journal article·2014-01-01Open access

Size-dependent mobility of gold nano-clusters during growth on chemically modified graphene

Gavin R. Bell, Peter M. Dawson, Priyanka A. Pandey, Neil R. Wilson, Paul A. Mulheran

APL Materials· Volume 2· Issue 1

Abstract

Gold nano-clusters were grown on chemically modified graphene by direct sputter deposition. Transmission electron microscopy of the nano-clusters on these electron-transparent substrates reveals an unusual bimodal island size distribution (ISD). A kinetic Monte Carlo model of growth incorporating a size-dependent cluster mobility rule uniquely reproduces the bimodal ISD, providing strong evidence for the mobility of large clusters during surface growth. The cluster mobility exponent of −5/3 is consistent with cluster motion via one-dimensional diffusion of gold atoms around the edges of the nano-clusters.
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Research context

OpenAlex topics: Graphene research and applications · Gold and Silver Nanoparticles Synthesis and Applications · nanoparticles nucleation surface interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

University of Warwick 1 Department of Physics, , Coventry CV4 7AL, United Kingdom

University of Strathclyde 2 Department of Chemical and Process Engineering, , James Weir Building, 75 Montrose St., Glasgow G1 1XJ, United Kingdom

References (28)

Show source-provided references
1. Rev. Mod. Phys. · 2013 · 85 · 92110.1103/RevModPhys.85.921 ↗
2. Int. Mater. Rev. · 2012 · 57 · 32810.1179/1743280411Y.0000000015 ↗
3. Surf. Sci. Rep. · 1998 · 31 · 12510.1016/S0167-5729(99)80001-6 ↗
4. Surf. Sci. Rep. · 2006 · 61 · 110.1016/j.surfrep.2005.08.004 ↗
5. Phys. Rev. Lett. · 2008 · 100 · 06810210.1103/PhysRevLett.100.068102 ↗
6. Langmuir · 2012 · 28 · 1557710.1021/la303323r ↗
7. J. Chem. Phys. · 2009 · 131 · 09470310.1063/1.3212092 ↗
8. J. Phys.: Condens. Matter · 2004 · 16 · R153710.1088/0953-8984/16/50/R01 ↗
9. Phys. Rev. B · 2006 · 73 · 04542210.1103/PhysRevB.73.045422 ↗
10. Surf. Sci. · 2011 · 605 · L110.1016/j.susc.2010.12.034 ↗
11. Europhys. Lett. · 2004 · 65 · 37910.1209/epl/i2003-10098-x ↗
12. Phys. Rev. Lett. · 2002 · 88 · 03610210.1103/PhysRevLett.88.036102 ↗
13. Phys. Rev. Lett. · 1998 · 81 · 63310.1103/PhysRevLett.81.633 ↗
14. Phys. Rev. B · 2002 · 66 · 20130210.1103/PhysRevB.66.201302 ↗
15. ACS Nano · 2009 · 3 · 254710.1021/nn900694t ↗
16. Small · 2011 · 7 · 320210.1002/smll.201101430 ↗
17. Nature (London) · 2012 · 490 · 19210.1038/nature11458 ↗
18. Laser Photonics Rev. · 2008 · 2 · 13610.1002/lpor.200810003 ↗
19. J. Mater. Sci. · 2013 · 48 · 732110.1007/s10853-013-7542-z ↗
20. Sens. Actuators · 2013 · 183 · 47810.1016/j.snb.2013.03.089 ↗
21. Appl. Phys. Lett. · 2012 · 100 · 06111610.1063/1.3683534 ↗
22. Nat. Methods · 2012 · 9 · 67610.1038/nmeth.2019 ↗
23. Phys. Rev. E · 2011 · 83 · 04161110.1103/PhysRevE.83.041611 ↗
24. Phys. Rev. B · 2008 · 77 · 07542710.1103/PhysRevB.77.075427 ↗
25. Phys. Rev. B · 2001 · 64 · 11540210.1103/PhysRevB.64.115402 ↗
26. Phys. Rev. Lett. · 1994 · 73 · 259110.1103/PhysRevLett.73.2591 ↗
27. Phys. Rev. Lett. · 1995 · 75 · 157410.1103/PhysRevLett.75.1574 ↗
28. See supplementary material at http://dx.doi.org/10.1063/1.4862696 for an AVI-format movie of the KMC model at optimized parameters.