journal article·2022-12-01Open access

Flexocaloric effect in superelastic materials

Clàudia Pérez-Junyent, Marcel Porta, Emma Valdés, Lluís Mañosa, Antoni Planes, Avadh Saxena, Eduard Vives

APL Materials· Volume 10· Issue 12

Abstract

We present a combined theoretical–experimental study of flexocaloric effects in superelastic materials exhibiting structural transitions. We study a Ginzburg–Landau model combined with a vibrational model for a beam near a ferroelastic transition loaded with a three-point bending setup. We also perform experiments on a Cu–Al–Ni single crystal undergoing a martensitic transition. We measure bent beam profiles, vertical force vs vertical deflection during a slow isothermal process, time evolution of the bending and unbending amplitudes, and the evolution of temperature profiles. We also compute the evolution of heat source and heat sink profiles. Finally, we study the location of acoustic emission events during the bending/unbending experiment. Our observations are consistent with the model predictions and allow us to identify the main physical parameters relevant for flexocaloric applications.
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Research context

OpenAlex topics: Shape Memory Alloy Transformations · Ferroelectric and Piezoelectric Materials · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departament de Física de la Matèria Condensada, Facultat de Física, Universitat de Barcelona 1 , Martí i Franquès 1, 08028 Barcelona, Catalonia

Departament de Física Quàntica i Astrofísica, Facultat de Física, Universitat de Barcelona 2 , Martí i Franquès 1, 08028 Barcelona, Catalonia

Theoretical Division, Los Alamos National Laboratory 3 , Los Alamos, New Mexico 87545, USA

Funding

Ministerio de Ciencia e Innovación · U.S. Department of Energy

References (24)

Show source-provided references
1. The resource basis of magnetic refrigeration10.1111/jiec.12488 ↗
2. Solid-state cooling by stress: A perspective10.1063/1.5140555 ↗
3. Caloric materials for cooling and heating10.1126/science.abb0973 ↗
4. Elastocaloric effect associated with the martensitic transition in shape-memory alloys10.1103/physrevlett.100.125901 ↗
5. The elastocaloric effect: A way to cool efficiently10.1002/aenm.201500361 ↗
6. Materials with giant mechanocaloric effects: Cooling by strength10.1002/adma.201603607 ↗
7. Flexocaloric effect near a ferroelastic transition10.1103/physrevb.104.094108 ↗
8. Torsional refrigeration by twisted, coiled, and supercoiled fibers10.1126/science.aax6182 ↗
9. Low-force compressive and tensile actuation for elastocaloric heat pumps10.1016/j.apmt.2020.100557 ↗
10. Low-force elastocaloric refrigeration via bending10.1063/5.0041500 ↗
11. Twist-based cooling of polyvinylidene difluoride for mechanothermochromic fibers10.1016/j.cej.2020.128060 ↗
12. Materials, physics and systems for multicaloric cooling10.1038/s41578-022-00428-x ↗
13. Frontiers of theoretical reserach on shape memory alloys: A general overview10.1007/s40830-018-0161-4 ↗
14. Acoustic emission and energy dissipation during front propagation in a stress-driven martensitic transition10.1103/physrevb.78.094104 ↗
15. Acoustic emission in martensitic transformations10.1016/j.jallcom.2011.10.082 ↗
16. Localizing sources of acoustic emission during the martensitic transformation10.1103/physrevb.89.214118 ↗
17. 2009
18. Disorder-driven pretransitional tweed pattern in martensitic transformations10.1103/physrevb.52.803 ↗
19. Tracking the dynamics of power sources and sinks during the martensitic transformation of a Cu–Al–Ni single crystal10.1063/5.0006859 ↗
20. Heat sink avalanche dynamics in elastocaloric Cu–Al–Ni single crystal detected by infrared calorimetry and Gaussian filtering10.1063/5.0066525 ↗
21. Imaging the dynamics of martensitic transitions using acoustic emission10.1103/physrevb.84.060101 ↗
22. Avalanche criticality in thermal-driven martensitic transitions: The asymmetry of the forward and reverse transitions in shape-memory materials10.1088/1361-648x/aa78d7 ↗
23. Driving-induced crossover in the avalanche criticality of martensitic transitions10.1103/physrevb.80.180101 ↗
24. Experimental evidence for universality of acoustic emission avalanche distributions during structural transitions10.1103/physrevlett.81.1889 ↗