journal article·2009-05

Influence of degree of dehydroxylation on the pozzolanic activity of metakaolin

Ch. Bich, J. Ambroise, J. Péra

Applied Clay Science· Volume 44· Issue 3-4
Publisher page

Abstract

Abstract Three kaolins were heated between 500 and 850 °C. The samples were tested by X-ray diffraction (XRD), differential thermal analysis (DTA), and Infra-Red (IR) spectroscopy in order to determine their mineralogical composition and degrees of crystallinity and dehydroxylation. The reactivity of the heated samples was evaluated by the determination of the residual quantity of Ca(OH) 2 by differential thermal analysis (DTA) performed on hydrated mixtures of 50% metakaolin and 50% Ca(OH) 2 . There was no direct relationship between the pozzolanic activity of metakaolin and the degree of dehydroxylation. Highest activity was obtained when the degree of dehydroxylation was > 95%.
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Research context

OpenAlex topics: Clay minerals and soil interactions · Concrete and Cement Materials Research · Glass properties and applications

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References (21)

Show source-provided references
1. Elaboration de liants pouzzolaniques à moyenne température et études de leurs propriétés physico-chimiques et mécaniques
2. Investigations on synthetic binders obtained by middle-temperature thermal dissociation of clay minerals
3. Pozzolanic behaviour of thermally activated kaolin
4. Bich, Ch., 2005. Contribution à l'étude de l'activation thermique du kaolin: évolution de la structure cristallographique et activité pouzzolanique. Ph. D. Thesis, Institut National des Sciences Appliqués de Lyon, France. (in French).
5. Metakaolin as a pozzolanic microfiller for high-performance mortars10.1016/S0008-8846(98)00045-3 ↗
6. Hydration of cements based on metakaolin: thermochemistry10.1680/adcr.1990.3.12.167 ↗
7. Pozzolanic reaction of metakaolinite and its effects on Portland cement hydration10.1007/BF01191976 ↗
8. Pore size distribution and degree of hydration of metakaolin-cement pastes10.1016/S0008-8846(00)00203-9 ↗
9. Réactivité des montmorillonites calcinées
10. Thermal treatment of kaolin: the effect of mineralogy on the pozzolanic activity10.1016/S0169-1317(01)00040-0 ↗
11. Liétard, O. 1977 Contribution à l'étude des propriétés physico-chimiques cristallographiques et morphologiques des kaolins. Ph. D. Thesis, Institut National Polytechnique de Lorraine, Nancy, France. (in French).
12. Martin-Calle, S., 1989. Pouzzolanicité d'argiles thermiquement activées: influence de la minéralogie et des conditions de calcination. Ph. D. Thesis, Institut National des Sciences Appliqués de Lyon, France. (in French).
13. Flash calcination of kaolinite studied by DSC, TG and MAS NMR10.1007/BF01979617 ↗
14. Pozzolanic activity of calcined laterite
15. Infrared spectroscopy of inorganic compounds
16. Properties of mass concrete containing active pozzolan made from clay
17. Metakaolin and calcined clays as pozzolans for concrete: a review10.1016/S0958-9465(00)00092-5 ↗
18. Studies on thermal transformations and pozzolanic activities of clay from Jammu region (India)10.1007/BF01914268 ↗
19. Portlandite consumption in metakaolin cement pastes and mortars10.1016/S0008-8846(96)00187-1 ↗
20. Chemical and autogenous shrinkage of Portland cement-metakaolin pastes10.1680/adcr.1998.10.3.109 ↗
21. Worral · 1986