journal article·2017-08-01Open access

Fabrication of atomically abrupt interfaces of single-phase TiH2 and Al2O3

Ryota Shimizu, Yuki Sasahara, Hiroyuki Oguchi, Kuniko Yamamoto, Issei Sugiyama, Susumu Shiraki, Shin-ichi Orimo, Taro Hitosugi

APL Materials· Volume 5· Issue 8

Abstract

We report the fabrication of atomically abrupt interfaces of titanium dihydride (δ-TiH2) films and α-Al2O3(001) substrates. With the assistance from reactive hydrogen in plasma, single-phase δ-TiH2 epitaxial thin films were grown on α-Al2O3(001) substrates using the reactive magnetron sputtering technique. Scanning transmission electron microscopy measurements revealed an atomically abrupt interface at the δ-TiH2(111) film and Al2O3(001) substrate. These results indicate that the reactive magnetron sputtering has great potential to deposit various epitaxial thin films of hydrides restricted by the hydrogenation limit. The fabrication of high-quality hydride epitaxial thin films with atomically controlled interfaces paves the way for future hydride electronics.
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Research context

OpenAlex topics: Hydrogen Storage and Materials · Nuclear Materials and Properties · Fusion materials and technologies

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Affiliations

School of Materials and Chemical Technology, Tokyo Institute of Technology 1 , 152-8552 Tokyo, Japan

Advanced Institute for Materials Research, Tohoku University 2 , 980-8577 Sendai, Japan

Institute for Materials Research, Tohoku University 3 , 980-8577 Sendai, Japan

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