Dynamics of exciton–polariton emission in CuI

We report on temperature-dependent (10 K – 250 K) spectral and dynamical properties of free exciton–polariton and bound exciton emission in copper iodide (CuI) bulk single crystals analyzed by means of time-resolved photoluminescence spectroscopy. The characteristic line shape of the polariton emission at low temperatures is interpreted in terms of the “k-linear term effect” on the degenerate Z1,2 excitons in CuI. For free exciton–polaritons, an increase in the decay time with increasing temperature up to 360 ps at 160 K is observed. For bound exciton emission, decay times between 180 ps and 380 ps are observed at low temperatures, revealing the expected EB3/2 dependence of radiative lifetime on the localization energy. Based on the observed rise times of bound excitons at low temperatures, a defect density of shallow acceptors of 1 × 1017 cm−3 was estimated, in agreement with measured room temperature free hole density.