journal article·2016-07

Functional magnetic nanoparticle/clay mineral nanocomposites: preparation, magnetism and versatile applications

Liang Chen, Chun Hui Zhou, Saverio Fiore, Dong Shen Tong, Hao Zhang, Chun Sheng Li, Sheng Fu Ji, Wei Hua Yu

Applied Clay Science· Volume 127-128
Publisher page

Abstract

Clay minerals and magnetic nanoparticles (MNP) combine to form a class of advanced nanocomposites that would possess exceptional magnetism, stability, adsorption, catalysis, and biocompatibility. This review summarizes and examines recent preparation strategies, properties and applications of magnetic nanoparticle/clay mineral (MNP/CM) nanocomposites. It is organized into five sections. The first section introduces the characteristics of magnetic nanoparticles, clay minerals and the scientific and technological necessity and significance of MNP/CM nanocomposites. The second section is concerned with the preparation of MNP/CM nanocomposites which involve the introduction of MNP into clay minerals via the coprecipitation of MNP and clay minerals, the combination of MNP and pillared clay minerals, the MNP-pillared clay minerals, the combination of surfactants coated MNP and clay minerals, and the intercalation of molecular magnetic compounds into clay minerals. In particular, great strides have been made in the integration of MNP with organo-clay minerals and the resultant nanocomposites can be assembled into the films of MNP/CM nanocomposite. The third focuses on discussion on the distinct magnetism, reactivity and stability of MNP/CM naanocomposites. The superparamagnetic MNP in MNP/CM nanocomposites show a fast response to external magnetic fields and allow MNP/CM nanocomposites to be readily manipulated, well functionalized and easily separated. The fourth section deals with the uses and potentials of MNP/CM nanocomposites in electromagnetic devices, magnetorheological fluids/ferrofluids, magnetic adsorbents, catalysts and biomaterials. The last section presents the view on the existing problems and challenges. Accordingly, it is suggested that future studies need place emphasis on narrowing the size distribution of the MNP/CM nanocomposites, endowing the MNP/CM nanocomposites with more functionalities, uncovering the preparation-modification-structure-magnetism-activity relationships of the MNP/CM nanocomposites, and advancing the practical applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Iron oxide chemistry and applications · Nanoparticle-Based Drug Delivery · Clay minerals and soil interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Influence of pH and ionic strength on removal processes of a sedimentary humic acid in a suspension of vermiculite10.1016/S0927-7757(03)00418-7 ↗
2. Nanoparticle interaction with plasma proteins as it relates to particle biodistribution, biocompatibility and therapeutic efficacy10.1016/j.addr.2009.03.009 ↗
3. Removal of methylene blue from aqueous solution by montmorillonite/CoFe2O4 composite with magnetic separation performance10.1016/j.desal.2010.08.004 ↗
4. Quinoline sorption on Na-montmorillonite: contribution of protonated and neutral species10.1346/CCMN.1987.0350204 ↗
5. Preparation of a biocompatible magnetic film from an aqueous ferrofluid10.1016/j.jmmm.2005.11.021 ↗
6. Layer-by-layer assembly of core-shell magnetite nanoparticles: effect of silica coating on interparticle interactions and magnetic properties10.1002/(SICI)1521-4095(199908)11:12<1006::AID-ADMA1006>3.0.CO;2-2 ↗
7. Novel flow injection synthesis of iron oxide nanoparticles with narrow size distribution10.1016/j.ces.2006.02.032 ↗
8. Mössbauer study of magnetic nanoparticles encapsulated in vermiculite
9. Antibody-functionalized hybrid superparamagnetic nanoparticles10.1002/adfm.200600560 ↗
10. Chitosan-clay composite as highly effective and low-cost adsorbent for batch and fixed-bed adsorption of methylene blue10.1016/j.cej.2013.09.066 ↗
11. Degradation of phenol in photo-Fenton process by phosphoric acid modified kaolin supported ferric-oxalate catalyst: optimization and kinetic modeling10.1016/j.cej.2012.04.053 ↗
12. Pillared montmorillonite supported ferric oxalate as heterogeneous photo-Fenton catalyst for degradation of amoxicillin10.1016/j.apcata.2011.11.023 ↗
13. Degradation of phenol in aqueous solution by Fenton, sono-Fenton and sono-photo-Fenton methods10.1002/clen.201000072 ↗
14. The role of the nature of pillars in the structural and magnetic properties of magnetic pillared clays10.1346/CCMN.2011.0590601 ↗
15. Adsorption of poly (4-vinylpyridine) onto bentonites10.1016/S0167-577X(03)00524-X ↗
16. Magnetic nanoscaled Fe3O4 as an efficient and reusable heterogeneous catalyst for degradation of methyl orange in microwave-enhanced Fenton-like system10.4028/www.scientific.net/AMM.448-453.830 ↗
17. Magnetically retrievable catalysts for organic synthesis10.1039/C2CC35663E ↗
18. Molecular-sieve based MRI contrast agents10.1016/0925-8388(94)90170-8 ↗
19. A study of suspending agents for gadolinium(III)-exchanged hectorite. An oral magnetic resonance imaging contrast agent10.1021/la9605100 ↗
20. Studies of gadolinium(III)-modified hectorite clays as potential oral MRI contrast agents10.1021/jp961478l ↗
21. Synthesis of hexagonal Y type zeolites in the presence of Gd(III) complexes of 18-crown-610.1016/S0927-6513(97)00054-0 ↗
22. Colloidal drug carriers: achievements and perspectives10.1007/s000180300002 ↗
23. Magnetically modified bentonite as a possible contrast agent in MRI of gastrointestinal tract10.2478/s11696-007-0057-9 ↗
24. Electrospray of ionic precursor solutions to synthesize iron oxide nanoparticles: modified scaling law10.1016/j.ces.2006.11.029 ↗
25. Applicability of the various adsorption models of three dyes adsorption onto activated carbon prepared waste apricot10.1016/j.jhazmat.2005.11.055 ↗
26. A biosensor based on magnetoresistance technology10.1016/S0956-5663(98)00037-2 ↗
27. Finite-size effects in fine particles: magnetic and transport properties10.1088/0022-3727/35/6/201 ↗
28. The gaint transverse magnetoresistance in a magnetorheological suspension with a conducting carrier10.1016/S0304-8853(99)00304-2 ↗
29. Adsorption of formaldehyde at mineral nanoporous sorbents exposed to a pulse magnetic field10.1134/S2070205109020130 ↗
30. Pillared Clays and Clays Minerals
31. General Introduction: Clays, Clay Minerals, and Clay Science
32. Functionalisation of magnetic nanoparticles for applications in biomedicine10.1088/0022-3727/36/13/203 ↗
33. Novel method to evaluate diffusion controlled release of drug from resinate10.1016/0378-5173(86)90147-X ↗
34. Surface effects in metallic iron namoparticles10.1103/PhysRevLett.72.282 ↗
35. Functionalized silica for heavy metal ions adsorption10.1016/S0927-7757(03)00138-9 ↗
36. Organophilic bentonites as adsorbents for radionuclides: I. Adsorption of ionic fission products10.1016/S0169-1317(99)00041-1 ↗
37. Synthesis and characterization of magnetically modified clay composites10.1021/cm000137o ↗
38. In situ manipulation of magnetic anisotropy in magnetite thin films10.1103/PhysRevB.77.104445 ↗
39. Struktur und entstehung des sepioliths
40. Electro-Fenton process and related electrochemical technologies based on Fenton's reaction chemistry10.1021/cr900136g ↗
41. Structures and Mineralogy of Clay Minerals
42. Dielectric properties improvement of polymer composite prepared from poly(vinylidene difluoride) and barium-modified porous clay heterostructure10.1007/s13391-012-2210-z ↗
43. Synthesis and characterization of magnetic porous clay heterostructure10.1007/s10934-013-9739-6 ↗
44. Multifunctional biocompatible coatings on magnetic nanoparticles10.1070/RC2012v081n11ABEH004280 ↗
45. Magnetic Composites from Minerals: Study of the Iron Phases in Clay and Diatomite Using Mössbauer Spectroscopy, Magnetic Measurements and XRD
46. Gadolinium(III) chelates as MRI contrast agents: structure, dynamics, and applications10.1021/cr980440x ↗
47. A study on Al and Al-Ce-Fe pillaring species and their catalytic potential as they are supported on a bentonite10.1016/j.apcata.2007.09.047 ↗
48. Catalytic wet hydrogen peroxide oxidation of para-chlorophenol over Al/Fe pillared clays (AlFePILCs) prepared from different host clays10.1016/j.apcatb.2010.10.015 ↗
49. Degradation of 4-chlorophenol from wastewater through heterogeneous Fenton and photo-Fenton process, catalyzed by Al-Fe PILC10.1016/j.clay.2012.01.019 ↗
50. Catalytic wet peroxide oxidation of phenol over Fe-exchanged pillared beidellite10.1016/S0043-1354(02)00449-9 ↗
51. Copper- and iron-pillared clay catalysts for the WHPCO of model and real wastewater streams from olive oil milling production10.1016/j.apcatb.2006.01.031 ↗
52. Aggregation and adsorption of reactive dyes in the presence of an anionic surfactant on mesoporous aminopropyl silica10.1016/j.jcis.2006.11.049 ↗
53. Adsorption of methylene blue onto Fe3O4/activated montmorillonite nanocomposite10.1016/j.clay.2015.06.038 ↗
54. Sorption of p-nitrophenol by anion-cation modified palygorskite10.1016/j.jhazmat.2009.02.105 ↗
55. Superparamagnetic silica-iron oxide nanocomposites for application in hyperthermia10.1002/adem.200300574 ↗
56. Heterogeneous UV-Fenton catalytic degradation of dyestuff in water with hydroxyl-Fe pillared bentonite10.1016/j.cattod.2007.06.022 ↗
57. The thermal behavior of kaolinite intercalation complexes-a review10.1016/j.tca.2012.04.005 ↗
58. Microstructure and magnetic properties of strained Fe3O4 films10.1063/1.2832305 ↗
59. Catalytic activity of iron species in layered clays for photodegradation of organic dyes under visible irradiation10.1016/j.apcatb.2007.08.006 ↗
60. Phosphate adsorption from sewage sludge filtrate using zinc-aluminum layered double hydroxides10.1016/j.jhazmat.2009.04.052 ↗
61. Molecular composition of iron oxide nanoparticles, precursors for magnetic drug targeting, as characterized by confocal Raman microspectroscopy10.1039/b419004a ↗
62. New organo-montmorillonite complexes with hydrophobic and hydrophilic functions10.1016/S0167-577X(97)00092-X ↗
63. Dynamical mechanical properties of gelling colloidal disks10.1122/1.551107 ↗
64. Properties of ferromagnetic micropowders10.1016/0304-8853(80)90452-7 ↗
65. Adsorption characteristics of montmorillonite clay modified with iron oxide with respect to methylene blue in aqueous media10.1016/j.clay.2014.03.023 ↗
66. Preparation of TiO2-pillared montmorillonite as photocatalyst. Part I. Microwave calcination, characterization, and adsorption of a textile azo dye. Appl10.1016/j.clay.2008.12.010 ↗
67. Removal of chlorinated phenols aqueous solutions by adsorption on alumina pillared clays and mesoporous alumina aluminum phosphates10.1016/S0043-1354(97)00206-6 ↗
68. Physicochemical characterization and adsorption behavior of calcined Zn/Al hydrotalcite-like compound (HTlc) towards removal of fluoride from aqueous solution10.1016/S0021-9797(03)00082-1 ↗
69. Studies on Mg/Fe hydrotalcite-like-compound (HTIc): removal f chromium (VI) from aqueous solution10.1080/0020723042000212627 ↗
70. Studies on Mg/Fe hydrotalcite-like-compound (HTlc)- I. Removal of inorganic selenite (SeO32−) from aqueous medium10.1006/jcis.2002.8319 ↗
71. Organophilic clays: characteristics, preparation methods, intercalation compounds and characterization techniques
72. Effect of an oscillating magnetic field on the release properties of magnetic collagen gels10.1021/la060280h ↗
73. Applications of nanoparticles in biology10.1002/adma.200703183 ↗
74. Remotely triggered release from magnetic nanoparticles10.1002/adma.200700091 ↗
75. Magnetic hyperthermia of laponite based ferrofluid10.1016/j.jmmm.2013.02.032 ↗
76. Zeta potential study of natural-and acid-activated sepiolites in electrolyte solutions10.1002/cjce.20573 ↗
77. Preparation and properties of magnetite and polymer magnetite nanoparticles10.1021/la980971g ↗
78. Magnetic colloids as drug vehicles10.1002/jps.21249 ↗
79. Supercritical fluids as solvents for chemical and materials processing10.1038/383313a0 ↗
80. On the nature and location of nanoparticulate iron phases and their precursors synthetized within a sepiolite matrix10.1021/jp077173w ↗
81. Core-shell structured iron nanoparticles well dispersed on montmorillonite10.1016/j.jmmm.2009.06.060 ↗
82. Solvent-free atom transfer radical polymerization for the preparation of poly (poly (ethyleneglycol) monomethacrylate)-grafted Fe3O4 nanoparticles: synthesis, characterization and cellular uptake10.1016/j.biomaterials.2007.08.039 ↗
83. Composites of polymeric gels and magnetic nanoparticles: preparation and drug release behavior10.1002/app.26321 ↗
84. Uber die adsorption in Losungen [adsorption in solution]
85. Magnetic nanoparticles: synthesis, functionalization, and applications in bioimaging and magnetic energy storage10.1039/b815548h ↗
86. Treatment of municipal leachate of landfill by Fenton-like heterogeneous catalytic wet peroxide oxidation using an Al/Fe-pillared montmorillonite as active catalyst10.1016/j.cej.2011.10.031 ↗
87. Preparation and sedimentation behavior in magnetic fields of magnetite-covered clay particles10.1021/la047393q ↗
88. Imaging of non- or very subtle contrast-enhancing malignant gliomas with C-11-methionine positron emission tomography10.2310/7290.2011.00014 ↗
89. Optical negative refraction in ferrofluids with magnetocontrollability10.1103/PhysRevLett.104.034501 ↗
90. Magnetic modification of acid-activated kaolin: synthesis, characterization, and adsorptive properties10.1016/j.micromeso.2014.09.029 ↗
91. Montmorillonite-Cu(II)/Fe(III) oxides magnetic material for removal of cyanobacterial Microcystis aeruginosa and its regeneration10.1016/j.desal.2008.10.006 ↗
92. Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions—A review10.1016/j.clay.2009.11.044 ↗
93. A review on characterization of pillared clays by specific techniques10.1016/j.clay.2010.09.018 ↗
94. Nuclear Magnetic Resonance Spectroscopy of Molecules and Ions at Clay Surfaces
95. In vitro sustained release of LMWH from MgAl-layered double hydroxide nanohybrids10.1021/cm703602t ↗
96. Summary of recommendations of nomenclature committees relevant to clay mineralogy: report of the association Internationale pour l'etude des argiles (AIPEA) nomenclature committee for 200610.1346/CCMN.2006.0540610 ↗
97. Direct control of drug release behavior from layered double hydroxides through particle interactions10.1002/jps.21321 ↗
98. Selective adsorption and separation of BPA from aqueous solution using novel molecularly imprinted polymers based on kaolinite/Fe3O4 composites10.1016/j.cej.2011.04.036 ↗
99. Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications10.1016/j.biomaterials.2004.10.012 ↗
100. Surface-modified superparamagnetic nanoparticles for drug delivery: preparation, characterization, and cytotoxicity studies10.1109/TNB.2003.820277 ↗