journal article·2003-04

Clay and iron oxide pigments in the history of painting

David Hradil, Tomáš Grygar, Janka Hradilová, Petr Bezdička

Applied Clay Science· Volume 22· Issue 5
Publisher page

Abstract

Clay minerals and iron oxides are intimately related in the process of their natural formation. Their mineralogical composition and physical properties correspond to the physical–chemical conditions of weathering, sedimentation and alteration processes by means of which these minerals are associated giving different types of laterites, ferrolites, ochres, and coloured clays and soils. Very early in human history, these and other clay materials were adopted as mineral pigments. Their structural and mineralogical features are directly related with their natural genesis and provenance and help us in the study of historical painting techniques and materials. This paper gives general information about geological sources and their characteristics, the literary evidence of use of different forms of earthy pigments on historical paintings, about analytical methods suitable in their identification within the ground and colour layers of the painting, and handling with the samples of works of art. The examples focused preferentially on the period of European mediaeval and baroque painting. D 2003 Elsevier Science B.V. All rights reserved.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Cultural Heritage Materials Analysis · Building materials and conservation · Mineralogy and Gemology Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Academia Italica, the Public School of Drawing, or the Gentleman's Accomplishment, 1666. London.
2. Problems of conservation of wall paintings in India
3. Japanese wall-painting: an art historical overview
4. Mineral occurrence in soil environments
5. Augusti, S., 1967. I Colori Pompeiani. De Luca, Roma.
6. Bardwell · 1795
7. Wie man sol machen ein guete goltz grunndt: Anweisungen zur Glanzvergoldung in der Buchmalerei
8. Chemical and mineralogical analyses of Gallo-Roman wall painting from Dietikon, Switzerland10.1111/j.1475-4754.1996.tb00762.x ↗
9. Les pigments verts en peinture murale romaine: bilan analytique
10. Mineral fillers in paper10.1080/03094227.1991.9638393 ↗
11. Bentschev · 1997
12. Berger, E., 1973. Quellen für Maltechnik während der Renaissance und deren Folgezeit (16.–18. Jahrhundert) in Italien, Spanien, den Niederlanden, Deutschland, Franreich und England: Nebst dem de Mayerne Ms. Reprinted from 1901. Martin Sändig oHG, Walluf b. Wiesbaden.
13. Prussian Blue
14. Ochre-differentiation through micro-Raman and micro-FTIR spectroscopies: application on wall painting at Meteora and Mount Athos, Greece10.1016/S1386-1425(99)00134-1 ↗
15. Brunello · 1975
16. The identification of aerinite as a blue pigment in the Romanesque frescoes of the Pyrenean region10.1179/sic.1992.37.2.132 ↗
17. A Mössbauer approach to the physico-chemical characterisation of iron-containing pigments for historical wall paintings10.1016/S1296-2074(00)01088-8 ↗
18. Cennino, C., 1978. Il Libro dell' Arte. Thompson Jr., D.V. (translator), The Craftsman's Handbook. Reprinted from 1437. Dover Publications, New York.
19. Raman microscopy: application to the identification of pigments on medieval manuscripts10.1039/cs9952400187 ↗
20. The identification by Raman microscopy and X-ray diffraction of iron-oxide pigments and of the red pigments found on Italian pottery fragments10.1016/S0022-2860(97)00239-1 ↗
21. Colours and pigments of the Ancient Egypt
22. Chemical microscopy10.1021/a1000012s ↗
23. Cornell · 1996
24. Les matières pigmentés utilisés en préhistoire: provenance, préparation, mode d'utilisation
25. Mössbauer study of rock-paintings from Minas-Gerais (Brazil)10.1007/BF02398185 ↗
26. Interpretation of Mössbauer spectra of nontronite, celadonite and glauconite10.1346/CCMN.1987.0350506 ↗
27. Dissertation sur la chlorite ou terre verte de Vérone
28. Environmental magnetism: an introduction10.1023/A:1003122305503 ↗
29. Les terres vertes et leur utilisation en peinture murale romaine
30. Couleur, nature et origine des pigments verts employés en peinture murale gallo-romaine
31. Electrochemical analysis of the alterations in copper pigments using charge transfer coefficient/peak potential diagrams. Application to microsamples of baroque wall paintings attached to polymer film electrodes10.1007/s002160100736 ↗
32. Electrochemistry of iron oxide pigments (earths) from pictorial microsamples attached to graphite–polyester composite electrodes10.1039/b100257k ↗
33. Electrochemical identification of metal ions in archaeological ceramic glazes by stripping voltammetry at graphite/polyester composite electrodes10.1016/S0039-9140(01)00552-5 ↗
34. Isomorphous cation distribution in celadonites, glauconites and Fe-illites determined by infrared, Mössbauer and EXAFS spectroscopies10.1180/claymin.1997.032.2.01 ↗
35. Eastlake Sir, Ch.L., 1960. Methods and Materials of the Great Schools and Masters. Reprinted from 1847. Dover Publications, New York.
36. Romano–British wall-painting fragments: a spectroscopic analysis10.1039/b109762h ↗
37. 1986 · vol. 1
38. 1997 · vol. 3
39. A monument of Byzantine wall painting—the method of construction
40. Green earth
41. Electrochemical analysis of solids10.1135/cccc20020163 ↗
42. Voltammetric analysis of Fe-oxide pigments10.1039/B205199K ↗
43. Grygar, T., Hradilová, J., Hradil, D., Bezdička, P., Bakardjieva, S., in press. Analyses of earthy pigments in grounds of Baroque paintings. Anal. Bioanal. Chem.
44. Technické paralely deskové a nástěnné malby 14. stoletı́
45. Malı́řská technika Mistra Theodorika
46. Harley · 1982
47. A note on burnt yellow earth pigments: documentary sources and scientific analysis10.1179/sic.1997.42.3.181 ↗
48. Electron microscopy in materials research of historical paintings
49. Clay minerals in pigments of mediaeval and baroque paintings
50. Paint extenders based upon naturally occurring aluminium silicates (china clays)
51. Maya blue paint: an ancient nanostructured material10.1126/science.273.5272.223 ↗
53. Étude et Identification du “Bleu Maya”
54. In-situ phase analysis by a versatile miniaturized Mossbauer spectrometer10.1023/A:1012626322264 ↗
55. Clay and man: clay raw materials in the service of man10.1016/0169-1317(95)00029-4 ↗
56. Kužvart · 1984
57. Abrasive stripping voltammetry—the electrochemical alternative for pigment analysis
58. Review of extender pigments
59. Laurie · 1967
60. Maya blue—a new perspective10.2307/279662 ↗
61. Maya blue—further perspectives and the possible use of indigo as the colorant10.2307/279911 ↗
62. Ancient Egyptian materials and industries
63. Surface layer types of kaolinite: a high-resolution transmission electron microscope study10.1346/CCMN.1999.0470208 ↗
64. Baseline studies of the clay minerals society source clays: infrared method10.1346/CCMN.2001.0490508 ↗
65. Comparative FT-IR study of structural modifications during acid treatment of dioctahedral smectites and hectorite10.1016/S1386-1425(98)00040-7 ↗
66. Mayer · 1991
67. Merrifield · 1967
68. A paint mine from the early Upper Palaeolithic age near Lovas (Hungary, County Veszprem)
69. Moore · 1997
70. Factors influencing the grain size distribution of authigenic minerals10.2475/ajs.296.9.989 ↗
71. Analytical methods applied in the investigation of the Bardwell samples, appendix to “Thomas Bardwell and his practice of painting”
72. Some theoretical aspects of electrodissolution of iron oxide (α-Fe2O3) in carbon paste electrodes with acidic binder10.1016/0368-1874(84)83622-9 ↗
73. Neuberger, A., 2002. The Technical Arts of the Ancients. Reprinted from 1928. Kegan Paul Intl., New York.
74. Nature and origin of green phyllites utilized as pigment in Roman wall paintings from Gaul-celadonite and glaucony
75. Mineralogical data of prehistoric red colouring material of Provence: a proof that some of them were certainly obtained by goethite calcination
76. A propos des colorants rouges prehistoriques
77. Likneskjusmi: fourteenth century instructions for painting from Iceland
78. XRD study of the goethite–hematite transformation: application to the identification of heated prehistoric pigments10.1016/S0992-4361(98)80011-8 ↗
79. Red Paleolithic pigments: natural hematite or heated goethite?10.1111/j.1475-4754.1999.tb00983.x ↗
80. 1993 · vol. 2
81. Transmission electron microscopy applied to the study of works of art. Sample preparation methodology and possible techniques10.1046/j.1365-2818.1997.2460804.x ↗
82. Contribution to the study of grounds for panel painting of the Spanish school in the 15th and 16th centuries
83. Schäfer, G., 1855. Das Handbuch der Malerei vom Berge Athos. Trier. Godeh (translator).
84. Mineralogy and chemistry of ochre sediments from an acid mine drainage near a disused mine in Cornwall, UK10.1180/000985599546172 ↗
85. Slánský, B., 1953. Technika Malby I (The Painting Technique I). Stát. nakl. krás. lit., hudby a um. Praha (in Czech).
86. Slánský, B., 1956. Technika Malby II (The Painting Technique II). Stát. nakl. krás. lit., hudby a um. Praha (in Czech).
87. Oxygen-isotope ratio in quartz as indicators of the provenance of archaelogical ochres10.1006/jasc.1996.0159 ↗
88. Thermal and spectroscopic investigations of some Egyptian clays10.1016/0040-6031(83)80035-5 ↗
89. Thompson, D.V., 1936. The Materials of Mediaeval Painting. Dover Publications, London.
90. Thompson, D.V., Hamilton, G.H. (translator) 1933. De Arte Illuminandi. Yale University Press, New Haven.
91. Mossbauer characterization of iron oxides and (oxy)hydroxides: the present state of the art10.1023/A:1012603603203 ↗
92. Maya blue: a clay-organic pigment?10.1126/science.154.3749.645 ↗
93. Vitruvius · 1993
94. Essay of characterization of the colours discovered in the Lascaux cave (Dordogne-France) and future implications
95. Fragments of Roman wall painting in the J. Paul Getty Museum: a preliminary technical investigation
96. Watin · 1772
97. White pigments in Japanese paintings.
98. Pigments used on Japanese paintings from the protohistoric period through the 19th century
99. Polychromed sculptures in Japan
100. Raw materials for making porcelain and the characteristics of porcelain waxes in north and south China in ancient times10.1111/j.1475-4754.1987.tb00393.x ↗