journal article·2010-08

Ionic conductivity of (As2Se3)1 − x (AgHal) x (Hal = I, Br) nanocomposites

V. V. Tomaev, Yu. S. Tver’yanovich, M. D. Bal’makov, I. A. Zvereva, A. B. Missyul’

Glass Physics and Chemistry· Volume 36· Issue 4
Publisher page

Abstract

Nanocomposites based on chalcogenide glasses have been synthesized. A differential thermal analysis of (As2Se3)1 − x (AgI) x and (As2Se3)1 − x (AgBr)x (0 ≤ x ≤ 0.5) samples has been performed. The size of nanofragments that undergo elementary structural transformations has been evaluated. The data obtained are in agreement with the evaluated sizes of X-ray coherent scattering regions. The electrical properties of the glasses under consideration have been studied using impedance spectroscopy in the temperature range 293–393 K. It has been demonstrated that the ionic component of the electrical conductivity dominates in glasses with a high content of silver halide.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Phase-change materials and chalcogenides · Chemical Thermodynamics and Molecular Structure · Chalcogenide Semiconductor Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Ivanov-Shits, A.K. and Murin, I.V., Ionika tverdogo tela (Solid State Ionics), St. Petersburg: St. Petersburg State University, 2000, vol. 1 [in Russian].
2. Ivanov-Shits, A.K. and Dem’yanets, L.N., Materials of Solid State Ionics, Priroda (Moscow), 2003, no. 12, pp. 35–43.
3. Ukshe, E.A. and Bukun, N.G., Tverdye elektrolity (Solid Electrolytes), Moscow: Nauka, 1977 [in Russian].
4. Potanin, A.A., Solid-State Chemical Current Source Based on Ionic Conductor of the Lanthanum Trifluoride Type, Ross. Khim. Zh., 2001, vol. 45, nos. 5–6, pp. 58–63.
5. Borisova, Z.U., Khal’kogenidnye poluprovodnikovye stekla (Chalcogenide Semiconductor Glasses), Leningrad: Leningrad State University, 1983 [in Russian].
6. Onodera, Y., Furukawa, T., Hashimoto, S., Usuki, T., Amo, Y., and Kameda, Y., Vitrification and Transport Properties in AgBr-Doped Chalcogenide Systems, Solid State Ionics, 2006, vol. 177, pp. 2597–2599.10.1016/j.ssi.2006.05.028 ↗
7. Usuki, T., Nakajima, K., Furukawa, T., Sakurai, M., Kohara, S., Nasu, T., Amo, Y., and Kameda, Y., Structure of Fast Ion Conducting AgI-As2Se3 Glasses, J. Non-Cryst. Solids, 2007, vol. 353, pp. 3040–3044.10.1016/j.jnoncrysol.2007.05.036 ↗
8. Gaponenko, S.V., Optical Processes in Semiconductor Nanocrystals (Quantum Points), Fiz. Tekh. Poluprovodn. (St. Petersburg), 1996, vol. 30, no. 4, pp. 577–619 [Semiconductors (Engl. transl.), 1996, vol. 30, no. 4, pp. 315–336].
9. Pogosov, V.V., Calculation of the Surface-Tension Size Correction of Ultradisperse Metallic Particles, Fiz. Tverd. Tela (St. Petersburg), 1994, vol. 36, no. 9, pp. 2521–2529 [Phys. Solid State (Engl. transl.), 1994, vol. 36, no. 9, pp. 1371–1376].
10. Gibbs, J.W., The Collected Works of J. Willard Gibbs, vol. 1: Graphical Methods in the Thermodynamics of Fluids, New York: Dover, 1902. Translated under the title Termodinamicheskie raboty, Moscow: Goskhimizdat, 1950.
11. Volmer, M., Kinetik der Phasenbildung, Dresden, Germany: Theodor Steinkopff, 1939. Translated under the title Kinetika obrazovaiya novoi fazy, Moscow: Nauka, 1986 [in German and in Russian].
12. Skripov, V.P. and Kaverda, V.P., Spontannaya kristallizatsiya pereokhlazhdennykh zhidkostei (Spontaneous Crystallization of Supercooled Liquids), Moscow: Nauka, 1984 [in Russian].
13. Tolman, R.C., The Effect of Droplet Size on Surface Tension, J. Chem. Phys., 1949, vol. 17, pp. 333–337.10.1063/1.1747247 ↗
14. Rusanov, A.I., Fazovye ravnovesiya i poverkhnostnye yavleniya (Phase Equilibria and Surface Phenomena), Leningrad: Khimiya, 1967 [in Russian].
15. Valov, P.M. and Leiman, V.I., Size Effects in the Exciton Energy and First-Order Phase Transitions in CuCl Nanocrystals in Glass, Fiz. Tverd. Tela (St. Petersburg), 1999, vol. 41, no. 2, pp. 310–318 [Phys. Solid State (Engl. transl.), 1999, vol. 41, no. 2, pp. 278–285].
16. Bal’makov, M.D., On the Melting Temperature of Nanoparticles, Fiz. Khim. Stekla, 2008, vol. 34, no. 1, pp. 140–143 [Glass Phys. Chem. (Engl. transl.), 2008, vol. 34, no. 1, pp. 110–112].
17. Bal’makov, M.D., Microwave Aspect of Nanoparticle Melting, Vestn. St. Petersb. Univ., Ser. 4: Fiz., Khim. 2007, no. 2, pp. 58–65.
18. Bal’makov, M.D., The Thermodynamic Aspect of Melting and Softening of Nanoparticles, Fiz. Khim. Stekla, 2008, vol. 34, no. 5, pp. 727–739 [Glass Phys. Chem. (Engl. transl.), 2008, vol. 34, no. 5, pp. 559–568].
19. Borisova, Z.U., Khimiya stekloobraznykh poluprovodnikov, Leningrad: Leningrad State University, 1972. Translated under the title Glassy Semiconductors, New York: Plenum, 1981.
20. Vorokh, A.S., Disordered Atomic Structure of Cadmium Sulfide Nanoparticles, Extended Abstract of the Candidate Science Dissertation, Yekaterinburg: Advans Print, 2009 [in Russian].
21. Malinovskii, V.K., Disordered Solids: Universal Behavior of Structure, Dynamics, and Transport Phenomena, Fiz. Tverd. Tela (St. Petersburg), 1999, vol. 41, no. 5, pp. 805–808 [Phys. Solid State (Engl. transl.), 1999, vol. 41, no. 5, pp. 725–728].
22. Malinovsky, V.K. and Surovtsev, N.V., Inhomogeneity on the Nanometer Scale as a Universal Property of Glasses, Fiz. Khim. Stekla, 2000, vol. 26, no. 3, pp. 315–321 [Glass Phys. Chem. (Engl. transl.), 2000, vol. 26, no. 3, pp. 217–223].
23. Malinovskii, V.K., Novikov, V.N., and Sokolov, A.P., Nanometer-Scale Structure of Disordered Bodies, Usp. Fiz. Nauk, 1993, vol. 163, no. 5, pp. 119–124 [Phys.-Usp. (Engl. transl.), 1993, vol. 36, no. 5, pp. 440–444].10.3367/UFNr.0163.199305f.0119 ↗
24. Kleman, M., The Geometrical Nature of Disorder and Its Elementary Excitations, J. Phys. (Paris), 1982, vol. 43, pp. 1389–1396.10.1051/jphys:019820043090138900 ↗
25. Likhachev, V.A., Volkov, A.E., and Shudegov, V.E., Kontinual’naya teoriya defektov (Continuum Theory of Defects), Leningrad: Leningrad State University, 1986 [in Russian].
26. Rivier, N. and Duffy, D.M., Line Defects and Tunnelling Modes in Glasses, J. Phys. (Paris), 1982, vol. 43, pp. 293–306.10.1051/jphyscol:1982917 ↗
27. Sethna, J.P., Frustration and Curvature: Glasses and the Cholesteric Blue Phase, Phys. Rev. Lett., 1983, vol. 51, pp. 2198–2201.10.1103/PhysRevLett.51.2198 ↗
28. Nelson, D.R., Order, Frustration, and Defects in Liquids and Glasses, Phys. Rev. B: Condens. Matter, 1983, vol. 28, pp. 5515–5535.10.1103/PhysRevB.28.5515 ↗
29. Appen, A.A., Khimiya stekla (Glass Chemistry), Leningrad: Khimiya, 1974 [in Russian].
30. Majid, C.A., Prager, P.R., Fletcher, N.H., and Brettel, J.M., X-Ray Investigation of the Crystallization of Chalcogenide Glasses of the Type (As2Se3)1 − x -(AgI)x, J. Non-Cryst. Solids, 1974, vol. 16, pp. 365–374.10.1016/0022-3093(74)90081-7 ↗
31. Renninger, A.L. and Averbach, B.L., Crystalline Structures of As2Se3 and As4Se4, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1973, vol. 29, pp. 1583–1589.10.1107/S0567740873005091 ↗
32. Renninger, A.L. and Averbach, B.L., Atomic Radial Distribution Functions of As-Se Glasses, Phys. Rev. B: Solid State, 1973, vol. 8, no. 4, pp. 1507–1514.10.1103/PhysRevB.8.1507 ↗
33. West, A.R., Solid State Chemistry and Its Applications, Chichester: Wiley, 1984, part 1. Translated under the title Khimiya tverdogo tela: Teoriya i prilozheniya, Moscow: Mir, 1988, part 1.