of amines10.1016/j.catcom.2011.08.026 ↗
12. Synthesis and characterization of novel Fe@ZnO nanosystem10.1016/j.jallcom.2013.05.015 ↗
13. Effect of inorganic ions, photosensitisers and scavengers on the photocatalytic degradation of nicosulfuron10.1016/j.jphotochem.2016.12.031 ↗
14. ZnO/montmorillonite for photocatalytic and photochemical degradation of methylene blue10.1016/j.clay.2011.05.001 ↗
15. Removal of synthetic dyes from wastewaters: a review10.1016/j.envint.2004.02.001 ↗
16. Characterization of TiO2 and ZnO nanoparticles and their applications in photocatalytic degradation of azodyes10.1016/j.ecoenv.2015.04.043 ↗
17. Comparative photocatalytic degradation of estrone in water by ZnO and TiO2 under artificial UVA and solar irradiation10.1016/j.cej.2012.09.066 ↗
18. Effective photocatalytic decolorization of methylene blue utilizing ZnO/rectorite nanocomposite under simulated solar irradiation10.1016/j.jallcom.2014.07.102 ↗
19. Microwave assisted synthesis, characterization and antibacterial activity of Ag/ZnO nanoparticles supported bentonite clay10.1016/j.jhazmat.2013.08.074 ↗
20. Beneficial role of ZnO photocatalyst supported with porous activated carbon for the mineralization of alizarin cyanin green dye in aqueous solution10.1016/j.jare.2012.08.005 ↗
21. Photocatalytic degradation of 4-nitrophenol with ZnO supported nano-clinoptilolite 477 zeolite10.1016/j.jiec.2013.06.026 ↗
22. Efficient degradation of organic dyes by titanium dioxide–silicotungstic acid nanocomposite films: influence of inorganic salts and surfactants10.1016/j.colsurfa.2013.12.005 ↗
23. A novel photoresponsive ZnO-fly ash nanocomposite for environmental and energy applications10.1016/j.apcatb.2013.05.045 ↗
24. Solar photocatalytic degradation of hazardous Congo red using low-temperature synthesis of zinc oxide nanoparticles10.1016/j.psep.2016.04.006 ↗
25. Facile fabrication of mesoporous-Fe2O3/SnO2 nanoheterostructure for photocatalytic degradation of malachite green10.1016/j.cattod.2013.10.038 ↗
26. Photocatalytic performance of ZnO nanomaterials for self sensitized degradation of malachite green dye under solar light10.1016/j.apcata.2014.10.053 ↗
27. TiO2,ZnO and nanobimetallic silica catalyzed photodegradation of methylgreen10.1016/j.mssp.2012.04.018 ↗
28. Photocatalytic activity of TiO2 nanoparticles synthesized in presence of ammonium hexafluorosilicate10.1016/j.saa.2015.06.072 ↗
29. Photocatalytic process by immobilized carbon black/ZnO nanocomposite for dye removal from aqueous medium: optimization by response surface methodology10.1016/j.jiec.2013.09.003 ↗
30. Rapid degradation of Congo red by molecularly imprinted polypyrrole-coated magnetic TiO2 nanoparticles in dark at ambient conditions10.1016/j.jhazmat.2015.03.067 ↗
31. Photo-degradation of acid yellow 11 in aqueous on nano-ZnO/bentonite under ultraviolet and visible light irradiation10.1016/j.matlet.2013.12.022 ↗
32. Quantum sized zinc oxide immobilized on bentonite clay and degradation of C.I. Acid red 35 in aqueous under ultraviolet light10.1155/2015/750869 ↗
33. Influence of inorganic anions and organic additives on photocatalytic degradation of methyl orange with supported polyoxometalates as photocatalyst10.1016/S1002-0721(12)60286-5 ↗
34. Photocatalytic degradation of phenol over ZnO nanosheets immobilized on montmorillonite10.1016/j.mssp.2015.04.039 ↗
35. Preparation and photo-catalytic activities of FeOOH/ZnO/MMT composite10.1016/j.apsusc.2015.07.030 ↗